S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE Property

Melting point:

63-65 °C

Boiling point:

632.8±45.0 °C(Predicted)

pka

7.82±0.50(Predicted)

optical activity

[α]20/D 4.5±0.7°, c = 1% in acetone

BRN 

4608384

Safety

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-36/37/39-45

RIDADR 

UN 3259 8/PG 3

WGK Germany 

3

F 

1-10

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE Chemical Properties,Usage,Production

General Description

(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.