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ChemicalBook > CAS DataBase List > 3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole

3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole

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Product Name
3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole
CAS No.
1246888-90-3
Chemical Name
3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole
Synonyms
rac-BI-DIME;ZJ-0011;3-tert-butyl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphole;3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole;3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole;1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-;ZJ-0011/3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;rac-BIDIME, 3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole;3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%RAC-BI-DIME
CBNumber
CB33340348
Molecular Formula
C19H23O3P
Formula Weight
330.36
MOL File
1246888-90-3.mol
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3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole Property

Boiling point:
422.1±45.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
light-yellow
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-6205
Product name
3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% rac-BI-DIME
Purity
min. 97% rac-BI-DIME
Packaging
250mg
Price
$58
Updated
2024/03/01
Strem Chemicals
Product number
15-6205
Product name
3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% rac-BI-DIME
Purity
min. 97% rac-BI-DIME
Packaging
1g
Price
$172
Updated
2024/03/01
Strem Chemicals
Product number
15-6205
Product name
3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% rac-BI-DIME
Purity
min. 97% rac-BI-DIME
Packaging
5g
Price
$687
Updated
2024/03/01
ChemScene
Product number
CS-0020500
Product name
rac-BI-DIME
Purity
≥98.0%
Packaging
10g
Price
$1230
Updated
2021/12/16
ChemScene
Product number
CS-0020500
Product name
rac-BI-DIME
Purity
≥98.0%
Packaging
5g
Price
$629
Updated
2021/12/16
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3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole Chemical Properties,Usage,Production

Reaction

  1. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling
  2. reactions.
  3. Ligand/palladium catalyst for sterically demanding Buchwald-Hartwig amination.
  4. Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions.
  5. Ligand/nickel catalyst for asymmetric intramolecular reductive cyclization
  6. Ligand/rhodium catalyst for asymmetric hydroboration

3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole Suppliers

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1246888-90-3, 3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphospholeRelated Search:


  • 3-(tert-butyl)-4- (2,6-dimethoxyphenyl) -2,3-dihydrobenzo [d][1,3]oxaphosphole
  • 3-(T-BUTYL)-4-(2,6-DIMETHOXYPHENYL)-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,MIN.97%RAC-BI-DIME
  • 4-(2,6-Dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-1,3-benzoxaphosphole
  • ZJ-0011
  • rac-BIDIME, 3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • rac-BI-DIME
  • 1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-
  • ZJ-0011/3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
  • 3-tert-butyl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphole
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