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4-CYANOBUTYLZINC BROMIDE

Product Name
4-CYANOBUTYLZINC BROMIDE
CAS No.
226570-68-9
Chemical Name
4-CYANOBUTYLZINC BROMIDE
Synonyms
4-CYANOBUTYLZINC BROMIDE;4-cyanobutylzinc bromide solution;4-Cyanobutylzinc bromide solution 0.5 in THF;4-Cyanobutylzinc broMide solution 0.5 M in THF;4-CYANOBUTYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN;4-Cyanobutylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;4-Cyanobutylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
CBNumber
CB3209633
Molecular Formula
C5H8BrNZn
Formula Weight
227.42
MOL File
226570-68-9.mol
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4-CYANOBUTYLZINC BROMIDE Property

Density 
0.971 g/mL at 25 °C
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
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Safety

Hazard Codes 
F,Xn
Risk Statements 
14-19-22-36/38-40-36/37
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P281Use personal protective equipment as required.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
497894
Product name
4-Cyanobutylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$332
Updated
2024/03/01
Alfa Aesar
Product number
H58897
Product name
4-Cyanobutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$288
Updated
2023/06/20
Rieke Metals
Product number
2438
Product name
4-Cyanobutylzincbromide
Packaging
50mL
Price
$321
Updated
2021/12/16
Rieke Metals
Product number
2438
Product name
4-Cyanobutylzincbromide
Packaging
100mL
Price
$499
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0000555
Product name
4-CYANOBUTYLZINC BROMIDE
Purity
95.00%
Packaging
50ML
Price
$850
Updated
2021/12/16
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4-CYANOBUTYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

4-Cyanobutylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.
It can also be used as a reactant to prepare:

  • 5-(3-Thienyl)pentanenitrile by reacting with 3-bromothiophene in the presence of a nickel catalyst.
  • α-Cyanobutyl vinylphosphonates by palladium-catalyzed Negishi coupling vinylation reaction with α-(pseudo)halo vinylphosphonates.

4-CYANOBUTYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CYANOBUTYLZINC BROMIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
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96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
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China
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42982
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Shanghai Aladdin Bio-Chem Technology Co.,LTD
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18521735133 18521732826;
Fax
021-50323701
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market@aladdin-e.com
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China
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
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China
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Infinity SCI
Tel
400-400-1062016 17800804092
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admin@infsci.com
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China
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Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
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China
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Jiaxing Deyi Chemical Co., Ltd.
Tel
86-0573-85866609 13325730825
Fax
0573-85866609
Email
945717149@qq.com
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China
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 13028896684
Email
sales@rrkchem.com
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China
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55827
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Zhengzhou Alfa Chemical Co.,Ltd
Tel
+8618530059196
Email
sale04@alfachem.cn
Country
China
ProdList
12568
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226570-68-9, 4-CYANOBUTYLZINC BROMIDERelated Search:


  • 4-CYANOBUTYLZINC BROMIDE
  • 4-cyanobutylzinc bromide solution
  • 4-CYANOBUTYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN
  • 4-Cyanobutylzinc bromide solution 0.5 in THF
  • 4-Cyanobutylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • 4-Cyanobutylzinc broMide solution 0.5 M in THF
  • 4-Cyanobutylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
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