ChemicalBook > CAS DataBase List > CALCIUM SULFIDE

CALCIUM SULFIDE

Product Name
CALCIUM SULFIDE
CAS No.
20548-54-3
Chemical Name
CALCIUM SULFIDE
Synonyms
Baumol;Oldhamite;C.I. 77245;thioxocalcium;CALCIUM SULFIDE;Pigment White 9;Calcium-sulphide-;calciumsulfide(cas);Calcium monosulfide;C.I. Pigment White 9
CBNumber
CB3391370
Molecular Formula
CaHS
Formula Weight
73.15
MOL File
20548-54-3.mol
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CALCIUM SULFIDE Property

Melting point:
2000 °C
Density 
2.6
refractive index 
2.12
solubility 
slightly soluble in H2O; insoluble in ethanol
form 
Powder
Specific Gravity
2.5
color 
White
Water Solubility 
Slightly soluble in water. Insoluble in alcohol.
Sensitive 
Moisture Sensitive
Merck 
14,1707
CAS DataBase Reference
20548-54-3(CAS DataBase Reference)
EPA Substance Registry System
Calcium sulfide (CaS) (20548-54-3)
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Safety

Hazard Codes 
Xi,N
Risk Statements 
31-36/37/38-50
Safety Statements 
28-61
RIDADR 
UN 3179 4.1/PG 2
WGK Germany 
2
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
409553
Product name
Calcium sulfide
Purity
325mesh, ≥99.9% trace metals basis
Packaging
10g
Price
$782
Updated
2023/01/07
Alfa Aesar
Product number
013121
Product name
Calcium sulfide, 99.9% (metals basis excluding Sr), Sr typically 500 ppm
Packaging
5g
Price
$65.4
Updated
2024/03/01
Alfa Aesar
Product number
013121
Product name
Calcium sulfide, 99.9% (metals basis excluding Sr), Sr typically 500 ppm
Packaging
25g
Price
$258
Updated
2023/06/20
Strem Chemicals
Product number
93-2047
Product name
Calcium sulfide (99.9+%-Ca)
Packaging
10g
Price
$78
Updated
2024/03/01
Strem Chemicals
Product number
93-2047
Product name
Calcium sulfide (99.9+%-Ca)
Packaging
50g
Price
$316
Updated
2024/03/01
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CALCIUM SULFIDE Chemical Properties,Usage,Production

Chemical Properties

CALCIUM SULFIDE is OFF-WHITE POWDER

Physical properties

Calcium sulfide is slightly soluble in water but insoluble in alcohol. It reacts with acids, producing hydrogen sulfide gas. Calcium sulfide is pale yellow to light gray with a bitter taste. It is hygroscopic, producing an odor of H2S in moist air.

Occurrence

Calcium sulfide occurs in nature as the mineral oldhamite. It has several applications. The ‘luminous’ calcium sulfide is used in phosphors, luminous paints and varnishes. Calcium sulfide also is used as an additive to lubri cants; and as a flotation agent in ore extraction.

Uses

Calcium sulfide is used in phosphors, lubricant additives and luminous paints. It reacts with elemental sulfur to give a lime-sulfur. Further, it is used in ore dressing and flotation agent. In addition to this, it is used as a depilatory in the tanning industry and in cosmetics.

Uses

Calcium sulfide may be used to remove heavy metals from wastewater.

Uses

CALCIUM SULFIDE is used in electron emitters. Luminous CaS used for making luminous paints or varnishes.

Preparation

Calcium sulfide can be prepared by the direct reaction of the elements, calcined in an inert atmosphere, at a 1:1.05 molecular ratio:
Ca+S+heat→CaS
This white material crystallizes in a cubic structurelike rock salt and the bonding is highly ionic. This is consistent with its description as an ionic solid. CaS can also be produced by the “carbothermic reduction” of calcium sulfate, which entails the conversion of carbon, usually as charcoal, to CO2:
CaSO4+ 2C→CaS+ 2CO2
This can react further:
3CaSO4+ CaS→4CaO+ 4SO2
Thus, this type of preparation cannot be used to prepare a pure CaS salt.
Calcium sulfide is available commercially as the pure sulfide as well as the polysulfide due to its extensive usage in the past as an insecticide both agriculturally and in home gardens.

General Description

Crystal structure of CaS is cubic. Electrical conductivity of calcium sufide in the temperature range of 650oC-1000oC was studied in great detail. It was concluded that CaS could be used as a potential electrolyte in a sulfur concentration cell.2

CALCIUM SULFIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CALCIUM SULFIDE Suppliers

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View Lastest Price from CALCIUM SULFIDE manufacturers

Hebei Saisier Technology Co., LTD
Product
CALCIUM SULFIDE 20548-54-3
Price
US $6.00/KG
Min. Order
25KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-03-28
Shandong Juchuang Chemical Co., LTD
Product
Sulfide hair remover 20548-54-3
Price
US $7.00-2.00/kg
Min. Order
500kg
Purity
99.9
Supply Ability
200tons
Release date
2024-03-14
Hebei Jingbo New Material Technology Co., Ltd
Product
CALCIUM SULFIDE 20548-54-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000000
Release date
2024-01-08

20548-54-3, CALCIUM SULFIDERelated Search:


  • CALCIUM SULFIDE
  • Calcium sulfide (CaS)
  • calciumsulfide(cas)
  • Calcium-sulphide-
  • Calcium sulfide, #325 mesh, 99.9+% metals basis
  • Calcium sulfide, -325 mesh, pure, 99.9+%
  • CALCIUM SULFIDE, 99.99%
  • Calciumsulfide(99.9+%-Ca)
  • CALCIUM SULFIDE , -45 MICRON
  • Calcium sulfide,99.9+%,pure,-325 mesh
  • Calcium sulfide, 99% (metals basis excluding Mg), Mg <1%
  • Calcium sulfide, 99.9% (metals basis excluding Sr), Sr typically 500 ppm
  • Calcium sulfide, 99.95+% (metals basis excluding Sr), Sr typically 500 ppm
  • Oldhamite
  • Baumol
  • C.I. 77245
  • C.I. Pigment White 9
  • Calcium monosulfide
  • Pigment White 9
  • Calcium sulfide, 99% trace metals basis excluding Mg
  • Calcium sulfide, 99.9% trace metals basis
  • CALCIUM SULFIDE, LUMINOUS
  • sulfanylidenecalcium
  • thioxocalcium
  • Sulfide hair remover
  • 20548-54-3
  • Catalysis and Inorganic Chemistry
  • metal chalcogenides
  • Inorganics
  • CalciumMaterials Science
  • Catalysis and Inorganic Chemistry
  • Chalcogenides
  • Chemical Synthesis
  • Metal and Ceramic Science