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TRI-N-BUTYLGERMANE

Product Name
TRI-N-BUTYLGERMANE
CAS No.
998-39-0
Chemical Name
TRI-N-BUTYLGERMANE
Synonyms
TRIBUTYLGERMANE;TRI-N-BUTYLGERMANE;Germane, tributyl-;Tributylgermane,99%;TRIBUTYLGERMANIUM HYDRIDE;TRI-N-BUTYLGERMANIUM HYDRIDE;Tri-n-butylgermaniumhydride,97+%;TRI-N-BUTYLGERMANE ISO 9001:2015 REACH
CBNumber
CB3716913
Molecular Formula
C12H28Ge
Formula Weight
244.99
MOL File
998-39-0.mol
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TRI-N-BUTYLGERMANE Property

Melting point:
<0°C
Boiling point:
123 °C/20 mmHg (lit.)
Density 
0.949 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.45(lit.)
Flash point:
>230 °F
solubility 
Not miscible.
form 
Liquid
Specific Gravity
0.92
Sensitive 
Air & Moisture Sensitive
CAS DataBase Reference
998-39-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-41
Safety Statements 
26-36
WGK Germany 
3
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
409170
Product name
Tributylgermanium hydride
Purity
99%
Packaging
1g
Price
$196
Updated
2024/03/01
Alfa Aesar
Product number
042688
Product name
Tri-n-butylgermanium hydride
Purity
97+%
Packaging
1g
Price
$115
Updated
2024/03/01
Alfa Aesar
Product number
042688
Product name
Tri-n-butylgermanium hydride
Purity
97+%
Packaging
5g
Price
$420
Updated
2024/03/01
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TRI-N-BUTYLGERMANE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Chemical Properties

Reduces acid chlorides to aldehydes in presence of Pd(0). Effects free-radical reductive addition of alkyl halides to olefins. Reduces benzylic chlorides 70x faster than silyl hydrides.

Uses

Efficient reducing agent for benzylic chlorides.1

Uses

Tri-n-butylgermanium hydride is used in the reduction of benzylic chlorides. It is also used as pharmaceutical intermediate.

General Description

Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.

TRI-N-BUTYLGERMANE Preparation Products And Raw materials

Raw materials

Preparation Products

998-39-0, TRI-N-BUTYLGERMANERelated Search:


  • TRIBUTYLGERMANIUM HYDRIDE
  • TRIBUTYLGERMANE
  • TRI-N-BUTYLGERMANIUM HYDRIDE
  • TRI-N-BUTYLGERMANE
  • Tri-n-butylgermaniumhydride,97+%
  • Tributylgermane,99%
  • Germane, tributyl-
  • TRI-N-BUTYLGERMANE ISO 9001:2015 REACH
  • 998-39-0
  • CH3CH233GeH
  • Organogermanium
  • Others
  • Organometallic Reagents
  • Chemical Synthesis
  • GermaniumSynthetic Reagents
  • Metal HydridesOrganometallic Reagents
  • Organogermanium
  • Others
  • Precursors by Metal
  • Reduction
  • Vapor Deposition Precursors
  • CVD and ALD Precursors by Metal
  • Germanium
  • Materials Science
  • Metal Hydrides
  • Micro/NanoElectronics
  • Organometallic Reagents
  • Synthetic Reagents
  • Vapor Deposition Precursors