2-(Benzyloxy)-4-bromopyridine
- Product Name
- 2-(Benzyloxy)-4-bromopyridine
- CAS No.
- 960298-00-4
- Chemical Name
- 2-(Benzyloxy)-4-bromopyridine
- Synonyms
- 4-Bromo-2-benzyloxypyridine;2-(Benzyloxy)-4-bromopyridine;4-bromo-2-phenylmethoxypyridine;Pyridine, 4-bromo-2-(phenylmethoxy)-
- CBNumber
- CB32513015
- Molecular Formula
- C12H10BrNO
- Formula Weight
- 264.12
- MOL File
- 960298-00-4.mol
2-(Benzyloxy)-4-bromopyridine Property
- storage temp.
- Inert atmosphere,2-8°C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B291533
- Product name
- 2-(Benzyloxy)-4-bromopyridine
- Packaging
- 100mg
- Price
- $100
- Updated
- 2021/12/16
- Product number
- B291533
- Product name
- 2-(Benzyloxy)-4-bromopyridine
- Packaging
- 250mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- B291533
- Product name
- 2-(Benzyloxy)-4-bromopyridine
- Packaging
- 1g
- Price
- $550
- Updated
- 2021/12/16
- Product number
- FB153856
- Product name
- 2-(Benzyloxy)-4-bromopyridine
- Packaging
- 2g
- Price
- $690
- Updated
- 2021/12/16
- Product number
- V9866
- Product name
- 2-(Benzyloxy)-4-bromopyridine
- Packaging
- 5g
- Price
- $904
- Updated
- 2021/12/16
2-(Benzyloxy)-4-bromopyridine Chemical Properties,Usage,Production
Synthesis
128071-98-7
100-51-6
960298-00-4
4-Bromo-2-fluoropyridine (5.28 g, 30 mmol) and benzyl alcohol (3.24 g, 30.00 mmol) were dissolved in anhydrous tetrahydrofuran (THF, 50 mL) under argon protection. The reaction system was cooled to 0 °C in an ice-water bath. Potassium tert-butoxide (3.37 g, 30.00 mmol) was added slowly over 20 min with vigorous stirring, approximately 100 mg at a time. after addition, the reaction was continued at 0 °C for 60 min with stirring. Subsequently, the ice water bath was removed and the reaction mixture was warmed to room temperature and stirring was continued for 30 min. Upon completion of the reaction, water (5 mL) was added to the mixture and most of the THF was evaporated under reduced pressure. the residue was extracted by partitioning with pentane (75 mL) and water (50 mL). The organic phase was separated, washed with water (2 x 25 mL) and dried over anhydrous magnesium sulfate (MgSO4). The solvent was removed by concentration under reduced pressure to give the title compound 2-(benzyloxy)-4-bromopyridine 7.86 g in 99% yield. The product was characterized by 1H NMR (500 MHz, DMSO-d6): δ 8.10 (d, 1H), 7.44 (d, 2H), 7.38 (t, 2H), 7.33 (t, 1H), 7.25 (d, 1H), 7.20 (s, 1H), 5.36 (s, 2H).
References
[1] Patent: WO2011/2409, 2011, A1. Location in patent: Page/Page column 37
[2] Patent: WO2010/66028, 2010, A1. Location in patent: Page/Page column 28-29
[3] Patent: WO2009/135299, 2009, A1. Location in patent: Page/Page column 108
2-(Benzyloxy)-4-bromopyridine Preparation Products And Raw materials
Raw materials
Preparation Products
2-(Benzyloxy)-4-bromopyridine Suppliers
- Tel
- 0535-6385396
- Fax
- +86 (535) 638-9971
- info@carbottpharm.com
- Country
- China
- ProdList
- 957
- Advantage
- 56
- Tel
- 13526569071
- sales@leadmedpharm.com
- Country
- China
- ProdList
- 7892
- Advantage
- 64
- Tel
- 025-66113011 17798518460
- Fax
- (1)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 19913
- Advantage
- 55
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 18209
- Advantage
- 56
- Tel
- 400-8592883
- Fax
- 0731-82251112
- sales@huatengsci.com
- Country
- China
- ProdList
- 5872
- Advantage
- 58
- Tel
- 021-60345187 13671753212
- Fax
- 021-34702061
- lzz841106@aliyun.com
- Country
- China
- ProdList
- 10263
- Advantage
- 55
- Tel
- 025-66028182 18626450290
- yftan@aikonchem.com
- Country
- China
- ProdList
- 16679
- Advantage
- 50
- Tel
- 86(21)68097365
- Fax
- 86(21)33321566
- sales@anpharma.net
- Country
- China
- ProdList
- 4891
- Advantage
- 55
- Tel
- 021-64340559 13651849907;
- Fax
- 021- 64345308
- xinyu_shi@jwypharmlab.com.cn
- Country
- China
- ProdList
- 12000
- Advantage
- 58
- Tel
- 13812573443
- Fax
- -
- tongbenwan22@163.com
- Country
- China
- ProdList
- 1980
- Advantage
- 55
- Tel
- 0371-53778726 18003825608
- Fax
- QQ：2885354392
- liuxiaoyan@alfachem.cn
- Country
- China
- ProdList
- 1986
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 028-65791793 18140026355
- Fax
- QQ568470422
- 568470422@qq.com
- Country
- China
- ProdList
- 9997
- Advantage
- 58
- Tel
- 022-59987777 13552403979
- jia_guoqiang@wuxiapptec.com
- Country
- China
- ProdList
- 22345
- Advantage
- 58
- Tel
- 13918479294
- Fax
- -
- xiebenfa@163.com
- Country
- China
- ProdList
- 4090
- Advantage
- 58
- Tel
- 4009004166/18616739031 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52687
- Advantage
- 58
- Tel
- 025-58859352 13155353615
- qzhang@aikonchem.com
- Country
- China
- ProdList
- 15525
- Advantage
- 58
- Tel
- +1-2135480471
- sales@sarms4muscle.com
- Country
- China
- ProdList
- 10473
- Advantage
- 58
- Tel
- 0086-19817745290; +8619817745290
- bd@blocksynth.com
- Country
- China
- ProdList
- 5661
- Advantage
- 58
- Tel
- 13674959855 13674959855
- sales@synthontech.com
- Country
- China
- ProdList
- 3035
- Advantage
- 58
- Tel
- +86-023-6139-8061 +86-86-13650506873
- sales@chemdad.com
- Country
- China
- ProdList
- 39927
- Advantage
- 58
- Tel
- 0519-68985668 13685222090
- Fax
- qq735434464
- sales@kechem.cn
- Country
- China
- ProdList
- 26028
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing@energy-chemical.com
- Country
- China
- ProdList
- 44918
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39653
- Advantage
- 58
- Tel
- 029-81310890 13571859809
- info@pushanshiye.com
- Country
- China
- ProdList
- 9955
- Advantage
- 58
- Tel
- 1173954148q
- meishipharma@126.com
- Country
- China
- ProdList
- 20033
- Advantage
- 58
- Tel
- 0573-85866609 13588473046
- 824930988@qq.com
- Country
- China
- ProdList
- 7865
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 40000
- Advantage
- 58
- Tel
- 029-029-81123119 17391733320
- 1021@dideu.com
- Country
- China
- ProdList
- 9995
- Advantage
- 58
- Tel
- 15021035486 18081542813
- 1804873256@qq.com
- Country
- China
- ProdList
- 6684
- Advantage
- 58
- Tel
- 18455579438
- Country
- China
- ProdList
- 16684
- Advantage
- 58
- Tel
- 400-0628126 15697565236;
- sales-team@aobchem.com.cn
- Country
- China
- ProdList
- 50000
- Advantage
- 58
- Tel
- 021-54306202 18917919676
- info@hanhongsci.com
- Country
- China
- ProdList
- 29995
- Advantage
- 58
- Tel
- 13626726938
- Country
- China
- ProdList
- 3879
- Advantage
- 58
- Tel
- 19817745290
- bd@blocksynth.com
- Country
- China
- ProdList
- 5869
- Advantage
- 58
- Tel
- 021-34045219 13062664914
- huji@zunlijia.com
- Country
- China
- ProdList
- 10027
- Advantage
- 58
- Tel
- 25-57027686 17372956142
- li_lan@syntitan.com
- Country
- China
- ProdList
- 5807
- Advantage
- 58
- Tel
- 19916715086
- qingqing.wang@atntlife.com
- Country
- China
- ProdList
- 37
- Advantage
- 58
- Tel
- 13626726938
- 15952452933@163.cn
- Country
- China
- ProdList
- 4109
- Advantage
- 58
- Tel
- 02152215958
- 47697177@qq.com
- Country
- China
- ProdList
- 10011
- Advantage
- 58
- Tel
- 18117455885
- qihongchem@163.com
- Country
- China
- ProdList
- 9092
- Advantage
- 58
- Tel
- 0938-0938-8493022 1685585981;15379872136
- xiaoshi079@163.com
- Country
- China
- ProdList
- 2018
- Advantage
- 58
- Tel
- +undefined18143011203
- info@chemextension.com
- Country
- China
- ProdList
- 42056
- Advantage
- 58
- Tel
- +86-057181025280; +8617767106207
- Fax
- 0571-85806285
- sales@molcore.com
- Country
- China
- ProdList
- 49734
- Advantage
- 58
- Tel
- --
- Fax
- --
- chenjw@absin.cn
- Country
- CHINA
- ProdList
- 6208
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@zzsrm.com
- Country
- CHINA
- ProdList
- 6650
- Advantage
- 58
- Tel
- --
- Fax
- --
- Country
- CHINA
- ProdList
- 6333
- Advantage
- 58
- Tel
- --
- Fax
- --
- 15810802415@139.com
- Country
- CHINA
- ProdList
- 6750
- Advantage
- 58
- Tel
- --
- Fax
- --
- 3245176082@qq.com
- Country
- CHINA
- ProdList
- 6800
- Advantage
- 58
- Tel
- --
- Fax
- --
- 15821073967@163.com
- Country
- CHINA
- ProdList
- 6748
- Advantage
- 58