ChemicalBook > CAS DataBase List > 2-Methyl-2-nitropropan-1-ol

2-Methyl-2-nitropropan-1-ol

Product Name
2-Methyl-2-nitropropan-1-ol
CAS No.
76-39-1
Chemical Name
2-Methyl-2-nitropropan-1-ol
Synonyms
1-Propanol, 2-methyl-2-nitro-;2-Methyl-2-nitropropanol;2-methyl-2-nitro-1-propano;2-NITRO-2-METHYL-1-PROPANOL;2-METHYL-2-NITRO-1-PROPANOL;2-NITROISOBUTANOL;Methylnitropropanol;methyl-2nitro-2propanol;2-Nitro-2-methylpropanol;2-methyl-2-nitropropan-1-ol
CBNumber
CB3474945
Molecular Formula
C4H9NO3
Formula Weight
119.12
MOL File
76-39-1.mol
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2-Methyl-2-nitropropan-1-ol Property

Melting point:
86-89 °C(lit.)
Boiling point:
94-95 °C10 mm Hg(lit.)
Density 
1.0765 (estimate)
refractive index 
1.4413 (estimate)
pka
13.79±0.10(Predicted)
InChI
InChI=1S/C4H9NO3/c1-4(2,3-6)5(7)8/h6H,3H2,1-2H3
InChIKey
MVGJRISPEUZYAQ-UHFFFAOYSA-N
SMILES
C(O)C(C)([N+]([O-])=O)C
NIST Chemistry Reference
1-Propanol, 2-methyl-2-nitro-(76-39-1)
EPA Substance Registry System
1-Propanol, 2-methyl-2-nitro- (76-39-1)
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Safety

WGK Germany 
3
RTECS 
UB8575000
Hazardous Substances Data
76-39-1(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

AK Scientific
Product number
0231BA
Product name
2-Methyl-2-nitro-1-propanol
Packaging
250mg
Price
$181
Updated
2021/12/16
Matrix Scientific
Product number
159675
Product name
2-Methyl-2-nitropropan-1-ol
Packaging
0.500g
Price
$240
Updated
2021/12/16
Matrix Scientific
Product number
159675
Product name
2-Methyl-2-nitropropan-1-ol
Packaging
1g
Price
$300
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0009071
Product name
2-METHYL-2-NITRO-1-PROPANOL
Purity
95.00%
Packaging
5MG
Price
$499.28
Updated
2021/12/16
Matrix Scientific
Product number
159675
Product name
2-Methyl-2-nitropropan-1-ol
Packaging
5g
Price
$1000
Updated
2021/12/16
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2-Methyl-2-nitropropan-1-ol Chemical Properties,Usage,Production

Uses

The direct hydrogenation of 2-Methyl-2-nitropropan-1-ol obtains product 2-amino-2-methyl-1-propanol (AMP-95). AMP-95 is a kind of multifunction additive being widely known by the people, be widely used in coating and printing ink, metal working fluid, in the industries such as personal nursing and medicine intermediate.

Synthesis

By catalyst 10g (Ti-V-ZSM-5), acetone 58.08g, ammonium hydroxide 20g are added in 400ml methanol, are warming up to 70 DEG C, hydrogen peroxide (35%) 226.7g is slowly added dropwise, temperature is maintained to react 1h at 65-75 DEG C, obtain 2- nitros third after being added dropwise Alkane reaction solution；Filtering adds in 5g sodium hydroxides to reaction solution, is warming up to 35 DEG C, formaldehyde (40% aqueous solution) is added dropwise, drip with the reaction was continued afterwards 3h, obtains 2-Methyl-2-nitropropan-1-ol.

Purification Methods

Distil it under vacuum and/or crystallise it from pet ether or MeOH. [Astle & Abbott J Org Chem 21 1229 1956, Kambe & Yasuda Bull Soc Chem Jpn 41 1444 1968, Beilstein 1 H 378, 1 III 1546, 1 IV 1604.]

2-Methyl-2-nitropropan-1-ol Preparation Products And Raw materials

Raw materials

Preparation Products

2-Amino-2-methyl-1-propanol 1,2-DIAMINO-2-METHYLPROPANE
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2-Methyl-2-nitropropan-1-ol Suppliers

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