3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate

Product Name: 3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate
CAS No.: 693774-10-6
Chemical Name: 3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate
Synonyms: 2,6-DiMethylpyridine-3-boronic acid pinacol ester;(2,6-Dimethylpyridin-3-yl)methanediol pinacol ester;(2,6-Dimethy|pyridin -3- y|)methanedio| pinaco| ester;2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl);Pyridine, 2,6-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxabor...;2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine;Pyridine, 2,6-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-;3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate
CBNumber: CB32549955
Molecular Formula: C13H20BNO2
Formula Weight: 233.11
MOL File: 693774-10-6.mol

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3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light brown to brown Liquid

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Safety

HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: D479818
Product name: 2,6-Dimethylpyridine-3-boronicacidpinacolester
Packaging: 25mg
Price: $50
Updated: 2021/12/16

AK Scientific

Product number: 0708AC
Product name: 2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Packaging: 250mg
Price: $262
Updated: 2021/12/16

Matrix Scientific

Product number: 096451
Product name: 2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Purity: 95+%
Packaging: 250mg
Price: $394
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0006276
Product name: 2,6-DIMETHYL-3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRIDINE
Purity: 95.00%
Packaging: 5MG
Price: $499.49
Updated: 2021/12/16

Matrix Scientific

Product number: 096451
Product name: 2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
Purity: 95+%
Packaging: 1g
Price: $874
Updated: 2021/12/16

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3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate Chemical Properties,Usage,Production

Synthesis

61676-62-8

693774-10-6

Example 2A Synthesis of 2,6-dimethyl-3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine: 3-bromo-2,6-dimethylpyridine (5.10 g, 27.4 mmol) was dissolved in anhydrous ethyl ether (160 mL) under nitrogen protection and cooled to -78°C. Dropwise n-butyllithium (4.1 mL, 10 M hexane solution) was added and stirred at -78 °C for 45 min. Subsequently, an ether solution (20 mL) of 2-isopropoxy-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (10.2 g, 54.8 mmol) was added slowly and dropwise at the same temperature and stirring was continued for 3 hours at -78 °C. Upon completion of the reaction, the reaction was quenched with isopropanol (10 mL) and slowly warmed to room temperature. Saturated aqueous sodium chloride solution (150 mL) was added, and the aqueous phase was separated and extracted with dichloromethane (100 mL x 6) several times. The organic phases were combined, dried and concentrated to give 2,6-dimethylpyridine-3-boronic acid pinacol ester as a light brown oil (6.29 g, 98.4% yield). The product was confirmed by 1H NMR (300 MHz, CDCl3): δ 7.92 (d, J = 7.46 Hz, 1H), 6.96 (d, J = 7.80 Hz, 1H), 2.73 (s, 3H), 2.53 (s, 3H), 1.34 (s, 12H). Mass spectral analysis showed (M + H)+ = 234.

References

[1] Patent: US2007/66588, 2007, A1. Location in patent: Page/Page column 29-30

3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate Preparation Products And Raw materials

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3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate Suppliers

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View Lastest Price from 3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 693774-10-6
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 1000kg
Release date: 2025-06-13

Zhengzhou HQ Material CO.,LTD.

Product: 2,6-diMethyl-3-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)pyridine 693774-10-6
Price: US $0.00-0.00/Kg/Drum
Min. Order: 100g
Purity: 99%
Supply Ability: 100kg
Release date: 2021-09-23

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate 693774-10-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

693774-10-6, 3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronateRelated Search:

2,5-DIBROMOPYRIDINE-3-BORONIC ACID PINACOL ESTER 2,6-DICHLOROPYRIDINE-3-BORONIC ACID PINACOL ESTER 2,5-DiMethylpyridine-3-boronic acid pinacol ester 2,6-DIFLUORO-3-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE 2,5-DICHLORO-3-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE

3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate

2,6-DiMethylpyridine-3-boronic acid pinacol ester

2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine

2,6-Dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)

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Pyridine, 2,6-dimethyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxabor...

(2,6-Dimethylpyridin-3-yl)methanediol pinacol ester

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693774-10-6