ChemicalBook > CAS DataBase List > 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos

2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos

Reaction

Product Name: 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos
CAS No.: 1160861-59-5
Chemical Name: 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos
Synonyms: AdBrettPhos;AdBrettPhos 95%;Di-Ad-BrettPhos;AdBrettPhos ChemBeads;Di(1-adamantyl)(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine;Di(1-adamantyl)(2’,4’,6’-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine;2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl;2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl;Di(adamantan-1-yl)(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenyl yl)phosphine;bis(1-adamantyl)-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
CBNumber: CB32709254
Molecular Formula: C43H61O2P
Formula Weight: 640.92
MOL File: 1160861-59-5.mol

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2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos Property

Melting point:: 231-235°C
storage temp.: 2-8°C, protect from light, stored under nitrogen
form: Powder
color: off-white to pale yellow
InChIKey: NMGHOZQCYNKWBG-UHFFFAOYSA-N
SMILES: P(C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C)(C12CC3CC(CC(C3)C1)C2)C12CC3CC(CC(C3)C1)C2

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P391Collect spillage. Hazardous to the aquatic environment

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 768154
Product name: AdBrettPhos
Purity: 95%
Packaging: 100mg
Price: $138
Updated: 2025/07/31

Sigma-Aldrich

Product number: 768154
Product name: AdBrettPhos
Purity: 95%
Packaging: 1g
Price: $926
Updated: 2025/07/31

Strem Chemicals

Product number: 15-1138
Product name: 2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 95% AdBrettPhos
Packaging: 100mg
Price: $107
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1138
Product name: 2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 95% AdBrettPhos
Packaging: 500mg
Price: $448
Updated: 2024/03/01

Sigma-Aldrich

Product number: 768154
Product name: AdBrettPhos
Purity: 95%
Packaging: 500mg
Price: $658
Updated: 2025/07/31

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2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos Chemical Properties,Usage,Production

Reaction

Ligand used in the palladium-catalyzed amidation of five-membered heterocycles as electrophiles.

Uses

AdBrettPhos has been used in:
C-N Coupling reactions. (see 31896889)
The fluorination of alrl triflates.(see 25346547)
The Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols. (see 29474078)
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For general uses, product is also available in powdered form (768154)

reaction suitability

reagent type: ligand

2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos 1160861-59-5
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-13

Career Henan Chemical Co

Product: AdBrettPhos 1160861-59-5
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

1160861-59-5, 2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhosRelated Search:

Di-Ad-BrettPhos

AdBrettPhos 95%

2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 95% AdBrettPhos

AdBrettPhos

2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl,AdBrettPhos

Di(adamantan-1-yl)(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenyl yl)phosphine

adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 98% AdBrettPho

Phosphine, [3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(tricyclo[3.3.1.13,7]dec-1-yl)-

Di(1-adamantyl)(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine

Di(adamantan-1-yl)(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine

bis(1-adamantyl)-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl

2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl

Di(1-adamantyl)(2’,4’,6’-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine

2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl (AdBrettPhos)

AdBrettPhos ChemBeads

AdBrettPhos,2-(Di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl

2-(Di-1-adaMantylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl

2-Dibutylphosphine-2-(1-phenylpentyl)-3,6-dimethoxy-2',4',6'-tripropyl-1,1'-biphenyl

1160861-59-5

C43H61O2P

Buchwald Ligands Series

Achiral Phosphine

Aryl Phosphine

Buchwald Ligands&Precatalysts