Methyl 2-fluoro-4-formylbenzoate

Product Name: Methyl 2-fluoro-4-formylbenzoate
CAS No.: 85070-58-2
Chemical Name: Methyl 2-fluoro-4-formylbenzoate
Synonyms: Methyl 2-fluoro-4-formylbenzoate;Methyl 2-fluoro-4-formylbenzoate 96%;(2E)-3-(5-methyl-3-furyl)acrylic acid;Benzoic acid, 2-fluoro-4-formyl-, methyl ester
CBNumber: CB32565201
Molecular Formula: C9H7FO3
Formula Weight: 182.15
MOL File: 85070-58-2.mol

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Methyl 2-fluoro-4-formylbenzoate Property

Boiling point:: 292.5±30.0 °C(Predicted)
Density: 1.271±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light yellow to yellow Solid
InChI: InChI=1S/C9H7FO3/c1-13-9(12)7-3-2-6(5-11)4-8(7)10/h2-5H,1H3
InChIKey: CFMGPKZYEUOERS-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(C=O)C=C1F

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: M305473
Product name: Methyl2-fluoro-4-formylbenzoate
Packaging: 500mg
Price: $210
Updated: 2021/12/16

Apolloscientific

Product number: PC501652
Product name: Methyl2-fluoro-4-formylbenzoate
Purity: 96%
Packaging: 1g
Price: $102
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2623-3-88
Product name: Methyl 2-fluoro-4-formylbenzoate
Packaging: 1g
Price: $151
Updated: 2021/12/16

AK Scientific

Product number: Z5186
Product name: Methyl2-fluoro-4-formylbenzoate
Packaging: 100mg
Price: $89
Updated: 2021/12/16

Apolloscientific

Product number: PC501652
Product name: Methyl2-fluoro-4-formylbenzoate
Purity: 96%
Packaging: 5g
Price: $356
Updated: 2021/12/16

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Methyl 2-fluoro-4-formylbenzoate Chemical Properties,Usage,Production

Synthesis

175596-01-7

85070-58-2

Synthesis of Example 20B Methyl 2-fluoro-4-formylbenzoate: Example 20A (methyl 4-cyano-2-fluorobenzoate, 310 mg, 1.73 mmol) was dissolved in 60% aqueous acetic acid (10 mL) and heated until completely dissolved. Nickel Ruanne (60 mg) was then added and the reaction was stirred at room temperature under hydrogen atmosphere for 18 hours. Upon completion of the reaction, the solid catalyst was removed by filtration and the filtrate was concentrated under reduced pressure. The resulting crude product was purified by silica gel column chromatography with the eluent being a 1:4 (v/v) ethyl acetate/hexane solvent mixture, resulting in the target product methyl 2-fluoro-4-formylbenzoate (220 mg, 70% yield). Mass spectrometry (DCI) analysis showed m/z 183 (M + H)+.

References

[1] Patent: US2007/112047, 2007, A1. Location in patent: Page/Page column 16
[2] Patent: US2007/259937, 2007, A1. Location in patent: Page/Page column 13
[3] Patent: WO2015/25164, 2015, A1
[4] Patent: US2015/57298, 2015, A1

Methyl 2-fluoro-4-formylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-fluoro-4-formylbenzoate Suppliers

China 62 India 1 United Kingdom 1 United States 8 Global 72

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85070-58-2, Methyl 2-fluoro-4-formylbenzoateRelated Search:

Methyl 2-fluoro-4-formylbenzoate

Methyl 2-fluoro-4-formylbenzoate 96%

Benzoic acid, 2-fluoro-4-formyl-, methyl ester

(2E)-3-(5-methyl-3-furyl)acrylic acid

85070-58-2