2-(4-Bromophenyl)cyclopropanecarboxylic acid

Product Name: 2-(4-Bromophenyl)cyclopropanecarboxylic acid
CAS No.: 77255-26-6
Chemical Name: 2-(4-Bromophenyl)cyclopropanecarboxylic acid
Synonyms: 2-(p-bromophenyl)-1-cyclopropanecarboxylicacid;Cyclopropanecarboxylic acid, 2-(4-bromophenyl)-;2-(4-Bromophenyl)cyclopropane-1-carboxylic acid;2-(4-Bromophenyl)-1-cyclopropanecarboxylic acid
CBNumber: CB32676679
Molecular Formula: C10H9BrO2
Formula Weight: 241.08
MOL File: 77255-26-6.mol

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2-(4-Bromophenyl)cyclopropanecarboxylic acid Property

Melting point:: 122 °C
Boiling point:: 364.5±42.0 °C(Predicted)
Density: 1.652±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 4.53±0.10(Predicted)
Appearance: Off-white to light yellow Solid

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Safety

HS Code: 2916200090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

SynQuest Laboratories

Product number: 2621-9-47
Product name: 2-(4-Bromophenyl)cyclopropane-1-carboxylic acid
Packaging: 250mg
Price: $188
Updated: 2021/12/16

AK Scientific

Product number: 2060AC
Product name: 2-(4-Bromophenyl)cyclopropanecarboxylicacid
Packaging: 250mg
Price: $257
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2621-9-47
Product name: 2-(4-Bromophenyl)cyclopropane-1-carboxylic acid
Packaging: 1g
Price: $360
Updated: 2021/12/16

Matrix Scientific

Product number: 125841
Product name: 2-(4-Bromophenyl)cyclopropane-1-carboxylicacid
Purity: >95%
Packaging: 500mg
Price: $657
Updated: 2021/12/16

Matrix Scientific

Product number: 125841
Product name: 2-(4-Bromophenyl)cyclopropane-1-carboxylicacid
Purity: >95%
Packaging: 1g
Price: $889
Updated: 2021/12/16

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2-(4-Bromophenyl)cyclopropanecarboxylic acid Chemical Properties,Usage,Production

Synthesis

53582-00-6

6142-65-0

A 4N NaOH solution (20 mL) was added to a solution of ethyl (trans)-2-(4-bromophenyl)cyclopropanecarboxylate (Intermediate I, 4 g, 0.0149 mol) in methanol (40 mL), and the reaction was stirred for 2 h at room temperature. Upon completion of the reaction, the progress of the reaction was monitored by thin layer chromatography (TLC). Subsequently, the solvent was removed by evaporation and the residue was diluted with distilled water (50 mL) and acidified with 4N HCl solution to pH < 7. The precipitated solid was collected by filtration and dried to afford (trans)-2-(4-bromophenyl)cyclopropanecarboxylic acid (2.59 g, 72% yield) as a white solid.

References

[1] Organic and Biomolecular Chemistry, 2016, vol. 14, # 8, p. 2498 - 2503
[2] Monatshefte fur Chemie, 2017, vol. 148, # 12, p. 2143 - 2153
[3] Journal of Medicinal Chemistry, 2017, vol. 60, # 7, p. 3187 - 3197
[4] Journal of the American Chemical Society, 2010, vol. 132, # 19, p. 6827 - 6833
[5] Patent: WO2012/13728, 2012, A1. Location in patent: Page/Page column 101; 102

2-(4-Bromophenyl)cyclopropanecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(4-Bromophenyl)cyclopropanecarboxylic acid Suppliers

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77255-26-6, 2-(4-Bromophenyl)cyclopropanecarboxylic acidRelated Search:

2-(4-Bromophenyl)-1-cyclopropanecarboxylic acid

2-(4-Bromophenyl)cyclopropane-1-carboxylic acid

Cyclopropanecarboxylic acid, 2-(4-bromophenyl)-

2-(p-bromophenyl)-1-cyclopropanecarboxylicacid

77255-26-6