[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

Product Name: [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
CAS No.: 2102544-35-2
Chemical Name: [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
Synonyms: JackiePhos-Pd-G3;JackiePhos Pd G3;JackiePhos Palladacycle;Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II);[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate;JackiePhos Pd G3/Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis[3,5-bis(trifluoromethyl)phenyl][3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;Methanesulfonicacid[1,2-bis(3,5-bis(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl(2'-amino-1,1'-biphenyl-2-yl)palladium(II),JackiePhosPalladacycleGen.3;Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [JackiePhos Palladacycle Gen. 3]
CBNumber: CB32985667
Molecular Formula: C52H50F12NO5PPdS
Formula Weight: 1166.41
MOL File: 2102544-35-2.mol

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[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate Property

Melting point:: 195-197 °C (decomposition)
storage temp.: 2-8°C, protect from light, stored under nitrogen
form: solid
Appearance: White to light brown Solid
InChIKey: LLXGRQGGARSAOC-UHFFFAOYSA-M
SMILES: CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.COc3ccc(OC)c(c3P(c4cc(cc(c4)C(F)(F)F)C(F)(F)F)c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6c(cc(cc6C(C)C)C(C)C)C(C)C

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Safety

WGK Germany: 3
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 762830
Product name: JackiePhos Pd G3
Purity: 95%
Packaging: 100MG
Price: $138.92
Updated: 2025/07/31

Sigma-Aldrich

Product number: 762830
Product name: JackiePhos Pd G3
Purity: 95%
Packaging: 500MG
Price: $364.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: 762830
Product name: JackiePhos Pd G3
Purity: 95%
Packaging: 1G
Price: $539
Updated: 2025/07/31

Sigma-Aldrich

Product number: 762830
Product name: JackiePhos Pd G3
Purity: 95%
Packaging: 5G
Price: $2220
Updated: 2025/07/31

Strem Chemicals

Product number: 46-0340
Product name: Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [JackiePhos Palladacycle Gen. 3]
Packaging: 100mg
Price: $120
Updated: 2024/03/01

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[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate Chemical Properties,Usage,Production

Uses

JackiePhos Pd G3 can be used as a palladium precatalyst in Stille cross-coupling reaction between organostannane and ary halides.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

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[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate Suppliers

China 32 United States 4 Global 36

Wuhan Taiyu New Materials Co., Ltd.

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WuHan Taiyukaishang Chemical Co., Ltd.

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Sigma-Aldrich

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Alfa Chemistry

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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.

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LaaJoo

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Aikon International Limited

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Henan Alpha Chemical Co., Ltd.

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View Lastest Price from [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: JackiePhos Pd G3 2102544-35-2
Price: US $2.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-24

Shaanxi Dideu New Materials Co. Ltd

Product: JackiePhos Pd G3 2102544-35-2
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000kg
Release date: 2025-05-16

XINXIANG RUNYU MATERIAL CO., LTD.

Product: JackiePhos Palladacycle Gen.3 2102544-35-2
Price: US $0.00-0.00/g
Min. Order: 1g
Purity: 98%
Supply Ability: 100g
Release date: 2024-04-25

2102544-35-2, [(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonateRelated Search:

[(2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphine}-3,6-dimethoxy- 2′,4′,6′- triisopropyl-1,1′-biphenyl )-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

JackiePhos Pd G3

JackiePhos-Pd-G3

Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [JackiePhos Palladacycle Gen. 3]

Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2'',4'',6''-tri-i-propyl-1,1''-biphenyl](2''-amino-1,1''-biphenyl-2-yl)palladium(II)

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][bis[3,5-bis(trifluoromethyl)phenyl][3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium

Methanesulfonicacid[1,2-bis(3,5-bis(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl(2'-amino-1,1'-biphenyl-2-yl)palladium(II),JackiePhosPalladacycleGen.3

JackiePhos Palladacycle

JackiePhos Pd G3/Methanesulfonato[2-bis(3,5-di(trifluoromethyl)phenylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)

2102544-35-2

C52H50F12NO5PPdS