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ETHYNYL P-TOLYL SULFONE

Product Name
ETHYNYL P-TOLYL SULFONE
CAS No.
13894-21-8
Chemical Name
ETHYNYL P-TOLYL SULFONE
Synonyms
1-(ethynylsulfonyl)-4-Methylbenzene;TOSYLACETYLENE;ETHYNYL P-TOLYL SULFONE;Ethynylp-TolylSulfone>p-tolylsulfonylacetylene;4-(Ethynylsulfonyl)toluene;P-TOLUENESULFONYLACETYLENE;Ethynyl p-Tolyl Sulfone;Benzene, 1-(ethynylsulfonyl)-4-methyl-;p-Toluenesulfonylacetylene, Tosylacetylene
CBNumber
CB3427572
Molecular Formula
C9H8O2S
Formula Weight
180.22
MOL File
13894-21-8.mol
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ETHYNYL P-TOLYL SULFONE Property

Melting point:
73-74 °C (lit.)
Boiling point:
297.9±33.0 °C(Predicted)
Density 
1.219±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
organic solvents: soluble(lit.)
form 
powder to crystal
color 
White to Light yellow
BRN 
2556169
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29041000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
419869
Product name
Ethynyl p-tolyl sulfone
Purity
98%
Packaging
1g
Price
$110
Updated
2024/03/01
TCI Chemical
Product number
E0466
Product name
Ethynyl p-Tolyl Sulfone
Purity
>98.0%(GC)
Packaging
1g
Price
$172
Updated
2024/03/01
TCI Chemical
Product number
E0466
Product name
Ethynyl p-Tolyl Sulfone
Purity
>98.0%(GC)
Packaging
5g
Price
$547
Updated
2024/03/01
TRC
Product number
E938863
Product name
Ethynyl p-Tolyl Sulfone
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
7929AL
Product name
Ethynyl p-Tolyl Sulfone
Packaging
5g
Price
$343
Updated
2021/12/16
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ETHYNYL P-TOLYL SULFONE Chemical Properties,Usage,Production

Uses

Ethynyl p-tolyl sulfone (Tosylacetylene) may be used in the synthesis of 2-(4-methylphenylsulfonyl)ethenyl (tosvinyl, Tsv) protected derivatives. It may be used as starting reagent for the synthesis of optically active indan-2-ols.

Synthesis Reference(s)

The Journal of Organic Chemistry, 57, p. 697, 1992 DOI: 10.1021/jo00028a053

Purification Methods

Recrystallise the sulfone from pet ether, *C6H6 or EtOH (m 66o), and dry it in a vacuum. [Beilstein 6 III 1397, 6 IV 2160.]

ETHYNYL P-TOLYL SULFONE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYNYL P-TOLYL SULFONE Suppliers

J & K SCIENTIFIC LTD.
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TCI (Shanghai) Development Co., Ltd.
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Syntechem Co.,Ltd
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13894-21-8, ETHYNYL P-TOLYL SULFONERelated Search:


  • 1-(ethynylsulfonyl)-4-Methylbenzene
  • Ethynyl <i>p</i>-Tolyl Sulfone
  • ETHYNYL P-TOLYL SULFONE
  • P-TOLUENESULFONYLACETYLENE
  • TOSYLACETYLENE
  • p-Toluenesulfonylacetylene, Tosylacetylene
  • p-tolylsulfonylacetylene
  • Ethynylp-TolylSulfone&gt
  • 4-(Ethynylsulfonyl)toluene
  • Benzene, 1-(ethynylsulfonyl)-4-methyl-
  • 13894-21-8
  • CH3C6H4SO2C8801CH
  • C9H8O2S
  • Sulfur Compounds
  • Sulfones
  • Organic Building Blocks
  • Acetylenes
  • Sulfur Compounds (for Synthesis)
  • Functionalized Acetylenes
  • Building Blocks
  • Acetylenes
  • Functionalized Acetylenes
  • Sulfur Compounds (for Synthesis)
  • Synthetic Organic Chemistry