4-BUTOXY-3-FLUOROPHENYLBORONIC ACID

Product Name: 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
CAS No.: 156487-13-7
Chemical Name: 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
Synonyms: Boronic acid, B-(4-butoxy-3-fluorophenyl)-
CBNumber: CB3498525
Molecular Formula: C10H14BFO3
Formula Weight: 212.03
MOL File: 156487-13-7.mol

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4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Property

Melting point:: 91-96 °C(lit.)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
Appearance: White to off-white Solid

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Safety

WGK Germany: 3
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: B695085
Product name: 4-Butoxy-3-fluorophenylboronicAcid
Packaging: 50mg
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: X1333
Product name: 4-Butoxy-3-fluorophenylboronicacid
Packaging: 1g
Price: $117
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0000648
Product name: 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID
Purity: 95.00%
Packaging: 1G
Price: $210
Updated: 2021/12/16

AK Scientific

Product number: X1333
Product name: 4-Butoxy-3-fluorophenylboronicacid
Packaging: 5g
Price: $317
Updated: 2021/12/16

Crysdot

Product number: CD12137800
Product name: (4-Butoxy-3-fluorophenyl)boronicacid
Purity: 95+%
Packaging: 25g
Price: $582
Updated: 2021/12/16

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4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Chemical Properties,Usage,Production

Synthesis

121-43-7

54509-63-6

156487-13-7

4-Butoxy-3-fluorophenylboronic acid (T-9) was synthesized as follows: 4-bromo-1-butoxy-2-fluorobenzene (T-8) (97.5 g) prepared in the previous step was dissolved in dry tetrahydrofuran (THF) (500 ml) and the solution was cooled to -70 °C. Under nitrogen protection, n-butyllithium (n-BuLi) (241 ml) was slowly added dropwise with continuous stirring for 2 h at a maintained temperature of -70°C. Subsequently, a dry THF solution of trimethyl borate (62.4 g) was slowly added dropwise to the reaction system at the same temperature. The reaction mixture was gradually warmed to room temperature and stirring was continued for 16 hours. After completion of the reaction, 2N hydrochloric acid (HCl) (200 ml) was added to the reaction mixture for acidification. The mixture was extracted with toluene and after separating the organic layer, it was washed sequentially with water and saturated saline and finally dried with anhydrous magnesium sulfate. The organic phase was concentrated under reduced pressure to give a light brown solid product. Purification by recrystallization (solvent ratio: heptane/toluene=4:1, v/v) gave the target compound 4-butoxy-3-fluorophenylboronic acid (T-9) as a colorless powder (54.8 g) in 66% yield.

References

[1] Patent: EP2399896, 2011, A1. Location in patent: Page/Page column 38

4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BUTOXY-3-FLUOROPHENYLBORONIC ACID Suppliers

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View Lastest Price from 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID manufacturers

Career Henan Chemical Co

Product: 4-BUTOXY-3-FLUOROPHENYLBORONIC ACID 156487-13-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-14

156487-13-7, 4-BUTOXY-3-FLUOROPHENYLBORONIC ACIDRelated Search:

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Boronic acid, B-(4-butoxy-3-fluorophenyl)-

156487-13-7

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