NICKEL SULFIDE

NICKEL SULFIDE Property

Melting point:

797°C

Density 

5,3 g/cm³

storage temp. 

2-8°C, protect from light, stored under nitrogen

solubility 

insoluble in H2O

form 

Powder

color 

black

Specific Gravity

5.3～5.65

Water Solubility 

0.00036g/100mL H2O (18°C) [CRC10]

EPA Substance Registry System

Nickel sulfide (NiS) (16812-54-7)

Safety

Hazard Codes 

T,N

Risk Statements 

43-49-50/53

Safety Statements 

45-53-61-60

RIDADR 

2811

HazardClass 

9

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H341Suspected of causing genetic defects

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P281Use personal protective equipment as required.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

P314Get medical advice/attention if you feel unwell.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

P501Dispose of contents/container to..…

NICKEL SULFIDE Chemical Properties,Usage,Production

Chemical Properties

black powder(s); trig, yellow metallic luster; enthalpy of fusion 30.10 kJ/mol; can be formed by fusing Ni powder(s) and molten sulfur; other sulfides include Ni2S, 12137-08-5, Ni3S2, 12035-72-2 (heazlewoodite), NiS2, 12035-51-7, and Ni3S, 12137-12-1 (polydymite) [KIR81] [STR93] [CRC10] [JAN85]

Preparation

The black nickel sulphide precipitated from nickel(II) salt solutions by ammonium sulphide in neutral but not strongly acid solution is the so-called α-NiS ; it consists largely of amorphous Ni(SH,OH)2 when first precipitated. At low pH this crystallizes to give mainly the rhombohedral γ-NiS, while at higher pH the hexagonal β-NiS(Ni_1-XS) crystallizes.

Flammability and Explosibility

Non flammable

Safety Profile

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of SOx. See also NICKEL COMPOUNDS and SULFIDES.