ChemicalBook > CAS DataBase List > 2-AMINO-3-CYANOTOLUENE

2-AMINO-3-CYANOTOLUENE

Application

Product Name: 2-AMINO-3-CYANOTOLUENE
CAS No.: 69797-49-5
Chemical Name: 2-AMINO-3-CYANOTOLUENE
Synonyms: 2-AMINO-3-CYANOTOLUENE;2-Cyano-6-methylaniline;3-methyl-2-Amino-benzonitrile;2-AMINO-3-METHYL-BENZONITRILE;Benzonitrile, 2-aMino-3-Methyl-
CBNumber: CB32452268
Molecular Formula: C8H8N2
Formula Weight: 132.16
MOL File: 69797-49-5.mol

Less

2-AMINO-3-CYANOTOLUENE Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Appearance: Light yellow to brown Solid

Less

Safety

HS Code: 2926907090

Less

Hazard and Precautionary Statements (GHS)

Less

N-Bromosuccinimide Price

TRC

Product number: A898580
Product name: 2-Amino-3-methylbenzonitrile
Packaging: 2.5g
Price: $155
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA140141
Product name: 2-Amino-3-methylbenzonitrile
Packaging: 5G
Price: $160
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA140141
Product name: 2-Amino-3-methylbenzonitrile
Packaging: 2g
Price: $80
Updated: 2021/12/16

AK Scientific

Product number: W7951
Product name: 2-Amino-3-methylbenzonitrile
Packaging: 1g
Price: $97
Updated: 2021/12/16

Matrix Scientific

Product number: 119558
Product name: 2-Amino-3-methylbenzonitrile
Purity: 95+%
Packaging: 1g
Price: $144
Updated: 2021/12/16

Less

2-AMINO-3-CYANOTOLUENE Chemical Properties,Usage,Production

Application

3-Amino-2-methylbenzonitrile is an aniline heterocyclic compound mainly used in laboratory organic synthesis processes.

Synthesis

53848-17-2

544-92-3

69797-49-5

The general procedure for the synthesis of 2-amino-3-methylbenzonitrile from 2-bromo-6-methylaniline and cuprous cyanide was as follows: cuprous cyanide (CuCN, 197 mg, 2.2 mmol) was added to an anhydrous N-methylpyrrolidone (NMP, 3 mL) solution of 2-bromo-6-methylaniline (126 μL, 1 mmol). The reaction mixture was placed in a microwave reactor and irradiated at 220 °C for 40 min. Upon completion of the reaction, the mixture was cooled to room temperature and poured into a mixture consisting of ammonia (50% w/v, 10 mL) and ice. Subsequently, the mixture was stirred for 30 min and the target product was extracted with dichloromethane (3 x 20 mL). The organic layers were combined, washed sequentially with water and saturated saline, dried with anhydrous magnesium sulfate (MgSO4), and then concentrated. The crude product was purified by silica gel column chromatography (eluent: 50% ethyl acetate/hexane) to give a brown oil, which was crystallized after standing (128 mg, 96% yield). The structure of the product was confirmed by 1H NMR (400 MHz, DMSO-d6) and mass spectrometry (MS): 1H NMR δ 2.08 (s, 3H), 5.68 (bs, 2H), 6.51-6.55 (t, 1H), 7.17-7.19 (d, 1H), 7.22-7.24 (dd, 1H); MS m/z 133 ([M+H ]+).

References

[1] Patent: US2008/306053, 2008, A1. Location in patent: Page/Page column 60

2-AMINO-3-CYANOTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

2-AMINO-3-CYANOTOLUENE Suppliers

China 63 India 1 United Kingdom 2 United States 5 Global 71

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Suzhou Guide Fine Material Co.Ltd.

Tel: 0512-66627360 13914021065
Fax: 0512-66627360
Email: 706938434@qq.com
Country: China
ProdList: 237
Advantage: 60

Candia Thamtech Company Limited

Tel: 0371-86615086 18203638366 0371-86159066 13526786601
Fax: 0371-86159066
Country: China
ProdList: 2015
Advantage: 60

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 18209
Advantage: 56

SynAsst Chemical.

Tel: 021-60343070
Fax: 021-35122006
Country: China
ProdList: 12740
Advantage: 55

Jalor-Chem co.,LTD

Tel: 0510-0510-86396359 13382276200
Email: sales@jalor-chem.com
Country: China
ProdList: 997
Advantage: 56

Shanghai Xingui Biotechnology Co., Ltd.

Tel: 15121041756
Email: xingui2022@126.com
Country: China
ProdList: 9976
Advantage: 58

ShangHai AmK Pharmaceutical Technology Co., Ltd.

Tel: 微信 17321281695 18019252918
Fax: 17321281695
Email: sale@amkchem.com
Country: China
ProdList: 15136
Advantage: 55

Tianjin Anhao Biological Technology Co., Ltd.

Tel
Email: sales@ahpharmatech.com
Country: China
ProdList: 5734
Advantage: 55

Hangzhou J&H Chemical Co., Ltd.

Tel: 0571-87396432
Fax: 0571-87396431
Email: sales@jhechem.com
Country: China
ProdList: 14912
Advantage: 59

Hangzhou Milestone Pharmtech Co., Ltd.

Tel: 0571-82896630 18969958410
Email: sales_hz@milestonepharmtech.com
Country: China
ProdList: 4894
Advantage: 55

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

skychemical Co.Ltd

Tel: 021-20960837,QQ1332204249
Fax: 021-20960837
Email: sales@skychemical.com
Country: China
ProdList: 3341
Advantage: 55

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Nanjing KaiMubo Pharmaceutical Co., Ltd.

Tel: 025-66162170
Fax: 025-66162170
Country: China
ProdList: 7181
Advantage: 55

Yantai ShengKailun Chemical Technology Co., Ltd.

Tel: 13356901049
Fax: QQ：1025383091
Email: 3119594100@qq.com
Country: China
ProdList: 7964
Advantage: 55

Hangzhou Molcore Biopharmatech Co.,Ltd

Tel: 400-711-5280 86-571-81025280
Fax: 86-571-85806285
Email: sales@molcore.com
Country: China
ProdList: 9967
Advantage: 58

Sichuan BaiPeng Biotechnology Co., Ltd.

Tel: 028-65791793 18140026355
Fax: QQ568470422
Email: 568470422@qq.com
Country: China
ProdList: 9997
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: +86-（0）57185586718; +8613336195806
Fax: +86-571-85864795
Email: sales@capot.com
Country: China
ProdList: 29735
Advantage: 60

Aikon International Limited

Tel: 025-58859352 18068836627
Fax: 02557626880
Email: sales01@aikonchem.com
Country: China
ProdList: 15083
Advantage: 58

SHANGHAI FDC-CHEMICAL CO.,LTD

Tel: 021-61469567 13482353728
Fax: 021-61161605
Email: sales@fdc-chemical.com
Country: China
ProdList: 9717
Advantage: 58

Cool Pharm, Ltd

Tel: 021-58581007 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12878
Advantage: 58

Shanghai FWD Chemicals Limited

Tel: 021-54450827 021-54450828
Email: sales@fwdchem.com
Country: China
ProdList: 997
Advantage: 58

Xinyi Kangda Biological Technology Co., Ltd.

Tel: 13013943931 15152133928
Email: xinyikangda@163.com
Country: China
ProdList: 610
Advantage: 58

Xinyi Kaiwu Chemical Technology Co., Ltd.

Tel: 0516-0516-88997009 18651776937
Email: 4164357@qq.com
Country: China
ProdList: 3204
Advantage: 58

CR Corporation Limited

Tel: +8613062833949
Email: fred.wen@crcorporation.cn
Country: China
ProdList: 8645
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: +86-0551-65418684 +8618949823763
Fax: 0086-551-65418684
Email: sales@tnjchem.com
Country: China
ProdList: 25356
Advantage: 58

CD Chemical Group Limited

Tel: +8615986615575
Fax: 0086-13651442114
Email: info@codchem.com
Country: China
ProdList: 20342
Advantage: 58

Win-Win chemical CO., Limited

Tel: +86-0086-577-64498589 +86-15355981851
Fax: 0086-577-56994596
Email: sales@win-winchemical.com
Country: China
ProdList: 14359
Advantage: 58

Career Henan Chemica Co

Tel: +86-0371-86658258 +8613203830695
Fax: 0371-86658258
Email: laboratory@coreychem.com
Country: China
ProdList: 30229
Advantage: 58

Xinyi Huaju Pharmaceutical Technology Co., Ltd.

Tel: 13761372795
Email: huajupharm@163.com
Country: China
ProdList: 806
Advantage: 58

Fuxin Pharmaceutical

Tel: +86-021-021-50872116 +8613122107989
Email: contact@fuxinpharm.com
Country: China
ProdList: 10000
Advantage: 58

Guangzhou Yuheng Pharmaceutical Technology Co., Ltd

Tel: +8613580539051
Email: joe@yuhengpharm.com
Country: CHINA
ProdList: 21142
Advantage: 58

Changzhou Kechem Bio-Scientific Co., LTD.

Tel: 0519-68985668 13685222090
Fax: qq735434464
Email: sales@kechem.cn
Country: China
ProdList: 26028
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Hubei Co-prosperity Medicine Technonlogy Co., Ltd

Tel: 2383948258 19172820304
Email: 2383948258@qq.com
Country: China
ProdList: 12987
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29757
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

WUHAN JIXINYIBANG BIOTECHNOLOGY .,LTD

Tel: 027-59768661 13297943853
Email: 1704244976@qq.com
Country: China
ProdList: 4988
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-1647117 13681763483
Email: product02@bidepharm.com
Country: China
ProdList: 59936
Advantage: 58

Qi Qi hang Biotechnology Co., Ltd.

Tel: 15870833005
Email: 2232044025@qq.com
Country: China
ProdList: 8206
Advantage: 58

LinkChem Technology Co., Ltd.

Tel: +86(21)5895 0110 13124863828
Email: sales@linkchem.cn
Country: China
ProdList: 2999
Advantage: 58

Jiangsu Runfeng Synthetic Technology Co., Ltd.

Tel: 0513-66017678 18551497631
Email: 507167383@qq.com
Country: China
ProdList: 4991
Advantage: 58

Tianjin shanhaijing medicine technology co., ltd

Tel: 19129375004 15321929114
Email: yangtzechem@163.com
Country: China
ProdList: 497
Advantage: 58

Henan Alpha Chemical Co., Ltd.

Tel: 0371-55013243 15324716602
Email: 2853979810@qq.com
Country: China
ProdList: 9898
Advantage: 58

Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-021-50706066 15221275939
Email: shenlinxing@macklin.cn
Country: China
ProdList: 29784
Advantage: 58

Pushan Industry (Shaanxi) Co., Ltd.

Tel: 029-81310890 13571859809
Email: info@pushanshiye.com
Country: China
ProdList: 9955
Advantage: 58

69797-49-5, 2-AMINO-3-CYANOTOLUENERelated Search:

Disperse Blue 165 7-CYANOOXINDOLE 1,4-DIAMINO-2,3-DICYANO-9,10-ANTHRAQUINONE 2-AMINOISOPHTHALONITRILE 2-NITROISOPHTHALONITRILE 7-indolinecarbonitrile 2-[[4-(diethylamino)-2-methylphenyl]azo]-5-methylbenzene-1,3-dicarbonitrile 5'-AMINO-4''-BROMO-3-NITRO-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE 1-(2,6-DICYANOPHENYL)-4-PIPERIDINECARBOXAMIDE 5'-AMINO-3,4-DIMETHOXY-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE N-(2,4-DICYANO-6-METHYLPHENYL)ACETAMIDE 5'-AMINO-4-BROMO-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE 5'-AMINO-4''-BROMO-3,4-DIMETHOXY-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE ETHYL 4-AMINO-5-CYANO-2-HYDROXY-3-METHYLBENZOATE 2-MORPHOLINOISOPHTHALONITRILE 5'-AMINO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE 5'-AMINO-3-NITRO-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE 5'-AMINO-4''-CHLORO-4-METHYL-[1,1':3',1'']TERPHENYL-4',6'-DICARBONITRILE

2-AMINO-3-CYANOTOLUENE

2-AMINO-3-METHYL-BENZONITRILE

Benzonitrile, 2-aMino-3-Methyl-

2-Cyano-6-methylaniline

3-methyl-2-Amino-benzonitrile

69797-49-5