ChemicalBook > CAS DataBase List > 1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE

1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE

Product Name
1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE
CAS No.
1127-97-5
Chemical Name
1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE
Synonyms
4'-chloro-2'-hydroxypropiophenone;1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE;1-(4-Chloro-2-hydroxyphenyl)-1-propanone;1-Propanone, 1-(4-chloro-2-hydroxyphenyl)-
CBNumber
CB3205352
Molecular Formula
C9H9ClO2
Formula Weight
184.62
MOL File
1127-97-5.mol
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1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE Property

Melting point:
49 °C
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Safety

Hazard Note 
Harmful
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C588040
Product name
1-(4-Chloro-2-hydroxyphenyl)propan-1-one
Packaging
50mg
Price
$200
Updated
2021/12/16
Matrix Scientific
Product number
084519
Product name
1-(4-Chloro-2-hydroxyphenyl)propan-1-one
Purity
97%
Packaging
500mg
Price
$255
Updated
2021/12/16
Matrix Scientific
Product number
084519
Product name
1-(4-Chloro-2-hydroxyphenyl)propan-1-one
Purity
97%
Packaging
1g
Price
$393
Updated
2021/12/16
AK Scientific
Product number
8970AC
Product name
1-(4-Chloro-2-hydroxyphenyl)propan-1-one
Packaging
500mg
Price
$394
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0009551
Product name
1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE
Purity
95.00%
Packaging
1G
Price
$893.24
Updated
2021/12/16
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1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE Chemical Properties,Usage,Production

Preparation

Preparation by Fries rearrangement of m-chlo- rophenyl propionate (b.p.0.8 90°) with aluminium chloride,
without solvent at 100° for 2 h (92%), at 140° for 2 h (89%), ? at 140–150° for 3 h, at 130° for 2 h (77%), at 165° for 1 h (72%), at 50° for 3 h (55%) or at 30–40° (53%)
n nitrobenzene at 25° for 6 h (87%)
Preparation by Fries rearrangement of m-chlorophenyl propionate with titanium tetrachloride at 100° for 2 h (75%)
Also obtained by Friedel–Crafts reaction of propionyl chloride with m-chlorophenol in the presence of aluminium chloride
Also obtained by isomerization of 2-chloro-4-hydroxypropiophenone on heating with aluminium chloride between 165° and 200° (30–70%).

1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(4-CHLORO-2-HYDROXYPHENYL)PROPAN-1-ONE Suppliers

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