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Beta-Damascone

Product Name
Beta-Damascone
CAS No.
35044-68-9
Chemical Name
Beta-Damascone
Synonyms
2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-;α-DAMASCONE;B-Damascone;3,4-Dihydro-3,4,7-megastigmatrien-7-one;BETA-DAMASCONE;1-(2-Butenoyl)-2,6,6-trimethyl-1-cyclohexene;1-(2,6,6-Trimethyl-1-cyclohexenyl)-2-butene-1-one;J131X1Y3RE 35044-68-9 beta-Damascone 2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- 1-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-2-buten-1-one 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one UN
CBNumber
CB3511864
Molecular Formula
C13H20O
Formula Weight
192.3
MOL File
35044-68-9.mol
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Beta-Damascone Property

Boiling point:
271.2±10.0 °C(Predicted)
Density 
0.907±0.06 g/cm3(Predicted)
FEMA 
3243 | 1-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-2-BUTEN-1-ONE
storage temp. 
2-8°C
Odor
at 1.00 % in dipropylene glycol. fruity floral black currant plum rose honey tobacco
Odor Type
fruity
JECFA Number
384
LogP
4.40
EPA Substance Registry System
2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- (35044-68-9)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
1162648
Product name
Beta-Damascone
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
3x0.5ml
Price
$405
Updated
2022/05/15
Crysdot
Product number
CD13014912
Product name
1-(2,6,6-Trimethylcyclohex-1-en-1-yl)but-2-en-1-one
Purity
95+%
Packaging
25g
Price
$396
Updated
2021/12/16
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Beta-Damascone Chemical Properties,Usage,Production

Chemical Properties

Beta-Damascone is a colorless to pale yellow liquid with a very powerful floral, complex fruity note, reminiscent of plum, rose, and blackcurrant. ??-Damascone is found as a volatile constituent of many natural materials, for example, in rose oils and extracts.
One synthetic route to the damascones starts with an appropriate cyclogeranic acid derivative (halide, ester, etc.). This is reacted with an allyl magnesium halide to give 2,6,6-trimethylcyclohexenyl diallyl carbinol, which on pyrolysis yields the desired l-(2,6,6-trimethylcyclohexenyl)-3-buten-l-one. Damascone is obtained by rearrangement of the double bond in the side chain.
The ??- and ??-damascones are used in perfume compositions, especially rose perfumes, and in flavor compositions, to which they impart naturalness and body.

Occurrence

In Burley tobacco oil; in volatile fractions from leaves of Carphephorus corymbosus and C. paniculatus. Reported found in bilberry, butter, milk, caviar, chicken fat, cooked beef and mutton, cured pork, pork and beef fat, roasted filberts and peanuts, pecans, potato chips, soybean, coriander leaf and seed and kiwifruit.

Preparation

Various methods: recently from ionone izoxazoles, also from 7,8-dehydro-β-ionole.

Aroma threshold values

Detection: 8.6 to 41 ppb

Taste threshold values

Taste characteristics at 30 ppm: green, woody, minty with a herbal floral nuance.

Beta-Damascone Preparation Products And Raw materials

Raw materials

Preparation Products

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Beta-Damascone Suppliers

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19915
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai Witofly Chemical Co. ,Ltd.
Tel
15821189163
Email
sales@witofly.com
Country
China
ProdList
1604
Advantage
55
Conier Chem & Pharma Limited
Tel
13368167990
Email
sales@conier.com
Country
China
ProdList
2838
Advantage
58
CD Chemical Group Limited
Tel
+8615986615575
Fax
0086-13651442114
Email
info@codchem.com
Country
China
ProdList
20342
Advantage
58
Wuhan xinyangruihe Chemical Technology Co., Ltd.
Tel
153-07155313 15307155313
Fax
QQ:2274366233
Email
2274366233@qq.com
Country
China
ProdList
4782
Advantage
58
Shaanxi Dideu Medichem Co. Ltd
Tel
+86-029-81138252 +86-18789408387
Fax
029-88380327
Email
1057@dideu.com
Country
China
ProdList
3889
Advantage
58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd
Tel
17691182729 18161915376
Email
1046@dideu.com
Country
China
ProdList
9998
Advantage
58
Guangdong Fangxin Biotechnology Co., Ltd.
Tel
0751-2838688 13376594225
Email
1276075424@qq.com
Country
China
ProdList
9935
Advantage
58
Hubei Shiteng Chemical Technology Co. LTD
Tel
189-71839113 18971850150
Email
1273131441@qq.com
Country
China
ProdList
4988
Advantage
58
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View Lastest Price from Beta-Damascone manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Beta-Damascone 35044-68-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-09

35044-68-9, Beta-DamasconeRelated Search:


  • 2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-
  • B-Damascone
  • 1-(2,6,6-Trimethyl-1-cyclohexenyl)-2-butene-1-one
  • 1-(2-Butenoyl)-2,6,6-trimethyl-1-cyclohexene
  • 3,4-Dihydro-3,4,7-megastigmatrien-7-one
  • BETA-DAMASCONE
  • α-DAMASCONE
  • J131X1Y3RE 35044-68-9 beta-Damascone 2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- 1-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-2-buten-1-one 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one UN
  • 35044-68-9