Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
- Product Name
- Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
- CAS No.
- 137203-34-0
- Chemical Name
- Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
- Synonyms
- DABAL-Me3;DABAL-trimethylaluminum;Bis(trimethylaluminum)-DABCO(R) adduct;Triethylenediaminine bis(trimethylaluminum);1,4-diazabicyclo[2.2.2]octane,trimethylalumane;DABAL-Me3 (adduct of trimethylaluminum and DABCO);1,4-DIAZABICYLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX;1,4-Diazabicyclo[2.2.2]Octane Bis(Trimethylaluminum) Complex;Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct;Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3)
- CBNumber
- CB32095513
- Molecular Formula
- C12H24Al2N2
- Formula Weight
- 250.3
- MOL File
- 137203-34-0.mol
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Property
- Melting point:
- >250 °C
- Flash point:
- 23°C (73°F)
- storage temp.
- Hygroscopic, Room Temperature, Under inert atmosphere
- solubility
- Benzene (Slightly), DMSO (Slightly)
- form
- Solid
- color
- White to Off-White
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Stability:
- Hygroscopic, Moisture Sensitive, Unstable in Aqueous Solution
Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 14-15-22-36/37/38
- Safety Statements
- 16-26-43
- RIDADR
- UN 3395 4.3/PG 1
- WGK Germany
- 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H260In contact with water releases flammable gases which may ignite spontaneously
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 682101
- Product name
- Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
- Packaging
- 1g
- Price
- $71.2
- Updated
- 2024/03/01
- Product number
- 682101
- Product name
- Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
- Packaging
- 5g
- Price
- $186
- Updated
- 2024/03/01
- Product number
- D493348
- Product name
- 1,4-Diazabicyclo[2.2.2]OctaneBis(Trimethylaluminum)Complex
- Packaging
- 50mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 121974
- Product name
- Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octaneadduct(DABAL-Me3)
- Purity
- >95%
- Packaging
- 500mg
- Price
- $51
- Updated
- 2021/12/16
- Product number
- 121974
- Product name
- Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octaneadduct(DABAL-Me3)
- Purity
- >95%
- Packaging
- 1g
- Price
- $69
- Updated
- 2021/12/16
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct Chemical Properties,Usage,Production
Uses
DABAL-Me3: An Air Stable "Methyl Anion"
Uses
Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) is a non-pyrophoric alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.1
General Description
Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere.