2-(TRIBUTYLSTANNYL)THIAZOLE

Product Name: 2-(TRIBUTYLSTANNYL)THIAZOLE
CAS No.: 121359-48-6
Chemical Name: 2-(TRIBUTYLSTANNYL)THIAZOLE
Synonyms: TZ-Sn;SKL010;SKL978;2-(Tributyltin)thiazole;2-Tributylstaylthiazole;2-(TRIBUTYLSTANNYL)THIAZOLE;Tributyl-2-thiazolylstannane;2-Tributylstannanyl-thiazole;2-Tributylstannylthiazole 97%;Thiazole,2-(tributylstannyl)-
CBNumber: CB3238857
Molecular Formula: C15H29NSSn
Formula Weight: 374.17
MOL File: 121359-48-6.mol

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2-(TRIBUTYLSTANNYL)THIAZOLE Property

Melting point:: 224-225℃
Boiling point:: 307-309 °C(lit.)
Density: 1.1900 g/mL at 25 °C(lit.)
refractive index: n20/D 1.5200(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,2-8°C
solubility: Not miscible or difficult to mix.
pka: 2.73±0.10(Predicted)
form: liquid
color: Clear, almost colourless
InChI: InChI=1S/3C4H9.C3H2NS.Sn/c3*1-3-4-2;1-2-5-3-4-1;/h3*1,3-4H2,2H3;1-2H;
InChIKey: WUOFQGMXQCSPPV-UHFFFAOYSA-N
SMILES: S1C=CN=C1[Sn](CCCC)(CCCC)CCCC

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Safety

Hazard Codes: T,N,Xi
Risk Statements: 21-25-36/38-48/23/25-50/53
Safety Statements: 35-36/37/39-45-60-61
RIDADR: UN 2788 6.1/PG 2
WGK Germany: 3
HazardClass: IRRITANT, KEEP COLD, TOXIC
HazardClass: 6.1
HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 642541
Product name: 2-Tributylstannylthiazole
Purity: 97%
Packaging: 1g
Price: $111.3
Updated: 2025/07/31

Sigma-Aldrich

Product number: 642541
Product name: 2-Tributylstannylthiazole
Purity: 97%
Packaging: 5g
Price: $551
Updated: 2025/07/31

American Custom Chemicals Corporation

Product number: ING0003426
Product name: 2-(TRIBUTYLSTANNYL)THIAZOLE
Purity: 95.00%
Packaging: 1G
Price: $520
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: T3323
Product name: 2-(Tributylstannyl)thiazole
Purity: >95%
Packaging: 25g
Price: $590
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0003426
Product name: 2-(TRIBUTYLSTANNYL)THIAZOLE
Purity: 95.00%
Packaging: 5G
Price: $800
Updated: 2021/12/16

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2-(TRIBUTYLSTANNYL)THIAZOLE Chemical Properties,Usage,Production

Uses

Reagent for arylation of thiazole by Stille cross-coupling.1

Uses

Used as reagent for arylation of thiazole by Stille cross-coupling.

Synthesis

3034-53-5

1461-22-9

121359-48-6

A hexane solution of n-butyllithium (6.14 mmol, 2.5 M) was slowly added dropwise to a stirred anhydrous ethyl ether solution of 2-bromothiazole (3.07 mmol) at 0 °C under argon protection. After 1 hour of reaction, the mixture was cooled to -78 °C, followed by the slow addition of anhydrous ether solution of tributyltin chloride (3.07 mmol). The mixture was stirred at -78°C overnight. After completion of the reaction, the mixture was poured into water (50 mL) and the aqueous layer was extracted with ether (3 x 30 mL). The organic layers were combined, dried with anhydrous magnesium sulfate, and concentrated under reduced pressure to remove the solvent to give 2-(tri-n-butylmethylstannyl)thiazole (L-01b) as a light brown oil in quantitative yield. The product was used directly for the synthesis of the subsequent compound L-01a without further purification.

References

[1] Patent: US8575355, 2013, B2. Location in patent: Paragraph 0032
[2] Patent: JP2016/56276, 2016, A. Location in patent: Paragraph 0129; 0130
[3] Patent: KR2017/26286, 2017, A. Location in patent: Paragraph 0112-0115
[4] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 76
[5] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 1061-1064

2-(TRIBUTYLSTANNYL)THIAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(TRIBUTYLSTANNYL)THIAZOLE Suppliers

China 94 France 1 Germany 2 India 4 Japan 1 Switzerland 1 United Kingdom 3 United States 17 Global 123

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View Lastest Price from 2-(TRIBUTYLSTANNYL)THIAZOLE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 2-(Tributylstannyl)-1,3-thiazole 121359-48-6
Price: US $1.10-9.90/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-08-14

Sach biotech Co.,Ltd

Product: 2-(TRIBUTYLSTANNYL)THIAZOLE 121359-48-6
Price: US $7142.00-6900.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5mt
Release date: 2025-06-14

Career Henan Chemical Co

Product: 2-(TRIBUTYLSTANNYL)THIAZOLE 121359-48-6
Price: US $2.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: ask
Release date: 2020-01-08

121359-48-6, 2-(TRIBUTYLSTANNYL)THIAZOLERelated Search:

2-(Tributylstannyl)-1,3-thiazole

2-(Tri-n-butylstannyl)thiazole, 96%

2-(TRIBUTYLSTANNYL)THIAZOLE

2-(Tributylstannyl)-1,3-thiazole 95+%

2-Tributylstaylthiazole

(1,3-Thiazol-2-yl)tributylstannane

Thiazole,2-(tributylstannyl)-

2-(Tributyltin)thiazole

Tributyl-2-thiazolylstannane

2-Tributylstannylthiazole 97%

TZ-Sn

2-(tributylstannanyl)-1,3-thiazole

2-Tributylstannanyl-thiazole

tributyl(thiazol-2-yl)stannane

Tributyl(1,3-thiazol-2-yl)stannane

SKL010

SKL978

2-(Tributylstannyl)thiazole - [T2252]

121359-48-6

C15H29NSSn

Organometallic Reagents

Organotins

Organotin

Organometallic Reagents

Organostannes

Thiazole

Tributylstanny

Organometallic Reagents

Organotin

Organotins

Chemical Synthesis