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ChemicalBook > CAS DataBase List > 1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene

1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene

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Product Name
1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene
CAS No.
899811-43-9
Chemical Name
1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene
Synonyms
1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene;1,1'-Bis{1-[(R)-ferrocenyl-2-(S)-ethyl-1-(diethylamino)phenyl]-(R)-phosphino}ferrocene;1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene;1,1'-Bis-[1-[(S)-Ferrocenyl-2-(R)-ethyl-1-dimethylaminophenyl]-(S)-phosphino]-ferrocene;1,1’-Bis[(S)P-[(S)Fc-2-[(R)C-1-(dimethylamino)ethyl] ferrocenyl]phenylphosphino]ferrocene;1,1′-Bis[(S)-[(1R)-2-[(1R)-1-(dimethylamino)ethyl]ferrocenyl]phenylphosphino]ferrocene (ACI);1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(diMethylaMino) phenyl]-(S)-phosphino} ferrocene Trifer;1,1′-Bis[(S)-[(1R)-2-[(1R)-1-(dimethylamino)ethyl]ferrocenyl]phenylphosphino]ferrocene (acc to CAS);1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(diMethylaMino) phenyl]-(S)-phosphino} ferrocene, Min. 97% Trifer;cyclopenta-1,3-diene:(1R)-1-[2-[cyclopenta-2,4-dien-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-yl]-N,N-dimethylethanamine:iron(2+)
CBNumber
CB32637856
Molecular Formula
C50H54Fe3N2P2
Formula Weight
912.459682
MOL File
899811-43-9.mol
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1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene Property

Melting point:
190-192 °C(Solv: methanol (67-56-1))
form 
Powder
color 
orange
InChIKey
HZMMBYQKINSWIT-KATBJRPZSA-N
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Safety

WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
26-1260
Product name
1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene, min. 97% Trifer
Purity
min. 97% Trifer
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-1260
Product name
1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene, min. 97% Trifer
Purity
min. 97% Trifer
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-1260
Product name
1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene, min. 97% Trifer
Purity
min. 97% Trifer
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
26-1260
Product name
1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene, min. 97% Trifer
Purity
min. 97% Trifer
Packaging
10g
Price
$4824
Updated
2024/03/01
Strem Chemicals
Product number
26-1261
Product name
1,1'-Bis{1-[(R)-ferrocenyl-2-(S)-ethyl-1-(diethylamino)phenyl]-(R)-phosphino}ferrocene, min. 97% Trifer
Packaging
100mg
Price
$74
Updated
2021/12/16
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1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ligand used for the Rh-catalyzed asymmetric hydrogenation of α-substituted acrylic acids.
  2. Ligand used for the Rh-catalyzed asymmetric hydrogenation of 3-aryl-2-ethoxy-acrylic acids. 

Chemical Properties

Yellow powder

1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene Suppliers

J & K SCIENTIFIC LTD.
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Aladdin Scientific
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United States
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899811-43-9, 1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferroceneRelated Search:


  • 1,1′-Bis{(S)-{(SP)-2-[(R)-1-(diMethylaMino)ethyl]ferrocenyl}phenylphosphino}ferrocene
  • 1,1'-Bis-[1-[(S)-Ferrocenyl-2-(R)-ethyl-1-dimethylaminophenyl]-(S)-phosphino]-ferrocene
  • 1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(diMethylaMino) phenyl]-(S)-phosphino} ferrocene, Min. 97% Trifer
  • 1,1′-Bis[(S)-[(1R)-2-[(1R)-1-(dimethylamino)ethyl]ferrocenyl]phenylphosphino]ferrocene (acc to CAS)
  • cyclopenta-1,3-diene:(1R)-1-[2-[cyclopenta-2,4-dien-1-yl(phenyl)phosphanyl]cyclopenta-2,4-dien-1-yl]-N,N-dimethylethanamine:iron(2+)
  • 1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(diMethylaMino) phenyl]-(S)-phosphino} ferrocene Trifer
  • 1,1’-Bis[(S)P-[(S)Fc-2-[(R)C-1-(dimethylamino)ethyl] ferrocenyl]phenylphosphino]ferrocene
  • 1,1'-Bis{1-[(R)-ferrocenyl-2-(S)-ethyl-1-(diethylamino)phenyl]-(R)-phosphino}ferrocene
  • 1,1′-Bis[(S)-[(1R)-2-[(1R)-1-(dimethylamino)ethyl]ferrocenyl]phenylphosphino]ferrocene (ACI)
  • 1,1'-Bis{1-[(S)-ferrocenyl-2-(R)-ethyl-1-(dimethylamino)phenyl]-(S)-phosphino}ferrocene
  • 899811-43-9