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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE

Product Name
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
CAS No.
37891-79-5
Chemical Name
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Synonyms
BIS(METHYLTHIO)METHYLTRIMETHYLSILANE;TRIMETHYLBIS(METHYLTHIO)METHYLSILANE;BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE;Silane, [bis(methylthio)methyl]trimethyl-;Bis(methylthio)(trimethylsilyl)methane >Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
CBNumber
CB3275106
Molecular Formula
C6H16S2Si
Formula Weight
180.41
MOL File
37891-79-5.mol
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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Property

Boiling point:
82 °C(Press: 10.0 Torr)
Density 
0.941±0.06 g/cm3(Predicted)
refractive index 
1.5060-1.5100
solubility 
insol H2O; sol organic solvents.
form 
clear liquid
color 
Colorless to Light yellow to Light orange
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Safety

HS Code 
2931.90.9010
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2004
Product name
Bis(methylthio)(trimethylsilyl)methane
Purity
>98.0%(GC)
Packaging
1g
Price
$99
Updated
2024/03/01
TRC
Product number
B102786
Product name
Bis(methylthio)(trimethylsilyl)methane
Packaging
10mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB61175
Product name
Bis(methylthio)(trimethylsilyl)methane
Packaging
250mg
Price
$100
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ORS0001338
Product name
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
Purity
95.00%
Packaging
1G
Price
$257.46
Updated
2021/12/16
AK Scientific
Product number
7236AL
Product name
Bis(methylthio)(trimethylsilyl)methane
Packaging
5g
Price
$664
Updated
2021/12/16
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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Chemical Properties,Usage,Production

Physical properties

bp 67–70°C/10 mmHg.

Uses

Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals from aldehydes and ketones;acyl anion synthon for conjugate additions to enones and enoates;useful for one-carbon homologations.
The bis(methylthio)ketene acetals are useful synthetic intermediates because they are readily converted into S-methyl thioesters (eq 9) or the corresponding carboxylic acids and esters.

Preparation

prepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.

BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Suppliers

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37891-79-5, BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANERelated Search:


  • TRIMETHYLBIS(METHYLTHIO)METHYLSILANE
  • Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
  • BIS(METHYLTHIO)METHYLTRIMETHYLSILANE
  • BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
  • Bis(methylthio)(trimethylsilyl)methane &gt
  • Silane, [bis(methylthio)methyl]trimethyl-
  • 37891-79-5
  • C6H16S2Si
  • Si-(C)4 Compounds
  • Si (Classes of Silicon Compounds)
  • Silicon Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Si (Classes of Silicon Compounds)
  • Si-(C)4 Compounds
  • Silicon Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry