ChemicalBook > CAS DataBase List > (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
Reaction- Product Name
- (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
- CAS No.
- 817176-80-0
- Chemical Name
- (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
- Synonyms
- (S)-Tol-SDP;(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-7,7'-Bis(di-p-tolylphosphanyl)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene];(S)-(1,2',3,3'-Tetrahydro-1,2'-spirobi[indene]-4,7'-diyl)bis(di-p-tolylphosphine);(S)-7,7'-bis[di(4-methylphenyl)phosphanyl]-2,2',3,3'-tetrahydro-1,1'-spirobi[indene;(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)phosphine;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(4-METHYLPHENYL)PHOSPHINE];Phosphine, 1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
- CBNumber
- CB32129579
- Molecular Formula
- C45H42P2
- Formula Weight
- 644.76
- MOL File
- 817176-80-0.mol
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(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Property
- Melting point:
- 150-152°C
- alpha
- -221° (c 0.54, CH2Cl2)
- Boiling point:
- 722.0±60.0 °C(Predicted)
- storage temp.
- -20°C
- form
- solid
- color
- white
- optical activity
- [α]22/D 206°, c = 1 in chloroform
- Sensitive
- air sensitive
- InChIKey
- VLIOMJFCGWZUON-UHFFFAOYSA-N
- SMILES
- Cc1ccc(cc1)P(c2ccc(C)cc2)c3cccc4CCC5(CCc6cccc(P(c7ccc(C)cc7)c8ccc(C)cc8)c56)c34
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Safety
- WGK Germany
- 3
- Storage Class
- 13 - Non Combustible Solids
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 700835
- Product name
- (S)-Tol-SDP
- Packaging
- 50mg
- Price
- $169
- Updated
- 2022/05/15
Strem Chemicals
- Product number
- 15-5181
- Product name
- (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP
- Packaging
- 25mg
- Price
- $76
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-5181
- Product name
- (S)-(-)-7,7'-Bis[di(4-methylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-Tol-SDP
- Packaging
- 100mg
- Price
- $229
- Updated
- 2024/03/01
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(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Chemical Properties,Usage,Production
Reaction
- Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
- Ligands used for palladium-catalyzed asymmetric allylic alkylations.
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Preparation Products And Raw materials
Raw materials
Palladium (II) Acetate
Silica gel
1,4-Bis(diphenylphosphino)butane
Sodium sulfate
Sodium chloride
Toluene
2-Aminoethyldiisopropylamine
Trichlorosilane
Sodium
Trifluoromethanesulfonic anhydride
4-Bromotoluene
Tetrahydrofuran
Ethyl acetate
Diethyl phosphite
Hydrochloric acid
Sodium bicarbonate
Dichloromethane
Dimethyl sulfoxide
Sodium hydroxide
Pyridine
PETROLEUM ETHER
Magnesium
(S)-1,1'-SPIROBIINDANE-7,7'-DIOL
Celite
Preparation Products
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(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% Suppliers
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817176-80-0, (S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%Related Search:
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