1-VINYLCYCLOHEXANOL 97 Property

Melting point:

4 °C

Boiling point:

74 °C19 mm Hg(lit.)

Density 

0.942 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.478(lit.)

Flash point:

158 °F

pka

14.56±0.20(Predicted)

Safety

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

WGK Germany 

3

RTECS 

GW0890000

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

1-VINYLCYCLOHEXANOL 97 Chemical Properties,Usage,Production

Uses

1-Vinyl cyclohexanol may be used to synthesize:

• 1-vinyl-1-cyclohexene
• 1-vinyl-1-cyclohexylacrylate
• cyclohexylideneacetaldehyde

General Description

1-Vinyl cyclohexanol, also known as 1-vinyl-1-cyclohexanol, is a tertiary allylic alcohol. It can be synthesized from cyclohexanone and vinyl chloride. It can undergo transition-metal-free tandem allylic borylation in the presence of B₂pin [bis(pinacolato)diboron], Cs₂CO₃, THF and MeOH to yield triborated product. Pd-fullerite catalysts have been prepared which effectively catalyzes the hydrogenation of 1-ethynyl-1-cyclohexanol to 1-vinyl-1-cyclohexanol.