ChemicalBook > CAS DataBase List > Tris(acetonitrile)tricarbonyltungsten
Tris(acetonitrile)tricarbonyltungsten
- Product Name
- Tris(acetonitrile)tricarbonyltungsten
- CAS No.
- 16800-47-8
- Chemical Name
- Tris(acetonitrile)tricarbonyltungsten
- Synonyms
- tris(acetonitrile)tungsten(0);Tris(acetonitryl)tungsten tricarbonyl;tris(acetonitrile)tricarbonyl-tungste;TRIS(ACETONITRILE)TRICARBONYLTUNGSTEN;Tris(acetonitrile)tungsten tricarbonyl;Tricarbonyl tris(acetonitrile)tungsten;tris(acetonitrile)tricarbonyltungsten(0);TRIS(ACETONITRILE)TRICARBONYLTUNGESTEN(&
- CBNumber
- CB3499678
- Molecular Formula
- C9H9N3O3W
- Formula Weight
- 391.03
- MOL File
- 16800-47-8.mol
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Tris(acetonitrile)tricarbonyltungsten Property
- Melting point:
- >300 °C(lit.)
- Boiling point:
- 34°C
- solubility
- sol acetonitrile, nitromethane
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Safety
- Hazard Codes
- T+
- Risk Statements
- 26/27/28
- Safety Statements
- 28-36/37-45-7/9
- RIDADR
- UN 3466 6.1/PG 1
- WGK Germany
- 3
- RTECS
- YO7800000
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N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- ING0007027
- Product name
- TRIS(ACETONITRILE)TRICARBONYLTUNGSTEN(0)
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $867.96
- Updated
- 2021/12/16
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Tris(acetonitrile)tricarbonyltungsten Chemical Properties,Usage,Production
Uses
Catalyst for allylic substitutions
Reactant for:
- Mixed disilyl-substituted cyclopentadiene derivatives
- Synthesis of catalytically active ansa compounds with cycloalkyl moieties
- Stepwise assembly of mixed metal dinuclear carbonyl complexes
- Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes
Preparation
By refluxing Hexacarbonyltungsten in Acetonitrile in an inert atmosphere. Removal of solvent under an inert atmosphere yields tris(acetonitrile)tricarbonyltungsten. Solutions of the reagent can be prepared by photolysis of hexacarbonyltungsten in acetonitrile.
reaction suitability
core: tungsten
reagent type: catalyst
storage
Air and thermally sensitive; pyrophoric. Use in a fume hood.
Tris(acetonitrile)tricarbonyltungsten Preparation Products And Raw materials
Raw materials
Preparation Products
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