ChemicalBook > CAS DataBase List > IRON DODECACARBONYL

IRON DODECACARBONYL

Product Name
IRON DODECACARBONYL
CAS No.
17685-52-8
Chemical Name
IRON DODECACARBONYL
Synonyms
Fe3(CO)12;Triiron dodecarbonyl;IRON DODECARBONYL;IRON DODECACARBONYL;DODECACARBONYLTRIIRON;TRIIRON DODECACARBONYL;TRIIRON(0) DODECACARBONYL;stabilisedwith5-10%methanol;Triiron dodecacarbonyl,99%,stabilized;Triiron dodecacarbonyl, stabilized, 99%
CBNumber
CB3467620
Molecular Formula
C12H24FeO12
Formula Weight
416.15676
MOL File
17685-52-8.mol
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IRON DODECACARBONYL Property

Melting point:
165 °C (dec.) (lit.)
Density 
1.99
Flash point:
9℃
storage temp. 
2-8°C
form 
crystal
Specific Gravity
2
color 
black
Water Solubility 
Insoluble in water. Soluble in non polar organic solvents.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
NIST Chemistry Reference
Triiron dodecacarbonyl(17685-52-8)
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Safety

Hazard Codes 
F,Xn,T
Risk Statements 
11-23/24/25-36/37/38-20/22-39/23/24/25-20/21/22
Safety Statements 
16-26-28-33-36/37/39-45-7/9-24-36/37
RIDADR 
UN 3175 4.1/PG 2
WGK Germany 
3
F 
10-23
HazardClass 
6.1
PackingGroup 
II
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
381411
Product name
Triirondodecacarbonyl
Purity
contains 1-10% methyl alcohol
Packaging
5g
Price
$80.7
Updated
2024/03/01
Sigma-Aldrich
Product number
381411
Product name
Triirondodecacarbonyl
Purity
contains 1-10% methyl alcohol
Packaging
25g
Price
$248
Updated
2024/03/01
Alfa Aesar
Product number
013059
Product name
Dodecacarbonyltriiron, 96% (dry wt.), stab. with 5-10% methanol
Packaging
10g
Price
$79.65
Updated
2024/03/01
Alfa Aesar
Product number
013059
Product name
Dodecacarbonyltriiron, 96% (dry wt.), stab. with 5-10% methanol
Packaging
2g
Price
$29
Updated
2023/06/20
Strem Chemicals
Product number
26-2500
Product name
Iron dodecacarbonyl (Stabilized with 5-10% methanol)
Packaging
10g
Price
$113
Updated
2024/03/01
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IRON DODECACARBONYL Chemical Properties,Usage,Production

Chemical Properties

black powder or crystals

Uses

It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.

Uses

Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.

General Description

This product has been enhanced for catalytic efficiency.

Purification Methods

It usually contains 10% by weight of MeOH as stabiliser. This can be removed by keeping it in a vacuum at 0.5mm for at least 5hours. It can be sublimed slowly at high vacuum and is soluble in organic solvents. [Landesberg et al. J Org Chem 37 930 1972, Case & Whiting J Chem Soc 4632 1960, King & Stone Inorg Synth VII 193 1963.] TOXIC.

IRON DODECACARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products

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IRON DODECACARBONYL Suppliers

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17685-52-8, IRON DODECACARBONYLRelated Search:

Iron chloride hexahydrate Iridium(III) chloride hydrate Tungsten hexacarbonyl Iron Iron dodecacarbonyl, stabilised with 5-10% methanol, 95% IRON DODECACARBONYL, FE3(CO)12 IRON DODECACARBONYL

  • Dodecacarbonyltriiron, 95+% (Assay on dry basis), stab. with 5-10% methanol
  • Triiron dodecacarbonyl, stabilized, 99%
  • Iron dodecacarbonyl(Stabilized with 5-10% methanol)
  • di-mu-carbonyldecacarbonyl-triangulo-triiron
  • TRIIRON DODECACARBONYL, PROTECTED WITH 5 -10% METHYL ALCOHOL
  • TRI-IRONDODECACARBONYL MOISTENED WITH ME THANOL(CH3OH 5-10%
  • stabilisedwith5-10%methanol
  • IRON DODECACARBONYL
  • IRON DODECARBONYL
  • DODECACARBONYLTRIIRON
  • TRIIRON(0) DODECACARBONYL
  • TRIIRON DODECACARBONYL
  • Fe3(CO)12
  • Iron, di-mu-carbonyldecacarbonyltri-, triangulo
  • Triiron dodecacarbonyl,99%,stabilized
  • Dodecacarbonyltriiron, 96% (dry wt.), stab. with 5-10% methanol
  • Triiron dodecarbonyl
  • Triirondodecacarbonyl contains 1-10% methyl alcohol
  • Triiron dodecacarbonyl, stabilized, 99% 5GR
  • Dodecacarbonyltriiron, 96% dry weight, may contain varying amounts of methanol
  • IRON DODECACARBONYL ISO 9001：2015 REACH
  • Iron, di-m-carbonyldecacarbonyltri-,triangulo
  • 17685-52-8
  • Catalysis and Inorganic Chemistry
  • metal carbonyl complexes