ChemicalBook > CAS DataBase List > METHYL 10-UNDECENOATE

METHYL 10-UNDECENOATE

Product Name
METHYL 10-UNDECENOATE
CAS No.
111-81-9
Chemical Name
METHYL 10-UNDECENOATE
Synonyms
NSC 1273;methylundec-10;Maskod MNS 01-10;Methyl 10-undecen;Eleven Methyl-ene;Methyl undecenate;METHYL UNDECENOATE;METHYL UNDECYLENATE;METHYL10-UNDECNOATE;METHYL 10-UNDECENATE
CBNumber
CB3296417
Molecular Formula
C12H22O2
Formula Weight
198.3
MOL File
111-81-9.mol
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METHYL 10-UNDECENOATE Property

Melting point:
26-27℃
Boiling point:
245 °C (lit.)
Density 
0.882 g/mL at 25 °C (lit.)
vapor pressure 
2.1hPa at 25℃
FEMA 
4253 | METHYL 10-UNDECENOATE
refractive index 
n20/D 1.437(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
H2O: insoluble
form 
clear liquid
Specific Gravity
0.882
color 
Colorless to Light yellow
Odor
at 100.00 %. fatty waxy citrus earthy fungal rose floral
Odor Type
fatty
Water Solubility 
794μg/L at 20℃
JECFA Number
1639
LogP
5.3 at 20℃
CAS DataBase Reference
111-81-9(CAS DataBase Reference)
EPA Substance Registry System
10-Undecenoic acid, methyl ester (111-81-9)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
36/37/38-20/22
Safety Statements 
26-36/37/39-61-60-24/25
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
3
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
115126
Product name
Methyl 10-undecenoate
Purity
96%
Packaging
25ml
Price
$62
Updated
2024/03/01
Sigma-Aldrich
Product number
115126
Product name
Methyl 10-undecenoate
Purity
96%
Packaging
500ml
Price
$216
Updated
2024/03/01
TCI Chemical
Product number
U0036
Product name
Methyl 10-Undecenoate
Purity
>96.0%(GC)
Packaging
25mL
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
U0036
Product name
Methyl 10-Undecenoate
Purity
>96.0%(GC)
Packaging
100mL
Price
$78
Updated
2024/03/01
Sigma-Aldrich
Product number
W425301
Product name
Methyl 10-Undecenoate
Purity
96%
Packaging
sample
Price
$54.6
Updated
2023/01/07
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METHYL 10-UNDECENOATE Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid; oily aroma.

Uses

Methyl 10-undecenoate, unsaturated fatty acid ester, is used to modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane for the preparation of silicone hollow nano/microstructures in water.

Uses

Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate:

  • To prepare bifunctional polymer precursors via hydroformylation reaction.
  • To synthesize α,ω-ester amides via aminocarbonylation in the presence of palladium catalyst.
  • To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.

Definition

ChEBI: A fatty acid methyl ester of 10-undecenoic acid.

Aroma threshold values

Medium strength odor, fatty type

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 3015, 1989 DOI: 10.1021/jo00274a010
Tetrahedron, 52, p. 915, 1996 DOI: 10.1016/0040-4020(95)00950-7
Synthetic Communications, 3, p. 281, 1973 DOI: 10.1080/00397917308065917

General Description

Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.

Flammability and Explosibility

Non flammable

METHYL 10-UNDECENOATE Preparation Products And Raw materials

Raw materials

Ricinoleic acid Undecenoic acid

Preparation Products

Heptaldehyde Undecanal Undecenoic acid
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View Lastest Price from METHYL 10-UNDECENOATE manufacturers

Career Henan Chemical Co
Product
METHYL 10-UNDECENOATE 111-81-9
Price
US $500.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2018-08-04

111-81-9, METHYL 10-UNDECENOATERelated Search:

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  • Methyl 10-undecylenate
  • METHYL10-UNDECNOATE
  • METHYL10-UNEDECENOATE
  • Methylundec-10-enoat
  • METHYL UNDECYLENATE (10-UNDECENOIC ACID, METHYL ESTER)
  • 10-Undecenoic acid methyl ester, Undecylenic acid methyl ester
  • Eleven Methyl-ene
  • Methyl undecylenate≥ 98% (GC)
  • Methyl ester of 10-Undecenoic acid
  • Methyl undecenate
  • methylundec-10
  • methylundec-10-enoate
  • undec-10-enoicacidmethylester
  • Undecenoic acid, methyl ester
  • Methyl 10-Undecenoate (10-Undecenoic Acid Methyl Ester)
  • METHYL 10-UNDECENOATE ISO 9001：2015 REACH
  • 10-cis-UNDECENOIC METHYL
  • 111-81-9
  • CH2CHCH28CO2CH3
  • C12 to C63
  • Carbonyl Compounds
  • Building Blocks
  • Biochemicals and Reagents
  • BioChemical
  • Fatty Acids
  • Esters
  • Organic Building Blocks
  • Methyl Esters
  • Lipids
  • Unsaturated fatty acids and derivatives
  • ESTER
  • Biochemicals and Reagents
  • Building Blocks
  • C12 to C63
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Fatty Acids and conjugates