N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester
- Product Name
- N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester
- CAS No.
- 220364-34-1
- Chemical Name
- N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester
- Synonyms
- tert-Butyl 3-(bromomethyl);3-(Boc-aMinoMethyl)benzylbroMide;tert-Butyl 3-(broMoMethyl)benzylcarbaMate;1-[3-(Bromomethyl)phenyl]-N-Boc-methanamine;3-(tert-Butoxycarbonylaminomethyl)benzyl bromide;[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester;tert-butyl N-[[3-(bromomethyl)phenyl]methyl]carbamate;N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester;Carbamic acid, N-[[3-(bromomethyl)phenyl]methyl]-, 1,1-dimethylethyl ester
- CBNumber
- CB32554317
- Molecular Formula
- C13H18BrNO2
- Formula Weight
- 300.19
- MOL File
- 220364-34-1.mol
N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester Property
- Boiling point:
- 390.9±30.0 °C(Predicted)
- Density
- 1.304
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 12.11±0.46(Predicted)
- Appearance
- White to off-white Solid
N-Bromosuccinimide Price
- Product number
- 119702
- Product name
- tert-Butyl 3-(bromomethyl)benzylcarbamate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $303
- Updated
- 2021/12/16
- Product number
- HCH0369905
- Product name
- TERT-BUTYL-3-(BROMOMETHYL)BENZYLCARBAMATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $498.25
- Updated
- 2021/12/16
- Product number
- Z4426
- Product name
- tert-Butyl3-(bromomethyl)benzylcarbamate
- Packaging
- 5g
- Price
- $1337
- Updated
- 2021/12/16
- Product number
- CD12095167
- Product name
- tert-Butyl3-(bromomethyl)benzylcarbamate
- Purity
- 98%
- Packaging
- 1g
- Price
- $294
- Updated
- 2021/12/16
- Product number
- 10-2493
- Product name
- tert-butyl3-(bromomethyl)benzylcarbamate
- Purity
- 95%-98%
- Packaging
- 1g
- Price
- $756
- Updated
- 2021/12/16
N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester Chemical Properties,Usage,Production
Synthesis
226070-69-5
220364-34-1
General procedure for the synthesis of tert-butyl 3-(bromomethyl)benzylcarbamate from tert-butyl (3-hydroxymethyl-benzyl)-carboxylate: Boc-aminomethylbenzyl alcohol (237 mg), triphenylphosphine (485 mg), and carbon tetrabromide (491 mg) were dissolved in dichloromethane (10 mL) and the reaction was stirred at room temperature overnight. After completion of the reaction, the reaction solution was concentrated. The crude product was purified by silica gel column chromatography to afford the target product tert-butyl 3-(bromomethyl)benzylcarbamate (200 mg, 67% yield).
References
[1] Patent: US2006/173183, 2006, A1. Location in patent: Page/Page column 113
[2] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 282-283
[3] Patent: WO2005/18557, 2005, A2. Location in patent: Page/Page column 282-283
[4] Patent: EP1452521, 2004, A1. Location in patent: Page 55
N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
N-[3-(Bromomethyl)benzyl]carbamic acid tert-butyl ester Suppliers
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