BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
- Product Name
- BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
- CAS No.
- 37891-79-5
- Chemical Name
- BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
- Synonyms
- BIS(METHYLTHIO)METHYLTRIMETHYLSILANE;TRIMETHYLBIS(METHYLTHIO)METHYLSILANE;BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE;Silane, [bis(methylthio)methyl]trimethyl-;Bis(methylthio)(trimethylsilyl)methane >Bis(methylthio)methyltrimethylsilane Trimethylbis(methylthio)methylsilane
- CBNumber
- CB3275106
- Molecular Formula
- C6H16S2Si
- Formula Weight
- 180.41
- MOL File
- 37891-79-5.mol
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Property
- Boiling point:
- 82 °C(Press: 10.0 Torr)
- Density
- 0.941±0.06 g/cm3(Predicted)
- refractive index
- 1.5060-1.5100
- solubility
- insol H2O; sol organic solvents.
- form
- clear liquid
- color
- Colorless to Light yellow to Light orange
Safety
- HS Code
- 2931.90.9010
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H227Combustible liquid
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235Store in a well-ventilated place. Keep cool.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B2004
- Product name
- Bis(methylthio)(trimethylsilyl)methane
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- B102786
- Product name
- Bis(methylthio)(trimethylsilyl)methane
- Packaging
- 10mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FB61175
- Product name
- Bis(methylthio)(trimethylsilyl)methane
- Packaging
- 250mg
- Price
- $100
- Updated
- 2021/12/16
- Product number
- ORS0001338
- Product name
- BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $257.46
- Updated
- 2021/12/16
- Product number
- 7236AL
- Product name
- Bis(methylthio)(trimethylsilyl)methane
- Packaging
- 5g
- Price
- $664
- Updated
- 2021/12/16
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Chemical Properties,Usage,Production
Physical properties
bp 67–70°C/10 mmHg.
Uses
Bis(methylthio)(trimethylsilyl)methane is a reagent used for synthesis of bis(methylthio)ketene acetals
from aldehydes and ketones;acyl anion synthon for conjugate
additions to enones and enoates;useful for one-carbon
homologations.
The bis(methylthio)ketene
acetals are useful synthetic intermediates because they are readily
converted into S-methyl thioesters (eq 9) or the corresponding
carboxylic acids and esters.
Preparation
prepared from lithiobis(methylthio)- methane by silylation with chlorotrimethylsilane (eq 1).Both bis(methylthio)methane and chlorotrimethylsilane are commercially available.
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Preparation Products And Raw materials
Raw materials
Preparation Products
BIS(METHYLTHIO)(TRIMETHYLSILYL)METHANE Suppliers
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 021-61259108 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 010-88425576
- Fax
- (+86)-10-88425546
- sales@dhltchem.com
- Country
- China
- ProdList
- 793
- Advantage
- 59
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44688
- Advantage
- 61
- Tel
- +86 (573) 82222445 (0)18006601000 452520369
- Fax
- +86 (573) 82222643
- sales@maya-r.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 025-66099280 17798518460
- Fax
- (1)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 19915
- Advantage
- 55
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23671
- Advantage
- 75
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75