11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol
- Product Name
- 11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol
- CAS No.
- 905-37-3
- Chemical Name
- 11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol
- Synonyms
- Krigeine;11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol;9,10-methanediyldioxy-11-methoxy-1-methyl-lycoran-4(12)-ene-5α,7α-diol
- CBNumber
- CB32246821
- Molecular Formula
- C18H21NO6
- Formula Weight
- 347.36244
- MOL File
- 905-37-3.mol
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11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Property
- Melting point:
- 209-210° (dec.).
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11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Chemical Properties,Usage,Production
Description
This alkaloid, which forms colourless crystals from Me2CO, occurs widely among the Amaryllidaceous species. It is dextrorotatory with [α]25D+ 234° (c 0.15, CHCI3). It contains a methylenedioxy groups, a methoxyl, two hydroxyl and a methylimino group in the molecule.
References
Briggs et al., J. Amer. Chem. Soc., 78, 2899 (1956)
Jeffs, Hawksworth., Tetrahedron Lett., 217 (1963)
11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Preparation Products And Raw materials
Raw materials
Preparation Products
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