2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE

Product Name: 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE
CAS No.: 169205-95-2
Chemical Name: 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE
Synonyms: AS0056;5Y-0215;5-b]pyridine;ZINC03884049;BUTTPARK 17\09-03;7-BroMo-3H-iMidazo[4;2-(Methylthio)oxazolo[4;7-broMo-2-Methyl-3H-iMidazo[4;2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE;2-Methylsulfanyl-oxazolo[5,4-b]pyridine
CBNumber: CB3306752
Molecular Formula: C7H6N2OS
Formula Weight: 166.2
MOL File: 169205-95-2.mol

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2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE Property

Melting point:: 59-62°
Boiling point:: 288.5±32.0 °C(Predicted)
Density: 1.35±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: -0.41±0.50(Predicted)
Appearance: White to yellow Solid

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Safety

Hazard Codes: Xn
Risk Statements: 22-36
Safety Statements: 26
HazardClass: IRRITANT
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M219180
Product name: 2-(Methylthio)oxazolo[4,5-b]pyridine
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 044924
Product name: 2-(Methylsulfanyl)[1,3]oxazolo[4,5-b]pyridine
Purity: >95%
Packaging: 500mg
Price: $181
Updated: 2021/12/16

Matrix Scientific

Product number: 044924
Product name: 2-(Methylsulfanyl)[1,3]oxazolo[4,5-b]pyridine
Purity: >95%
Packaging: 1g
Price: $228
Updated: 2021/12/16

AK Scientific

Product number: W3685
Product name: 2-Methylsulfanyl-oxazolo[5,4-b]pyridine
Packaging: 5g
Price: $486
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0027683
Product name: 2-METHYL SULFANYL-OXAZOLO[5,4-B]PYRIDINE
Purity: 95.00%
Packaging: 5MG
Price: $504.94
Updated: 2021/12/16

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2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE Chemical Properties,Usage,Production

Synthesis

53052-06-5

74-88-4

169205-95-2

Step 2: Preparation of 2-(methylthio)oxazolo[4,5-b]pyridine To a stirred solution of oxazolo[4,5-b]pyridine-2(3H)-thione (3.0 g, 19.73 mmol) in ethyl acetate (30 mL) at room temperature was sequentially added potassium carbonate (3.81 g, 27.62 mmol) and iodomethane (3.08 g, 21.71 mmol). The reaction mixture was stirred overnight at room temperature. After completion of the reaction, the mixture was diluted with water (100 mL) and extracted with ethyl acetate (2 x 50 mL). The organic phases were combined, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give 2-methylthiooxazolo[4,5-b]pyridine (3.0 g, 93.75% yield). 1H NMR (CDCl3, 300 MHz): δ 8.46-8.44 (d, 1H), 7.71-7.68 (d, 1H), 7.20-7.15 (m, 1H), 2.81 (s, 3H). LCMS: m/z 167.0 [M + H]+.

References

[1] Patent: WO2015/104688, 2015, A1. Location in patent: Page/Page column 36
[2] Patent: US2016/340366, 2016, A1. Location in patent: Paragraph 0207; 0208
[3] Journal of Organic Chemistry, 1995, vol. 60, # 17, p. 5721 - 5725
[4] Ultrasonics Sonochemistry, 2010, vol. 17, # 5, p. 783 - 788
[5] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 5, p. 2075 - 2078

2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE Suppliers

China 76 China Hong Kong 1 Germany 2 India 1 United Kingdom 3 United States 10 Global 93

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Xunteng International Trading Co.,Limited

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View Lastest Price from 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE manufacturers

Career Henan Chemical Co

Product: 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE 169205-95-2
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-12

169205-95-2, 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINERelated Search:

Lincomycin 2-(METHYLTHIO)OXAZOLO[5,4-C]PYRIDINE BUTTPARK 18\09-09 BUTTPARK 17\09-04 2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE BUTTPARK 18\09-08 BUTTPARK 18\09-10 BUTTPARK 17\09-01 BUTTPARK 24\09-26 BUTTPARK 24\09-25 BUTTPARK 18\09-07 BUTTPARK 17\09-02

2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE

2-(METHYLSULFANYL)[1,3]OXAZOLO[4,5-B]PYRIDINE

BUTTPARK 17\09-03

2-(Methylthio)[1,3]oxazolo[4,5-b]pyridine

2-Methylsulfanyl-oxazolo[5,4-b]pyridine

2-(Methylthio)oxazolo[4

5-b]pyridine

7-BroMo-3H-iMidazo[4

7-broMo-2-Methyl-3H-iMidazo[4

2-(Methylsulfanyl)oxazolo[4,5-b]pyridine

5Y-0215

AS0056

ZINC03884049

Oxazolo[4,5-b]pyridine, 2-(methylthio)-

2-(METHYLTHIO)OXAZOLO[4,5-B]PYRIDINE 169205-95-2

169205-95-2

Heterocycle-Pyridine series

CHIRAL CHEMICALS