2-IODO-9H-FLUORENE
- Product Name
- 2-IODO-9H-FLUORENE
- CAS No.
- 2523-42-4
- Chemical Name
- 2-IODO-9H-FLUORENE
- Synonyms
- Iodoluorene;Iodofluorene;2-IODO-9H-FL;2-IODOFLUORENE;2-Iodofluorene>2-IODO-9H-FLUORENE;3-Iodoethylbenzene;2-IODOFLUORENE 97%;9H-Fluorene, 2-iodo-;2-iodanyl-9H-fluorene
- CBNumber
- CB3343162
- Molecular Formula
- C13H9I
- Formula Weight
- 292.11
- MOL File
- 2523-42-4.mol
2-IODO-9H-FLUORENE Property
- Melting point:
- 126-129 °C
- Boiling point:
- 375.6±21.0 °C(Predicted)
- Density
- 1.714±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Orange to Green
- InChI
- InChI=1S/C13H9I/c14-11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H2
- InChIKey
- VNYQUOAQPXGXQO-UHFFFAOYSA-N
- SMILES
- C1C2=C(C=CC=C2)C2=C1C=C(I)C=C2
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
H320Causes eye irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P391Collect spillage. Hazardous to the aquatic environment
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 653918
- Product name
- 2-Iodofluorene
- Purity
- 98%
- Packaging
- 1g
- Price
- $136
- Updated
- 2023/06/20
- Product number
- 653918
- Product name
- 2-Iodofluorene
- Purity
- 98%
- Packaging
- 5g
- Price
- $194
- Updated
- 2023/06/20
- Product number
- I0793
- Product name
- 2-Iodofluorene
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $49
- Updated
- 2025/07/31
- Product number
- I0793
- Product name
- 2-Iodofluorene
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $237
- Updated
- 2025/07/31
- Product number
- I736008
- Product name
- 2-Iodo-9H-fluorene
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
2-IODO-9H-FLUORENE Chemical Properties,Usage,Production
Chemical Properties
White powder
Synthesis
86-73-7
2523-42-4
Example 1 Synthesis of 2-iodofluorene: 90 mL of glacial acetic acid and 90 mL of water were added to a 300 mL four-necked flask, followed by the addition of 41.6 g (0.25 mole) of fluorene. Under vigorous stirring, 12.7 g (0.10 mol) of iodine, 1.93 g (0.018 mol) of sodium chlorate and 4.5 mL of concentrated sulfuric acid were added sequentially. The reaction mixture was refluxed at 85 to 90 °C for 30 min, followed by warming to 95 to 100 °C to continue refluxing for 30 min. Upon completion of the reaction, the reaction mixture was extracted with 55 mL of toluene. The organic layer was washed sequentially with 5% aqueous sodium thiosulfate solution and 50 mL of 20% brine solution. 216 mL of methanol was added to the organic layer and the mixture was crystallized at an internal temperature of 25 to 30 °C for 2 h. The crystals were collected by filtration. The crude product was washed with 76 mL of methanol, and 24.8 g (yield: 84.8%) of 2-iodofluorene was obtained as white crystals after drying.HPLC analytical conditions: the column was YMC-A-312, the detection wavelength was 254 nm, the flow rate was 1.0 mL/min, the eluent was methanol/water (9:1, v/v/v), and the buffer was a solution containing 0.1% triethylamine and acetic acid. The analytical results showed that the product composition was 1.3% fluorene, 98.4% 2-iodofluorene and 0.02% 2,7-diiodofluorene.
References
[1] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 439 - 443
[2] New Journal of Chemistry, 2015, vol. 39, # 5, p. 4086 - 4092
[3] Patent: US6437203, 2002, B1
[4] Organic Electronics: physics, materials, applications, 2014, vol. 15, # 7, p. 1324 - 1337
[5] Journal of Materials Chemistry, 2012, vol. 22, # 12, p. 5319 - 5329
2-IODO-9H-FLUORENE Preparation Products And Raw materials
Raw materials
Preparation Products
2-IODO-9H-FLUORENE Suppliers
- Tel
- --
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- Country
- Ukraine
- ProdList
- 130
- Advantage
- 58
View Lastest Price from 2-IODO-9H-FLUORENE manufacturers
- Product
- 2-IODO-9H-FLUORENE 2523-42-4
- Price
- US $10.00/KG
- Min. Order
- 100KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-28
- Product
- 2-Iodofluorene 2523-42-4
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 300MT/year
- Release date
- 2019-12-24
- Product
- 2-Iodo-9H-fluorene 2523-42-4
- Price
- US $18.00-204.00/g
- Min. Order
- 5g
- Purity
- 0.97
- Supply Ability
- 25kg
- Release date
- 2023-12-07