4-BENZYLOXY-2-METHOXYBENZALDEHYDE

Product Name: 4-BENZYLOXY-2-METHOXYBENZALDEHYDE
CAS No.: 58026-14-5
Chemical Name: 4-BENZYLOXY-2-METHOXYBENZALDEHYDE
Synonyms: 4-Benzyloxy-o-anisaldehyde;5-(Benzyloxy)-2-formylanisole;4-BENZYLOXY-2-METHOXYBENZALDEHYDE;2-methoxy-4-benzyloxybenzaldehyde;2-Methoxy-4-(phenylMethoxy)benzaldehyde;4-BENZYLOXY-2-METHOXYBENZALDEHYDE, 98+%;Benzaldehyde, 2-methoxy-4-(phenylmethoxy)-
CBNumber: CB3683929
Molecular Formula: C15H14O3
Formula Weight: 242.27
MOL File: 58026-14-5.mol

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4-BENZYLOXY-2-METHOXYBENZALDEHYDE Property

Melting point:: 98-100°C
Boiling point:: 180°C 2mm
Density: 1.154±0.06 g/cm3(Predicted)
Flash point:: 180°C/2mm
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: Light yellow to brown Solid
Sensitive: Air Sensitive
BRN: 1880700
CAS DataBase Reference: 58026-14-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Safety Statements: 22-24/25
HS Code: 2912490090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B285983
Product name: 4-Benzyloxy-2-methoxybenzaldehyde
Packaging: 1g
Price: $115
Updated: 2021/12/16

TRC

Product number: B285983
Product name: 4-Benzyloxy-2-methoxybenzaldehyde
Packaging: 10g
Price: $925
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB18446
Product name: 4-Benzyloxy-2-methoxybenzaldehyde
Packaging: 50g
Price: $1365
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0011570
Product name: 4-BENZYLOXY-2-METHOXYBENZALDEHYDE
Purity: 95.00%
Packaging: 50G
Price: $3465
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB18446
Product name: 4-Benzyloxy-2-methoxybenzaldehyde
Packaging: 5G
Price: $227.2
Updated: 2021/12/16

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4-BENZYLOXY-2-METHOXYBENZALDEHYDE Chemical Properties,Usage,Production

Synthesis

18278-34-7

100-39-0

58026-14-5

4-Hydroxy-2-methoxybenzaldehyde (200 mg, 1.31 mmol) was dissolved in N,N-dimethylformamide (DMF) under the protection of nitrogen (N2), potassium carbonate (K2CO3, 543 mg, 3.93 mmol) was added, and stirred for 30 min at room temperature. Subsequently, benzyl bromide (BnBr, 0.312 mL, 2.62 mmol) was added dropwise to the reaction mixture and stirring was continued for 1.5 hours. After completion of the reaction, the reaction mixture was diluted with ethyl acetate (EtOAc) and washed with deionized water (H2O). The organic phase was dried with anhydrous sodium sulfate (Na2SO4) and concentrated under reduced pressure. Purification by silica gel column chromatography with ethyl acetate/hexane (1:2, v/v) as eluent afforded the target product 4-benzyloxy-2-methoxybenzaldehyde (304 mg, 95.7% yield).1H-NMR (CDCl3, 400 MHz) δ: 7.81 (d, 1H, J = 8.6 Hz), 7.36 (m, 5H), 6.62 ( dd, 1H, J = 8.7, 2.2 Hz), 6.54 (d, 1H, J = 2.2 Hz), 5.14 (s, 2H), 3.89 (s, 3H).

References

[1] Molecules, 2015, vol. 20, # 9, p. 15966 - 15975
[2] Bioorganic and Medicinal Chemistry, 1998, vol. 6, # 9, p. 1429 - 1437
[3] Journal of the American Chemical Society, 2006, vol. 128, # 33, p. 10640 - 10641
[4] Patent: WO2006/40520, 2006, A1. Location in patent: Page/Page column 103
[5] Patent: WO2007/99326, 2007, A1. Location in patent: Page/Page column 111

4-BENZYLOXY-2-METHOXYBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BENZYLOXY-2-METHOXYBENZALDEHYDE Suppliers

Canada 1 China 55 Germany 2 India 3 Switzerland 1 United Kingdom 11 United States 13 Global 86

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58026-14-5, 4-BENZYLOXY-2-METHOXYBENZALDEHYDERelated Search:

4'-BENZYLOXY-2'-METHOXY-3'-METHYLACETOPHENONE 4-BENZYLOXY-2-METHOXYBENZALDEHYDE 3-BENZYLOXY-4-METHOXYBENZALDEHYDE 4-BENZYLOXY-3-METHOXYBENZALDEHYDE 98%,O-BENZYLOXYVANILLIN (4-BENZYLOXY-3-METHOXYBENZALDEHYDE),4-BENZYLOXY-3-METHOXYBENZALDEHYDE 4-Benzyloxybenzaldehyde 1-[4-(BENZYLOXY)-2-METHOXYPHENYL]ETHANONE PS 990 2-(BENZYLOXY)-3-METHOXYBENZALDEHYDE MOLLICELLINC AURORA 15442 AURORA 15441 AURORA 15439 2,4-BIS(BENZYLOXY)BENZALDEHYDE thielocin B3 AURORA 15437 AURORA 15301 SPECS AG-690/36599057 AURORA 15328

2-methoxy-4-benzyloxybenzaldehyde

4-BENZYLOXY-2-METHOXYBENZALDEHYDE

4-Benzyloxy-o-anisaldehyde

4-BENZYLOXY-2-METHOXYBENZALDEHYDE, 98+%

2-Methoxy-4-(phenylMethoxy)benzaldehyde

5-(Benzyloxy)-2-formylanisole

Benzaldehyde, 2-methoxy-4-(phenylmethoxy)-

58026-14-5

58029-14-5

5806-14-5

ALDEHYDE

Phenyls & Phenyl-Het

Aromatics

Aldehydes

Phenyls & Phenyl-Het