Reaction
ChemicalBook > CAS DataBase List > N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB

Reaction
Product Name
N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
CAS No.
1384974-37-1
Chemical Name
N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
Synonyms
(S,S)-TS-DENEB;(S,S)-Ts-DENEB[R];(S,S)-Ts-DENEB®(S,S)-Ts-DENEB(regR);(S,S)-Ts-DENEB(regR) (S,S)-Ts-DENEB;(S,S)-Ts-DENEB?;Chloro[(S,S)-N-[2-[2-(4-methylbenzyloxy)ethyl]amino-1,2-diphenylethyl]-p-toluenesulfonamide]ruthenium(II);Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II);N-[(1S,2S)-1,2-Diphenyl-2-[2-(4-methylbenzyloxy)ethylamino]ethyl]-4-methylbenzenesulfonamide(chloro)ruthenium;N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)
CBNumber
CB32709209
Molecular Formula
C31H28ClN2O3RuS
Formula Weight
645.16
MOL File
1384974-37-1.mol
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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Property

storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
solid
color 
gray to brown
Sensitive 
air sensitive
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Safety

RIDADR 
UN 3077 9/PG III
HS Code 
2843.90.0000
HazardClass 
9
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
926124
Product name
(<i>S</i>,<i>S</i>)-Ts-DENEB<SUP>™</SUP>
Packaging
250 mg
Price
$79.8
Updated
2025/07/31
Sigma-Aldrich
Product number
926124
Product name
(<i>S</i>,<i>S</i>)-Ts-DENEB<SUP>™</SUP>
Packaging
1 g
Price
$234
Updated
2025/07/31
Sigma-Aldrich
Product number
926124
Product name
(<i>S</i>,<i>S</i>)-Ts-DENEB<SUP>™</SUP>
Packaging
5 g
Price
$638
Updated
2025/07/31
TCI Chemical
Product number
T3077
Product name
(S,S)-Ts-DENEB[R]
Packaging
200mg
Price
$76
Updated
2025/07/31
TCI Chemical
Product number
T3077
Product name
(S,S)-Ts-DENEB[R]
Packaging
1g
Price
$246
Updated
2025/07/31
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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Chemical Properties,Usage,Production

Reaction

1. Catalyst used for asymmetric -transfer hydrogenation. 2. Catalyst used for asymmetric H2 – hydrogenation. 3. Catalyst used for dynamic kinetic resolution.

Uses

(S,S)-Ts-DENEB (regR) (CAS# 1384974-37-1) is a catalyst used in transfer hydrogenation reactions, such as in the selective asymmetric transfer hydrogenation of α-substituted acetophenones, and asymmetric transfer hydrogenation of aryl N-heteroaryl ketones.

reaction suitability

reagent type: ligand

N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Preparation Products And Raw materials

Raw materials

Preparation Products

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N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB Suppliers

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1384974-37-1, N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEBRelated Search:


  • N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (S,S)-Ts-DENEB
  • (S,S)-Ts-DENEB(regR)
  • (S,S)-TS-DENEB
  • (S,S)-Ts-DENEB&reg
  • N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB(TM)
  • (S,S)-Ts-DENEB[R]
  • (S,S)-Ts-DENEB(regR) (S,S)-Ts-DENEB
  • Chloro[(S,S)-N-[2-(4-methylbenzyloxy)ethyl]-N'-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • Chloro[(S,S)-N-[2-[2-(4-methylbenzyloxy)ethyl]amino-1,2-diphenylethyl]-p-toluenesulfonamide]ruthenium(II)
  • N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)
  • N-[(1S,2S)-1,2-Diphenyl-2-[2-(4-methylbenzyloxy)ethylamino]ethyl]-4-methylbenzenesulfonamide(chloro)ruthenium
  • (<i>S</i>,<i>S</i>)-Ts-DENEB<sup>?</sup>
  • 1384974-37-1