ChemicalBook > CAS DataBase List > 1-Bromohexadecane

1-Bromohexadecane

Product Name
1-Bromohexadecane
CAS No.
112-82-3
Chemical Name
1-Bromohexadecane
Synonyms
CETYL BROMIDE;1-Bromhexadecan;BROMOHEXADECANE;Hexadecylbromid;Palmitylbromide;1-BROMOHEXADECANE;HEXADECYL BROMIDE;1-bromo-hexadecan;1-HEXADECYL BROMIDE;N-HEXADECYL BROMIDE
CBNumber
CB3211988
Molecular Formula
C16H33Br
Formula Weight
305.34
MOL File
112-82-3.mol
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1-Bromohexadecane Property

Melting point:
16-18 °C(lit.)
Boiling point:
190 °C11 mm Hg(lit.)
Density 
0.999 g/mL at 25 °C(lit.)
vapor density 
10.6 (vs air)
vapor pressure 
<1 mm Hg ( 20 °C)
refractive index 
n20/D 1.4609(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Difficult to mix.
form 
Liquid After Melting
Specific Gravity
1.000 (20/4℃)
color 
Clear amber to brown-black
Water Solubility 
INSOLUBLE
BRN 
773989
Dielectric constant
3.71
Stability:
Stable. Incompatible with strong oxidizing agents. Combustible.
InChIKey
HNTGIJLWHDPAFN-UHFFFAOYSA-N
LogP
8.54
CAS DataBase Reference
112-82-3(CAS DataBase Reference)
NIST Chemistry Reference
Hexadecane, 1-bromo-(112-82-3)
EPA Substance Registry System
Hexadecane, 1-bromo- (112-82-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
TSCA 
Yes
HS Code 
29033036
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
234451
Product name
1-Bromohexadecane
Purity
97%
Packaging
100g
Price
$46.4
Updated
2024/03/01
TCI Chemical
Product number
B0599
Product name
1-Bromohexadecane
Purity
>96.0%(GC)
Packaging
25g
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
B0599
Product name
1-Bromohexadecane
Purity
>96.0%(GC)
Packaging
100g
Price
$34
Updated
2024/03/01
Alfa Aesar
Product number
A15147
Product name
1-Bromohexadecane, 98%
Packaging
25g
Price
$20.65
Updated
2024/03/01
Alfa Aesar
Product number
A15147
Product name
1-Bromohexadecane, 98%
Packaging
250g
Price
$62.2
Updated
2024/03/01
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1-Bromohexadecane Chemical Properties,Usage,Production

Chemical Properties

colourless to yellow liquid or solid.soluble in ether, alcohol, insoluble in water.

Uses

1-Bromohexadecane has been used:
in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains
as extraction solvent in determination of endocrine-disrupting phenols (EDPs) in water samples by ultrasound-assisted emulsification microextraction (MS-USAEME) method
in the preparation of [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents
in the synthesis of surfactant, N-hexadecyl ethylenediamine triacetic acid (HED3A)

Uses

1-Bromohexadecane is used in the preparation of soluble carbon nano-onions by covalent functionalization with hexadecyl chains. It is also used to synthesize [2-(methacryloyloxy)ethyl]dimethylhexadecylammonium bromide monomer, required for the synthesis of novel methacrylate based adsorbents.

Preparation

Synthesis of 1-Bromohexadecane from hexadecanol by bromination: put hexadecanol into the reaction pot and stir, heat, melt and put in red phosphorus. Add bromine drop by drop at 100℃ with sufficient stirring on one side, control 120-130℃, about 6h drop by drop, continue the reaction and drain the hydrogen bromide. Cool to below 50 ℃, add saturated and sodium chloride, stirring and washing, resting stratification, parting off the lower waste stream, then wash with water to neutral, distillation, collect 220-230 ℃ (2kPa) fraction, to obtain 1-bromohexadecane.

Purification Methods

Shake the bromide with H2SO4, wash with H2O, dry with K2CO3 and fractionally distil it in vacuo.[Beilstein 1 IV 542.]

1-Bromohexadecane Preparation Products And Raw materials

Raw materials

1-Hexadecanol Government regulation

Preparation Products

1-HEPTADECANOL Hexadecyl trimethyl ammonium bromide Hexadecyltrimethylammonium hydroxide 1,2-Hexadecanediol AMBRETTOLIDE 1-HEXADECANESULFONIC ACID SODIUM SALT
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1-Bromohexadecane Suppliers

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View Lastest Price from 1-Bromohexadecane manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
1-Bromohexadecane 112-82-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-26
Hebei Zhuanglai Chemical Trading Co Ltd
Product
1-Bromohexadecane 112-82-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-12
Hebei Weibang Biotechnology Co., Ltd
Product
1-Bromohexadecane 112-82-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-07

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