ChemicalBook > CAS DataBase List > 5-Bromo-2-chlorobenzyl amine

5-Bromo-2-chlorobenzyl amine

Product Name: 5-Bromo-2-chlorobenzyl amine
CAS No.: 1096296-85-3
Chemical Name: 5-Bromo-2-chlorobenzyl amine
Synonyms: (5-Bromo-2-chlorophenyl);5-Bromo-2-chlorobenzyl amine;(5-BroMo-2-chlorophenyl)MethanaMine;BenzeneMethanaMine, 5-broMo-2-chloro-;(5-Bromo-2-chlorophenyl)methanamine - [B90087]
CBNumber: CB32490837
Molecular Formula: C7H7BrClN
Formula Weight: 220.49
MOL File: 1096296-85-3.mol

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5-Bromo-2-chlorobenzyl amine Property

storage temp.: 2-8°C(protect from light)
form: solid
Appearance: Colorless to light yellow Liquid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B699868
Product name: (5-Bromo-2-chlorophenyl)methanamine
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 074595
Product name: 5-Bromo-2-chlorobenzylamine
Purity: 95+%
Packaging: 1g
Price: $347
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0366822
Product name: 5-BROMO-2-CHLOROBENZYLAMINE
Purity: 95.00%
Packaging: 5MG
Price: $503.04
Updated: 2021/12/16

AK Scientific

Product number: X8926
Product name: 5-Bromo-2-chlorobenzylamine
Packaging: 25g
Price: $851
Updated: 2021/12/16

Matrix Scientific

Product number: 074595
Product name: 5-Bromo-2-chlorobenzylamine
Purity: 95+%
Packaging: 5g
Price: $899
Updated: 2021/12/16

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5-Bromo-2-chlorobenzyl amine Chemical Properties,Usage,Production

Synthesis

478374-91-3

1096296-85-3

The synthesis of 5-bromo-2-chlorobenzylamine (3) as the target was carried out as follows: azide 2 (2.4 g, 9.76 mmol) was dissolved in THF (60 mL) at 0 °C, and triphenylphosphine (2.86 g, 10.90 mmol, 1.12 eq.) was slowly added while stirring. After addition, the mixture was continued to stir at 0 °C for 10 min, followed by overnight stirring at room temperature. Complete consumption of the raw material was confirmed by TLC analysis (unfolding agent: EtOAc-hexane, 1:20). Subsequently, ammonium hydroxide solution (10 mL) was added drop-wise and after stirring for 30 minutes, 1N NaOH solution (20 mL) was added and the resulting mixture was continued to be stirred for 2 hours at room temperature. After the reaction was completed, it was diluted by adding ether (100 mL) and water (80 mL). The mixture was adjusted to acidity (pH 2) by slowly adding 4N H2SO4 solution dropwise. The aqueous layer was separated and adjusted to basicity with 4N NaOH solution, followed by extraction with DCM (2 x 100mL). The organic layers were combined, dried with MgSO4 and concentrated under reduced pressure. The residue was purified by column chromatography (eluent: MeOH-DCM, 1:20) to afford the target product 3 as a colorless liquid (1.45 g, 67% yield). The product was analyzed by LC-MS showing: retention time (R t) 3.67 min, mass-to-charge ratio (m/e) 221.1,205.1; 1H NMR (CDCl3) δ 7.64 (s, 1H), 7.40 (dd, 1H), 7.28 (d, 1H), 4.02 (s, 2H), 1.58 (s, broad peak, 2H, NH2).

References

[1] Patent: WO2009/62059, 2009, A2. Location in patent: Page/Page column 39-40

5-Bromo-2-chlorobenzyl amine Preparation Products And Raw materials

Raw materials

Preparation Products

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1096296-85-3, 5-Bromo-2-chlorobenzyl amineRelated Search:

5-Bromo-2-chlorobenzyl amine

(5-BroMo-2-chlorophenyl)MethanaMine

(5-Bromo-2-chlorophenyl)

BenzeneMethanaMine, 5-broMo-2-chloro-

(5-Bromo-2-chlorophenyl)methanamine - [B90087]

1096296-85-3