1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
- Product Name
- 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
- CAS No.
- 21969-12-0
- Chemical Name
- 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
- Synonyms
- 4-BROMOPHENYL 4-NITROPHENYL SULFIDE;(4-BroMophenyl)(4-nitrophenyl)sulfane;Benzene,1-bromo-4-[(4-nitrophenyl)thio]-;1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
- CBNumber
- CB3306510
- Molecular Formula
- C12H8BrNO2S
- Formula Weight
- 310.17
- MOL File
- Mol file
1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE Property
- Melting point:
- 92-94 °C
- Boiling point:
- 452.2±30.0 °C(Predicted)
- Density
- 1.63±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B698603
- Product name
- 1-[(4-Bromophenyl)sulfanyl]-4-nitrobenzene
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- V4419
- Product name
- 1-[(4-Bromophenyl)sulfanyl]-4-nitrobenzene
- Packaging
- 1g
- Price
- $131
- Updated
- 2021/12/16
- Product number
- 114166
- Product name
- 1-[(4-Bromophenyl)sulfanyl]-4-nitrobenzene
- Purity
- 97%
- Packaging
- 1g
- Price
- $449
- Updated
- 2021/12/16
- Product number
- HCH0099341
- Product name
- 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
- Purity
- 95.00%
- Packaging
- 10MG
- Price
- $679.14
- Updated
- 2021/12/16
- Product number
- V4419
- Product name
- 1-[(4-Bromophenyl)sulfanyl]-4-nitrobenzene
- Packaging
- 25g
- Price
- $891
- Updated
- 2021/12/16
1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE Chemical Properties,Usage,Production
Synthesis
5335-84-2
100-01-6
21969-12-0
General steps: 1. For the solid disulfide (1,2-bis(4-bromophenyl)disulfide) a. To a 10 mL Schlenk tube fitted with a magnetic stirrer, sequentially add 4-nitroaniline (0.2 mmol) and 1,2-bis(4-bromophenyl)disulfide (0.2 mmol). b. Evacuate the reaction tube and backfill with dry nitrogen, repeat this procedure three times to ensure an oxygen-free environment. c. Using a syringe, add acetonitrile (1 mL) followed by L-ascorbic acid (0.5 eq., 20 mg) dissolved in 0.1 mL of DMSO. 2. for liquid disulfide: a. 4-nitroaniline (0.2 mmol) was added to a 10 mL Schlenk tube equipped with a magnetic stirrer. b. Evacuate the reaction tube and backfill with dry nitrogen, repeating this procedure three times to ensure an oxygen-free environment. c. Using a syringe, add acetonitrile (1 mL) followed by disulfide (0.2 mmol or 0.4 mmol) and L-ascorbic acid (0.5 equiv., 20 mg) dissolved in 0.1 mL of DMSO. 3. 3. The reaction mixture was stirred vigorously for 1 min before t-BuONO (0.3 mmol, 36 μL) was added via syringe. 4. The resulting mixture was stirred at 20 °C for 4 hours. 5. After completion of the reaction, the solvent was removed under reduced pressure. 6. The crude product was purified by column chromatography to afford the target product (4-bromophenyl)(4-nitrophenyl) sulfide.
References
[1] Synlett, 2015, vol. 26, # 13, p. 1841 - 1846
1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE Preparation Products And Raw materials
Raw materials
Preparation Products
1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE Suppliers
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 18209
- Advantage
- 56
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 39966
- Advantage
- 60
- Tel
- 400-685-9117
- Fax
- 021-51816740
- market@bepharm.com
- Country
- China
- ProdList
- 15081
- Advantage
- 60
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 025-66113011 13155353615
- Fax
- (7)02557626880
- qzhang@aikonchem.com
- Country
- China
- ProdList
- 15394
- Advantage
- 58
- Tel
- 010-82387566 18001021521;
- Fax
- 82387566-801
- sales@mreda.com.cn
- Country
- China
- ProdList
- 10083
- Advantage
- 58
- Tel
- 0371-63284658 18135795563
- Fax
- QQ:2885349392
- 2885349392@qq.com
- Country
- China
- ProdList
- 9989
- Advantage
- 58
- Tel
- 15210893940; 15116916250
- Fax
- QQ: 237008221
- chemistryliu@163.com
- Country
- China
- ProdList
- 7327
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing1@energy-chemical.com
- Country
- China
- ProdList
- 44894
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44119
- Advantage
- 58