ChemicalBook > CAS DataBase List > 4,5-Dichloro-1,2,3-dithiazolium chloride

4,5-Dichloro-1,2,3-dithiazolium chloride

Product Name
4,5-Dichloro-1,2,3-dithiazolium chloride
CAS No.
75318-43-3
Chemical Name
4,5-Dichloro-1,2,3-dithiazolium chloride
Synonyms
D14145;Appel salt;Appel's Salt;4,5-Dichlorodithiaz;4,5-dichlorodithiazol-1-ium;4,5-DICHLORO-1,2,3-DITHIAZOLIUM;4,5-Dichlorodithiazol-2-ium chloride;4,5-dichlorodithiazol-1-ium chloride;4,5-Dichloro-[1,2,3]dithiazol-2-ylium;4,5-Dichloro-1,2,3-dithiazolium chloride
CBNumber
CB3511622
Molecular Formula
C2Cl3NS2
Formula Weight
208.5
MOL File
75318-43-3.mol
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4,5-Dichloro-1,2,3-dithiazolium chloride Property

Melting point:
172° (dec)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
Brown
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

TRC
Product number
D432328
Product name
4,5-Dichloro-1,2,3-dithiazoliumchloride
Packaging
500mg
Price
$175
Updated
2021/12/16
AK Scientific
Product number
4308CS
Product name
4,5-Dichloro-1,2,3-dithiazol-1-iumchloride
Packaging
1g
Price
$215
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD149446
Product name
4,5-Dichloro-1,2,3-dithiazoliumchloride
Packaging
1g
Price
$250
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD149446
Product name
4,5-Dichloro-1,2,3-dithiazoliumchloride
Packaging
2g
Price
$450
Updated
2021/12/16
SynQuest Laboratories
Product number
7H70-5-0LT
Product name
4,5-Dichloro-1,2,3-dithiazol-2-yliumchloride
Purity
tech%
Packaging
5G
Price
$453
Updated
2021/12/16
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4,5-Dichloro-1,2,3-dithiazolium chloride Chemical Properties,Usage,Production

Description

4,5-Dichloro-1,2,3-dithiazolium chloride is an useful organosulfur compound. It is the chloride salt of the 4,5-dichloro-1,2,3-dithiazolium cation. It is a green solid that is poorly soluble in organic solvents. Most primary arylamines react readily with 4,5-dichloro-1,2,3-dithiazolium chloride to give, after treatment with tertiary amine base (2 equiv.), the corresponding N-aryl-4-chloro-5H-1,2,3-dithiazolimines in good to excellent yields. This compound is commonly used to synthesize monocyclic 1,2,3-dithiazoles which act as fungicides, antibacterials, antivirals or anticancer agents[1-2].

Uses

Synthon in heterocyclic chemistry; in conversion of alcohols and carboxylic acids to esters.

References

[1] Kalogirou A, et al. The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines. Molecules, 2009; 14: 2356–2362.    
[2] Plakas K, et al. Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with 2-(Phenylsulfonyl)acetonitrile. Molbank, 2022; 2022: M1322.

4,5-Dichloro-1,2,3-dithiazolium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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75318-43-3, 4,5-Dichloro-1,2,3-dithiazolium chlorideRelated Search:


  • 4,5-Dichloro-1,2,3-dithiazol-2-ylium chloride, tech
  • 4,5-Dichlorodithiaz
  • DICHLORO-1,2,3-DITHIAZOL-1-YLIUM CHLORIDE
  • 4,5-dichloro-3H-dithiazol-3-ium chloride
  • 4,5-Dichloro-[1,2,3]dithiazol-2-ylium
  • 4,5-Dichloro-1,2,3-dithiazol-1-ium chloride
  • Appel salt
  • 4,5-Dichloro-1,2,3-dithiazolium chloride
  • D14145
  • 4,5-DICHLORO-1,2,3-DITHIAZOLIUM
  • 4,5-Dichloro-1,2,3-dithiazol-2-ylium chloride
  • 4,5-Dichlorodithiazol-2-ium chloride
  • Appel's Salt
  • 4,5-dichlorodithiazol-1-ium
  • 4,5-dichloro-5H-dithiazol-3-ium chloride
  • 4,5-dichlorodithiazol-1-ium chloride
  • dichloro-1lambda4,2,3-dithiazol-1-ylium chloride
  • 1,2,3-Dithiazol-1-ium, 4,5-dichloro-, chloride (1:1)
  • 4,5-dichloro-1,2,3-Dithiazol-1-ium chloride (1:1)
  • 4,5-Dichloro-1,2,3-dithiazol-2-ium Chloride
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  • C2Cl2NS2Cl