Methyl 2-(3-broMophenyl)propanoate
- Product Name
- Methyl 2-(3-broMophenyl)propanoate
- CAS No.
- 80622-53-3
- Chemical Name
- Methyl 2-(3-broMophenyl)propanoate
- Synonyms
- Methyl 2-(3-broMophenyl)propanoate
- CBNumber
- CB32659487
- Molecular Formula
- C10H11BrO2
- Formula Weight
- 243.1
- MOL File
- 80622-53-3.mol
Methyl 2-(3-broMophenyl)propanoate Property
- Boiling point:
- 271.7±15.0 °C(Predicted)
- Density
- 1.383±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- Colorless to light yellow Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 5064CU
- Product name
- Methyl2-(3-bromophenyl)propanoate
- Packaging
- 500mg
- Price
- $649
- Updated
- 2021/12/16
- Product number
- A919296
- Product name
- Methyl2-(3-bromophenyl)propanoate
- Purity
- 95%
- Packaging
- 5g
- Price
- $651
- Updated
- 2021/12/16
- Product number
- A919296
- Product name
- Methyl2-(3-bromophenyl)propanoate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $53
- Updated
- 2021/12/16
- Product number
- A919296
- Product name
- Methyl2-(3-bromophenyl)propanoate
- Purity
- 95%
- Packaging
- 250mg
- Price
- $80
- Updated
- 2021/12/16
- Product number
- A919296
- Product name
- Methyl2-(3-bromophenyl)propanoate
- Purity
- 95%
- Packaging
- 1g
- Price
- $196
- Updated
- 2021/12/16
Methyl 2-(3-broMophenyl)propanoate Chemical Properties,Usage,Production
Synthesis
150529-73-0
74-88-4
80622-53-3
Methyl 3-bromophenylacetate (4.58 g, 20 mmol, 1.0 eq.) was added to a dry 100 mL three-neck flask under nitrogen protection. Anhydrous tetrahydrofuran (30 mL) was added, followed by the slow dropwise addition of 2.0 M lithium diisopropylammonium THF/heptane/ethylbenzene solution (10.5 mL, 21 mmol, 1.05 eq.) at -78 °C. After dropwise addition, the reaction mixture was stirred at -78 °C for 30 min. Then, iodomethane (2.84 g, 20 mmol, 1.0 eq.) was added and the reaction mixture was gradually warmed to room temperature and stirring was continued for 3 hours. Upon completion of the reaction, 60 mL of water was added to the reaction flask and the organic phase was separated by extraction with 50 mL of dichloromethane. The aqueous phase was extracted twice more with 30 mL of dichloromethane. All organic phases were combined, washed twice with saturated brine solution and dried over anhydrous sodium sulfate. After concentration under reduced pressure, the residue was purified by column chromatography to afford methyl 2-(3-bromophenyl)propionate 3.95 g in 82.3% yield.
References
[1] Patent: CN108794319, 2018, A. Location in patent: Paragraph 0033-0035
[2] Green Chemistry, 2017, vol. 19, # 20, p. 4798 - 4803
[3] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 11, p. 3299 - 3311
Methyl 2-(3-broMophenyl)propanoate Preparation Products And Raw materials
Raw materials
Preparation Products
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