4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER

Product Name: 4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER
CAS No.: 34837-88-2
Chemical Name: 4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER
Synonyms: Methyl 2-(4-methoxy-3-nitrophenyl);Methyl 2-(4-methoxy-3-nitrophenyl)acetate;4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER;BENZENEACETIC ACID, 4-METHOXY-3-NITRO-, METHYL ESTER;2-(4-METHOXY-3-NITRO PHENYL) ACETIC ACID METHYL ETSER
CBNumber: CB32450491
Molecular Formula: C10H11NO5
Formula Weight: 225.2
MOL File: 34837-88-2.mol

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4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER Property

Melting point:: 100-102°
Boiling point:: 356.8±27.0 °C(Predicted)
Density: 1.264±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: White to off-white Solid

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Matrix Scientific

Product number: 046101
Product name: Methyl 2-(4-methoxy-3-nitrophenyl)acetate
Purity: >95%
Packaging: 5g
Price: $497
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0090635
Product name: METHYL 2-(4-METHOXY-3-NITROPHENYL)ACETATE
Purity: 95.00%
Packaging: 500MG
Price: $683.53
Updated: 2021/12/16

AK Scientific

Product number: 1086AE
Product name: Methyl2-(4-methoxy-3-nitrophenyl)acetate
Packaging: 5g
Price: $720
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0090635
Product name: METHYL 2-(4-METHOXY-3-NITROPHENYL)ACETATE
Purity: 95.00%
Packaging: 1G
Price: $722.8
Updated: 2021/12/16

Matrix Scientific

Product number: 046101
Product name: Methyl 2-(4-methoxy-3-nitrophenyl)acetate
Purity: >95%
Packaging: 500mg
Price: $120
Updated: 2021/12/16

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4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

61873-93-6

74-88-4

34837-88-2

General procedure for the synthesis of methyl 2-(4-methoxy-3-nitrophenyl)acetate from methyl 2-(4-hydroxy-3-nitrophenyl)acetate and iodomethane: To a solution of methyl 2-(4-hydroxy-3-nitrophenyl)acetate (4.87 g, 23.1 mmol) was added K2CO3 (8 g, 58 mmol) at room temperature, followed by slow addition of CH3I ( 6.6 g, 46.5 mmol). The reaction mixture was stirred at room temperature overnight. After the reaction was completed, the mixture was poured into ice water (100 mL) and extracted with CH2Cl2 (3 x 300 mL). The organic layers were combined, washed with brine, dried over Na2SO4, filtered and concentrated to give methyl 2-(4-methoxy-3-nitrophenyl)acetate (5 g, 96% yield) as a yellow solid.LCMS analysis showed an [M + H]+ of 226.0; retention time (Rt) of 1.438 min.

References

[1] Patent: WO2013/19682, 2013, A1. Location in patent: Page/Page column 106; 107

4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER Suppliers

China 21 India 2 United States 3 Global 26

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34837-88-2, 4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTERRelated Search:

4-HYDROXY-3-NITROPHENYLACETIC ACID 4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER (4-METHOXY-3-NITROPHENYL)ACETIC ACID (3-NITROPHENYL)ACETIC ACID METHYL ESTER Methyl (4-Hydroxy-3-nitrophenyl)acetate methyl 2-(3-amino-4-hydroxyphenyl)acetate

4-METHOXY-3-NITRO-BENZENEACETIC ACID METHYL ESTER

BENZENEACETIC ACID, 4-METHOXY-3-NITRO-, METHYL ESTER

Methyl 2-(4-methoxy-3-nitrophenyl)acetate

Methyl 2-(4-methoxy-3-nitrophenyl)

2-(4-METHOXY-3-NITRO PHENYL) ACETIC ACID METHYL ETSER

34837-88-2