(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON

Product Name: (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
CAS No.: 36548-60-4
Chemical Name: (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
Synonyms: IRON ACETYL CHIRAL;IRON ACETYL COMPLEX (+)-(S)-ENANTIOMER;IRON ACETYL COMPLEX (-)-(R)-ENANTIOMER;(S)-(+)-Acetylcarbonyl(eta-5,2,4-cyclopentadien-1-y;acetylcyclopentadienyl/ iron carbonyl triphenylphosphine;(R)-(-)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;S(+)-CYCLOPENTADIENYL IRON ACETYL CARBONYL TRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLO- PENTANEDIENYL IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX;(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
CBNumber: CB3274947
Molecular Formula: C26H23FeO2P5*
Formula Weight: 454.28
MOL File: 36548-60-4.mol

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(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Property

Melting point:: 151-156 °C
storage temp.: 2-8°C
solubility: soluble in THF, CHCl3, CH2Cl2, acetone

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
F: 8-10

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: ING0001374
Product name: (S)-ACETO(CARBONYL)(CYCLOPENTADIENYL)-(TRIPHENYLPHOSPHINE)IRON
Purity: 95.00%
Packaging: 5MG
Price: $502.05
Updated: 2021/12/16

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(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Chemical Properties,Usage,Production

Uses

(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON is used as chiral acetate enolate equivalent which can be deprotonated with BuLi or LDA in THF at -78 °C; the enolate reacts stereoselectively with a variety of achiral, prochiral, and chiral electrophiles to generate functionalized organoiron compounds from which the iron can subsequently be removed.

storage

(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON can be stored in air for days with little decomposition. The solid is best stored under nitrogen for long periods of time. More air sensitive when in solution, especially chlorinated hydrocarbons.

(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Suppliers

China 6 Germany 2 Switzerland 1 United States 1 Global 10

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

36548-60-4, (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRONRelated Search:

Dicyclopentadiene (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON,(S)-(+)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON

IRON ACETYL COMPLEX (-)-(R)-ENANTIOMER

IRON ACETYL COMPLEX (+)-(S)-ENANTIOMER

(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON

(R)-(-)-ACETYLCARBONYL((ETA)5-2,4-CYCLOPENTADIENE-1-YL)(TRIPHENYLPHOSPHINE)IRON

(R)-(-)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX

S(+)-CYCLOPENTADIENYL IRON ACETYL CARBONYL TRIPHENYLPHOSPHINE COMPLEX

(S)-(+)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX

(S)-(+)-ACETYLCYCLO- PENTANEDIENYL IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX

(S)-(+)-ACETYLARBONYL((ETA)5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON

(S)-(+)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON

(S)-(+)-Acetylcarbonyl(eta-5,2,4-cyclopentadien-1-y

(S)-(+)-ACETYL-CYCLOPENTADIENYL-IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX PURUM 97%

acetylcyclopentadienyl/ iron carbonyl triphenylphosphine

Iron acetyl chiral, (S)-(+)-Cyclopentadienyl iron acetyl carbonyl triphenylphosphine complex

IRON ACETYL CHIRAL

36548-60-4

C26H23FeO2P

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Carbonyl/Imine Addition