ChemicalBook > CAS DataBase List > TRIMETHYLTIN CHLORIDE

TRIMETHYLTIN CHLORIDE

Product Name
TRIMETHYLTIN CHLORIDE
CAS No.
1066-45-1
Chemical Name
TRIMETHYLTIN CHLORIDE
Synonyms
CHLOROTRIMETHYLSTANNANE;trimethylstannylchloride;TRIMETHYLTIN(IV) CHLORIDE;1mTHF;tin chL;SKL1103;ai3-28454;(CH3)3SnCl;CHLOROTRIMETHYLTIN;TRIMETHYLCHLOROTIN
CBNumber
CB3277094
Molecular Formula
C3H9ClSn
Formula Weight
199.27
MOL File
1066-45-1.mol
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TRIMETHYLTIN CHLORIDE Property

Melting point:
37-39 °C (lit.)
Boiling point:
148 °C
Density 
0.988 g/mL at 25 °C
Flash point:
207 °F
storage temp. 
Poison room
solubility 
Chloroform (Slightly)
form 
Liquid
Specific Gravity
1.356
color 
White
Odor
Strong unpleasant stench; no threshold data available
Water Solubility 
Soluble in water, chloroform and organic solvents.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3535111
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability:
Moisture Sensitive
InChIKey
KWTSZCJMWHGPOS-UHFFFAOYSA-M
CAS DataBase Reference
1066-45-1(CAS DataBase Reference)
EPA Substance Registry System
Trimethyltin chloride (1066-45-1)
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Safety

Hazard Codes 
T+,N,F
Risk Statements 
26/27/28-50/53-51/53-36/37-19-11-34-40-65-62-48/23/25-36/37/38
Safety Statements 
28-36/37-45-61-27-26-16-60-62
RIDADR 
UN 3146 6.1/PG 2
WGK Germany 
3
RTECS 
WH6850000
F 
10-21
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319090
Hazardous Substances Data
1066-45-1(Hazardous Substances Data)
Toxicity
LD50 oral (rat) 12.6 mg/kg
PEL (OSHA) 0.1 mg tin/m3
The ACGIH has established the following uniform exposure limits for all organotin compounds based on the concentration of tin in air:
TLV-TWA (ACGIH) 0.1 mg tin/m3
STEL (ACGIH) 0.2 mg tin/m3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P262Do not get in eyes, on skin, or on clothing.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
146498
Product name
Trimethyltin chloride
Packaging
5g
Price
$39.36
Updated
2024/03/01
Sigma-Aldrich
Product number
146498
Product name
Trimethyltin chloride
Packaging
10g
Price
$109
Updated
2024/03/01
TCI Chemical
Product number
T0958
Product name
Trimethyltin Chloride
Purity
>98.0%(GC)
Packaging
5g
Price
$75
Updated
2024/03/01
TCI Chemical
Product number
T0958
Product name
Trimethyltin Chloride
Purity
>98.0%(GC)
Packaging
25g
Price
$230
Updated
2024/03/01
Alfa Aesar
Product number
071166
Product name
Trimethyltin chloride
Packaging
2g
Price
$31.5
Updated
2023/06/20
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TRIMETHYLTIN CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

WHITE CRYSTALS

Uses

Trimethyltin chloride is an organotin reagent widely used in transferring trimethylstannyl groups onto the substrates to synthesize various organostannanes. Trimethylstannyl compounds derived from this reagent, are extensively used in the palladium-catalyzed Stille coupling reactions.

General Description

Solid.

Reactivity Profile

TRIMETHYLTIN CHLORIDE is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation.

Hazard

A deadly poison. A reproductive hazard.

Health Hazard

(Non-Specific -- Tin Compounds, Organic) The material is an irritant to the skin and gastrointestinal tract. Contact may specifically damage the following target organs: central nervous system, eyes, liver, urinary tract, and skin.

Health Hazard

Trimethyltin chloride and other organotin compounds are highly toxic by ingestion, inhalation, or skin contact. Trimethyltin chloride can cause irritation and burns of the skin and eyes. Organotin compounds can affect the central nervous system. The degree of toxicity is greatest for compounds with three or four alkyl groups attached to tin. Diand monoalkyltin compounds are moderately toxic. The toxicity diminishes as the size of the alkyl groups increases. Thus, the oral LD50s in rats are as follows: dimethyltin dichloride, 74 to 237 mg/kg; tributyltin chloride, 122 to 349 mg/kg; dibutyltin oxide, 487 to 520 mg/kg; trioctyltin chloride, >4000 mg/kg.
Organotin compounds have been shown to cause reproductive effects in laboratory animals.

Fire Hazard

Not a significant fire hazard. Emits toxic fumes in fire.

Fire Hazard

When heated to decomposition, TRIMETHYLTIN CHLORIDE emits toxic fumes of chlorides. Avoid decomposing heat.

Flammability and Explosibility

Not a significant fire hazard. Emits toxic fumes in fire.

Safety Profile

A deadly poison by intravenous route. Experimental reproductive effects. See also TIN COMPOUNDS. When heated to decomposition it emits toxic fumes of Cl-.

Incompatibilities

Trimethyltin chloride and other organotin halides react with water to produce hydrogen halides. Organotin hydrides react with water to produce hydrogen gas, which is flammable and explosive.

Waste Disposal

Excess trimethyltin chloride or other organotin compound and waste material containing this substance should be placed in an appropriate container, clearly labeled, and handled according to your institution's waste disposal guidelines.

TRIMETHYLTIN CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

4-BROMO-2-(TRIFLUOROMETHYL)-5-METHOXYPYRIDINE
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View Lastest Price from TRIMETHYLTIN CHLORIDE manufacturers

Career Henan Chemical Co
Product
TRIMETHYLTIN CHLORIDE 1066-45-1
Price
US $1.00/KG
Min. Order
1KG
Purity
95%~99%
Supply Ability
1ton
Release date
2019-12-18

1066-45-1, TRIMETHYLTIN CHLORIDERelated Search:

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