ChemicalBook > CAS DataBase List > 2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]

2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]

Product Name
2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]
CAS No.
133463-88-4
Chemical Name
2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]
Synonyms
SF140046;(S,S)-Bn-Bisbox;-Bis[(4S)-4-benzyl-2-oxazoline;2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE;2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE];(s,s)-2,2'-bis(4-benzyl-2-oxazoline);(S,S)-4,4'-dibenzyl-2,2'-bi(2-oxazoline);(2S,2’S)-4,4’-Dibenzyl-2,2’,5,5’-tetrahydro-2,2’-bioxazole;(4S,4'S)-4,4'-dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole;(2S,2’S)-4,4’-Dibenzyl-2,2’,5,5’-tetrahydro-2,2’-bioxazole
CBNumber
CB3689734
Molecular Formula
C20H20N2O2
Formula Weight
320.39
MOL File
133463-88-4.mol
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2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE] Property

Melting point:
129-132 °C(lit.)
Boiling point:
449.3±28.0 °C(Predicted)
Density 
1.21±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
3.89±0.70(Predicted)
optical activity
[α]20/D 40.6°, c = 1 in ethanol
BRN 
4756827
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
405973
Product name
2,2′-Bis[(4S)-4-benzyl-2-oxazoline]
Purity
98%
Packaging
250mg
Price
$107
Updated
2024/03/01
Sigma-Aldrich
Product number
405973
Product name
2,2′-Bis[(4S)-4-benzyl-2-oxazoline]
Purity
98%
Packaging
1g
Price
$126
Updated
2024/03/01
ChemScene
Product number
CS-0090557
Product name
(4S,4'S)-4,4'-Dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole
Purity
≥97.0%
Packaging
1g
Price
$262
Updated
2021/12/16
AK Scientific
Product number
2175AQ
Product name
(4S,4'S)-4,4'-Dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole
Packaging
250mg
Price
$270.8
Updated
2021/12/16
ChemScene
Product number
CS-0090557
Product name
(4S,4'S)-4,4'-Dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole
Purity
≥97.0%
Packaging
250mg
Price
$77
Updated
2021/12/16
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2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE] Chemical Properties,Usage,Production

Uses

2,2′-Bis[(4S)-4-benzyl-2-oxazoline] can be used as:

  • A catalyst for the enantioselective hydrosilylation of ketones.
  • A Schiff base ligand in the preparation of rhodium(I) and palladium(II) coordination complexes.
  • A ligand in the formation of copper(I) halide complexes; applicable in the synthesis of coordination polymers.

2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE] Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE] Suppliers

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133463-88-4, 2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]Related Search:


  • 2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE]
  • (4S,4'S)- 4,4',5,5'-tetrahydro-4,4'-bis(phenylmethyl)-2,2'-Bioxazole
  • (S,S)-4,4'-dibenzyl-2,2'-bi(2-oxazoline)
  • (s,s)-2,2'-bis(4-benzyl-2-oxazoline)
  • (S,S)-2,2μ-Bis(4-benzyl-2-oxazoline), (S,S)-4,4μ-Dibenzyl-2,2μ-bi(2-oxazoline)
  • 2,2′-Bis[(4S)-4-benzyl-2-oxazoline],(S,S)-2,2′-Bis(4-benzyl-2-oxazoline), (S,S)-4,4′-Dibenzyl-2,2′-bi(2-oxazoline)
  • (4S,4'S)-4,4'-dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole
  • SF140046
  • 2,2'-Bioxazole, 4,4',5,5'-tetrahydro-4,4'-bis(phenylmethyl)-, (4S,4'S)-
  • (S,S)-Bn-Bisbox
  • (2S,2’S)-4,4’-Dibenzyl-2,2’,5,5’-tetrahydro-2,2’-bioxazole
  • -Bis[(4S)-4-benzyl-2-oxazoline
  • 2,2'-BIS[(4S)-4-BENZYL-2-OXAZOLINE
  • (2S,2’S)-4,4’-Dibenzyl-2,2’,5,5’-tetrahydro-2,2’-bioxazole
  • 133463-88-4
  • Privileged Ligands
  • Asymmetric Synthesis
  • BOX
  • Chiral Catalysts, Ligands, and Reagents