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(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE

Product Name
(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE
CAS No.
24774-61-6
Chemical Name
(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE
Synonyms
Dimethylbromomethyleneammonium Bromide;(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE;(BROMOMETHYLENE)DIMETHYLAMMONIUM BROMIDE;bromomethylidene(dimethyl)azanium,bromide;(Bromomethylene)dimethyliminiumbromide95+%;(Bromomethylene)dimethyliminium bromide 95%;N-(bromomethylene)-N-methylmethanaminium bromide
CBNumber
CB3458644
Molecular Formula
C3H7Br2N
Formula Weight
216.9
MOL File
24774-61-6.mol
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(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE Property

Melting point:
148-153 °C (lit.)
BRN 
4155730
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37
WGK Germany 
3
10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
411531
Product name
(Bromomethylene)dimethyliminium bromide
Purity
95%
Packaging
25g
Price
$152.8
Updated
2024/03/01
Oakwood
Product number
099927
Product name
(Bromomethylene)dimethyliminium bromide
Purity
95%
Packaging
5g
Price
$120
Updated
2021/12/16
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(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE Chemical Properties,Usage,Production

Uses

(Bromomethylene)dimethyliminium bromide (bromodi- methylformiminium bromide) may be employed for the synthesis of 6-phenyl-6-deoxy-2,3-di-O-methylcellulose.

General Description

(Bromomethylene)dimethyliminium bromide participates in one-carbon homologation of aldehydes to carboxylic acid derivatives.

Synthesis

Dimethylbromomethyleneammonium Bromide can be synthesized by adding Phosphorus(III) Bromide slowly to DMF in chloroform. It is more reactive than the bromide salt, which has been accounted for by a rapid exchange of the bromide and dibromophosphate anions.

Precautions

(Bromomethylene)dimethyliminium bromide is corrosive, air-sensitive, and lachrymatory, and must be treated with caution.

(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE Suppliers

Energy Chemical
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Sigma-Aldrich
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24774-61-6, (BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDERelated Search:


  • (BROMOMETHYLENE)DIMETHYLAMMONIUM BROMIDE
  • (BROMOMETHYLENE)DIMETHYLIMINIUM BROMIDE
  • (Bromomethylene)dimethyliminiumbromide95+%
  • N-(bromomethylene)-N-methylmethanaminium bromide
  • Dimethylbromomethyleneammonium Bromide
  • bromomethylidene(dimethyl)azanium,bromide
  • (Bromomethylene)dimethyliminium bromide 95%
  • 24774-61-6
  • BrCHNCH32Br
  • C3H7BrNBr
  • C3H7Br2N
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  • C-C Bond Formation
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  • C-C Bond Formation
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  • Imines/Amidines
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