1-Methylcyclobutanecarboxylic acid
- Product Name
- 1-Methylcyclobutanecarboxylic acid
- CAS No.
- 32936-76-8
- Chemical Name
- 1-Methylcyclobutanecarboxylic acid
- Synonyms
- 1-Methylcyclobutanecarboxylic acid;Cyclobutanecarboxylic acid, 1-methyl-;1-methyl-1-cyclobutanecarboxylic acid;1-Methylcyclobutane-1-carboxylic acid
- CBNumber
- CB32500642
- Molecular Formula
- C6H10O2
- Formula Weight
- 114.14
- MOL File
- 32936-76-8.mol
1-Methylcyclobutanecarboxylic acid Property
- Boiling point:
- 203℃
- Density
- 1.122
- Flash point:
- 92℃
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 5.00±0.20(Predicted)
- form
- liquid
- color
- Colourless
- InChI
- InChI=1S/C6H10O2/c1-6(5(7)8)3-2-4-6/h2-4H2,1H3,(H,7,8)
- InChIKey
- GCZGQVRHZLOCDD-UHFFFAOYSA-N
- SMILES
- C1(C)(C(O)=O)CCC1
Safety
- RIDADR
- 3265
- HazardClass
- 8
- PackingGroup
- Ⅲ
- HS Code
- 2916200090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
N-Bromosuccinimide Price
- Product number
- M338323
- Product name
- 1-MethylcyclobutanecarboxylicAcid
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 113255
- Product name
- 1-Methylcyclobutanecarboxylic acid
- Packaging
- 1g
- Price
- $284
- Updated
- 2021/12/16
- Product number
- OR317127
- Product name
- 1-Methylcyclobutane-1-carboxylicacid
- Packaging
- 1g
- Price
- $166
- Updated
- 2021/12/16
- Product number
- 2221-1-25
- Product name
- 1-Methylcyclobutanecarboxylic acid
- Packaging
- 1g
- Price
- $183
- Updated
- 2021/12/16
- Product number
- OR317127
- Product name
- 1-Methylcyclobutane-1-carboxylicacid
- Packaging
- 5g
- Price
- $493
- Updated
- 2021/12/16
1-Methylcyclobutanecarboxylic acid Chemical Properties,Usage,Production
Uses
1-Methylcyclobutanecarboxylic Acid is used for acid chlorination.
Synthesis
3721-95-7
74-88-4
32936-76-8
Example B19: Diisopropylamine (17 mL, 121 mmol) was dissolved in THF (50 mL) at 0 °C, n-butyllithium (2.5 M hexane solution, 48 mL, 120 mmol) was slowly added and the reaction was stirred for 10 minutes. Subsequently, cyclobutanecarboxylic acid (5.00 g, 49.9 mmol) was added and stirring was continued for 0.5 hours. Next, methyl iodide (9.00 g, 63.4 mmol) was added dropwise to the reaction mixture and the mixture was stirred at room temperature for 3 hours. After completion of the reaction, the mixture was concentrated to dryness. The residue was treated with saturated NaHCO3 solution and then extracted with DCM (2×). The organic phases were combined, washed with brine, dried over anhydrous Na2SO4 and concentrated to dryness to afford 1-methylcyclobutanecarboxylic acid (3.54 g, 62% yield) as a brown oil.
References
[1] Chemical Communications, 2006, # 39, p. 4107 - 4109
[2] Patent: US2014/275080, 2014, A1. Location in patent: Paragraph 0.384
[3] Journal of Organic Chemistry, 1982, vol. 47, # 17, p. 3242 - 3247
[4] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980, p. 1083 - 1092
[5] Patent: WO2009/98283, 2009, A1. Location in patent: Page/Page column 120-121
1-Methylcyclobutanecarboxylic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-Methylcyclobutanecarboxylic acid manufacturers
- Product
- 1-Methylcyclobutanecarboxylic acid 32936-76-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-14
- Product
- 1-Methylcyclobutanecarboxylic acid 32936-76-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-02