1-PHENYL-1-CYCLOPROPANECARBONITRILE
- Product Name
- 1-PHENYL-1-CYCLOPROPANECARBONITRILE
- CAS No.
- 935-44-4
- Chemical Name
- 1-PHENYL-1-CYCLOPROPANECARBONITRILE
- Synonyms
- 1-Phenylcyclopropyl Cyanide;1-Cyano-1-phenylcyclopropane;1-PHENYLCYCLOPROPANECARBONITRILE;1-Phenylcyclopropan-carbonitrile;1-PHENYL-1-CYCLOPROPANECARBONITRILE;1-Phenyl-1-cyclopeopanecarbonitrile;Cyclopropanecarbonitrile, 1-phenyl-;1-Phenylcyclopropane-1-carbonitrile;1-phenyl-1-cyclopropyl methylonitrile;1-Phenyl-1-cyclopropanecarbonitrile,97%
- CBNumber
- CB3430930
- Molecular Formula
- C10H9N
- Formula Weight
- 143.19
- MOL File
- 935-44-4.mol
1-PHENYL-1-CYCLOPROPANECARBONITRILE Property
- Boiling point:
- 133-137 °C30 mm Hg(lit.)
- Density
- 1 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.539(lit.)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- Specific Gravity
- 1.000
- color
- Clear colorless to slightly yellow
- InChI
- InChI=1S/C10H9N/c11-8-10(6-7-10)9-4-2-1-3-5-9/h1-5H,6-7H2
- InChIKey
- ZHFURHRJUWYDKG-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)(C#N)CC1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- P2323
- Product name
- 1-Phenylcyclopropanecarbonitrile
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $40
- Updated
- 2021/12/16
- Product number
- P2323
- Product name
- 1-Phenylcyclopropanecarbonitrile
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $136
- Updated
- 2021/12/16
- Product number
- P336620
- Product name
- 1-Phenylcyclopropanecarbonitrile
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- Z2339
- Product name
- 1-Phenyl-cyclopropane-carbonitrile
- Packaging
- 5g
- Price
- $99
- Updated
- 2021/12/16
- Product number
- 084527
- Product name
- 1-Phenylcyclopropanecarbonitrile
- Purity
- 97%
- Packaging
- 1g
- Price
- $120
- Updated
- 2021/12/16
1-PHENYL-1-CYCLOPROPANECARBONITRILE Chemical Properties,Usage,Production
Chemical Properties
Clear colorless to slightly yellow liquid
Synthesis
140-29-4
106-93-4
935-44-4
Step 1: Preparation of 1-phenylcyclopropanecarbonitrile To a stirred mixture of phenylacetonitrile (100 g, 0.8547 mol) dissolved in aqueous KOH (447 g, dissolved in 420 mL of water) and 2.7 g of tetrabutylammonium bromide, 1,2-dibromoethane (147 mL, 1.709 mol) was added slowly dropwise, with the rate of dropwise acceleration being controlled to maintain the temperature of the reaction at 50 °C. After the dropwise addition was completed, the reaction mixture was continued to be stirred at 50 °C for 1 hour. Upon completion of the reaction, the mixture was poured into cold water and extracted with diisopropyl ether. The organic phases were combined and the crude product was purified by high vacuum distillation to give 90 g of colorless liquid 1-phenylcyclopropane carbonitrile in 73% yield.
References
[1] Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, # 10, p. 1775 - 1779
[2] Zhurnal Organicheskoi Khimii, 1980, vol. 16, # 10, p. 2086 - 2091
[3] Tetrahedron Letters, 2006, vol. 47, # 23, p. 3871 - 3874
[4] Patent: WO2011/61760, 2011, A1. Location in patent: Page/Page column 17-18
[5] Organic Letters, 2015, vol. 17, # 20, p. 4944 - 4947
1-PHENYL-1-CYCLOPROPANECARBONITRILE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1-PHENYL-1-CYCLOPROPANECARBONITRILE manufacturers
- Product
- 1-Phenylcyclopropanecarbonitrile 935-44-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.3%
- Supply Ability
- 100 tons
- Release date
- 2022-02-21
- Product
- 1-PHENYL-1-CYCLOPROPANECARBONITRILE 935-44-4
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-09