N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB

Reaction

Product Name: N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
CAS No.: 1384974-37-1
Chemical Name: N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
Synonyms: (S,S)-TS-DENEB;(S,S)-Ts-DENEB[R];(S,S)-Ts-DENEB®(S,S)-Ts-DENEB(regR);(S,S)-Ts-DENEB(regR) (S,S)-Ts-DENEB;Chloro[(S,S)-N-[2-[2-(4-methylbenzyloxy)ethyl]amino-1,2-diphenylethyl]-p-toluenesulfonamide]ruthenium(II);Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II);Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II);N-[(1S,2S)-1,2-Diphenyl-2-[2-(4-methylbenzyloxy)ethylamino]ethyl]-4-methylbenzenesulfonamide(chloro)ruthenium;N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)
CBNumber: CB32709209
Molecular Formula: C31H28ClN2O3RuS
Formula Weight: 645.16
MOL File: 1384974-37-1.mol

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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Property

form: solid
color: gray to brown
Sensitive: air sensitive

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Safety

RIDADR: UN 3077 9/PG III
HS Code: 2843.90.0000
HazardClass: 9
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical

Product number: T3077
Product name: (S,S)-Ts-DENEB[R]
Packaging: 200mg
Price: $76
Updated: 2024/03/01

TCI Chemical

Product number: T3077
Product name: (S,S)-Ts-DENEB[R]
Packaging: 1g
Price: $246
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0186
Product name: N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)
Packaging: 250mg
Price: $64
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0186
Product name: N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)
Packaging: 1g
Price: $190
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0186
Product name: N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)
Packaging: 5g
Price: $545
Updated: 2024/03/01

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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Chemical Properties,Usage,Production

Reaction

1. Catalyst used for asymmetric -transfer hydrogenation. 2. Catalyst used for asymmetric H2 – hydrogenation. 3. Catalyst used for dynamic kinetic resolution.

Uses

(S,S)-Ts-DENEB (regR) (CAS# 1384974-37-1) is a catalyst used in transfer hydrogenation reactions, such as in the selective asymmetric transfer hydrogenation of α-substituted acetophenones, and asymmetric transfer hydrogenation of aryl N-heteroaryl ketones.

reaction suitability

reagent type: ligand

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Preparation Products And Raw materials

Raw materials

Preparation Products

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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Suppliers

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1384974-37-1, N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEBRelated Search:

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB

(S,S)-Ts-DENEB(regR)

(S,S)-TS-DENEB

(S,S)-Ts-DENEB&reg

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)

(S,S)-Ts-DENEB[R]

(S,S)-Ts-DENEB(regR) (S,S)-Ts-DENEB

Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)

Chloro[(S,S)-N-[2-[2-(4-methylbenzyloxy)ethyl]amino-1,2-diphenylethyl]-p-toluenesulfonamide]ruthenium(II)

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)

N-[(1S,2S)-1,2-Diphenyl-2-[2-(4-methylbenzyloxy)ethylamino]ethyl]-4-methylbenzenesulfonamide(chloro)ruthenium

Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)

1384974-37-1