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Tris(acetonitrile)tricarbonyltungsten

Product Name
Tris(acetonitrile)tricarbonyltungsten
CAS No.
16800-47-8
Chemical Name
Tris(acetonitrile)tricarbonyltungsten
Synonyms
tris(acetonitrile)tungsten(0);Tris(acetonitryl)tungsten tricarbonyl;tris(acetonitrile)tricarbonyl-tungste;TRIS(ACETONITRILE)TRICARBONYLTUNGSTEN;Tris(acetonitrile)tungsten tricarbonyl;Tricarbonyl tris(acetonitrile)tungsten;tris(acetonitrile)tricarbonyltungsten(0);TRIS(ACETONITRILE)TRICARBONYLTUNGESTEN(&
CBNumber
CB3499678
Molecular Formula
C9H9N3O3W
Formula Weight
391.03
MOL File
16800-47-8.mol
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Tris(acetonitrile)tricarbonyltungsten Property

Melting point:
>300 °C(lit.)
Boiling point:
34°C
solubility 
sol acetonitrile, nitromethane
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Safety

Hazard Codes 
T+
Risk Statements 
26/27/28
Safety Statements 
28-36/37-45-7/9
RIDADR 
UN 3466 6.1/PG 1
WGK Germany 
3
RTECS 
YO7800000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ING0007027
Product name
TRIS(ACETONITRILE)TRICARBONYLTUNGSTEN(0)
Purity
95.00%
Packaging
5G
Price
$867.96
Updated
2021/12/16
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Tris(acetonitrile)tricarbonyltungsten Chemical Properties,Usage,Production

Uses

Catalyst for allylic substitutions

Reactant for:

  • Mixed disilyl-substituted cyclopentadiene derivatives
  • Synthesis of catalytically active ansa compounds with cycloalkyl moieties
  • Stepwise assembly of mixed metal dinuclear carbonyl complexes
  • Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes

Preparation

By refluxing Hexacarbonyltungsten in Acetonitrile in an inert atmosphere. Removal of solvent under an  inert atmosphere yields tris(acetonitrile)tricarbonyltungsten. Solutions of the reagent can be prepared by photolysis of  hexacarbonyltungsten in acetonitrile.

reaction suitability

core: tungsten
reagent type: catalyst

storage

Air and thermally sensitive; pyrophoric. Use in a fume hood.

Tris(acetonitrile)tricarbonyltungsten Preparation Products And Raw materials

Raw materials

Preparation Products

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Tris(acetonitrile)tricarbonyltungsten Suppliers

Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shaanxi Dideu Medichem Co. Ltd
Tel
029-81024372 15029046529
Fax
029-88380327
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1027@dideu.com
Country
China
ProdList
10009
Advantage
58
Energy Chemical
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021-58432009 400-005-6266
Fax
021-58436166
Email
marketing1@energy-chemical.com
Country
China
ProdList
44807
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Changzhou Furuisi Biotechnology Co., Ltd
Tel
0519-85524369
Email
3477467573@qq.com
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China
ProdList
8617
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Pushan Industry (Shaanxi) Co., Ltd.
Tel
029-81310890 13571859809
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info@pushanshiye.com
Country
China
ProdList
10011
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Baoji Funuokang Industrial Co., Ltd
Tel
13220096790; 13220096790
Email
1754423088@qq.com
Country
China
ProdList
2995
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Absin Bioscience Inc.
Tel
--
Fax
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chenjw@absin.cn
Country
CHINA
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Guangzhou WeiBo Chemical Co., Ltd.
Tel
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weibochem@163.com
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China
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Advanced Technology & Industrial Co., Ltd.
Tel
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sales@advtechind.com
Country
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6523
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16800-47-8, Tris(acetonitrile)tricarbonyltungstenRelated Search:


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