1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE

Product Name: 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE
CAS No.: 4163-65-9
Chemical Name: 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE
Synonyms: (2R,3S,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate;ALPHA-D-MANNOSE PENTAACETATE;α-D-Mannose pentaacetate;NSC 51251;D-Mannose Pentacetate;A-D-mannosepentaacetate;penta-O-acetyl-α-D-Mannose;αlpha-D-Mannose pentaacetate;D-(alpha)-Mannose pentaacetate;per-O-acetyl-α-D-mannopyranose
CBNumber: CB3716993
Molecular Formula: C16H22O11
Formula Weight: 390.34
MOL File: 4163-65-9.mol

More

Less

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE Property

Melting point:: 64-75°C
Boiling point:: 135 °C(Press: 0.0001 Torr)
Density: 1.30
storage temp.: Sealed in dry,Store in freezer, under -20°C
solubility: Soluble in chloroform
form: Powder
color: White to Off-white
InChI: InChI=1/C16H22O11/c1-7(17)22-6-12-13(23-8(2)18)14(24-9(3)19)15(25-10(4)20)16(27-12)26-11(5)21/h12-16H,6H2,1-5H3/t12-,13-,14+,15+,16+/s3
InChIKey: LPTITAGPBXDDGR-OWYFMNJBSA-N
SMILES: [C@@H]1(OC(=O)C)[C@H](OC(=O)C)[C@H](O[C@H](COC(=O)C)[C@H]1OC(=O)C)OC(=O)C |&1:0,5,10,12,18,r|
CAS DataBase Reference: 4163-65-9(CAS DataBase Reference)

More

Less

Safety

WGK Germany: 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M6633
Product name: α-D-Mannose pentaacetate
Packaging: 5g
Price: $363
Updated: 2025/07/31

Sigma-Aldrich

Product number: M6633
Product name: α-D-Mannose pentaacetate
Packaging: 25g
Price: $1340
Updated: 2023/06/20

TCI Chemical

Product number: M3672
Product name: α-D-Mannose Pentaacetate
Packaging: 5G
Price: $45
Updated: 2025/07/31

TCI Chemical

Product number: M3672
Product name: α-D-Mannose Pentaacetate
Packaging: 25G
Price: $135
Updated: 2025/07/31

Sigma-Aldrich

Product number: M6633
Product name: α-D-Mannose pentaacetate
Packaging: 100g
Price: $2750
Updated: 2023/06/20

More

Less

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE Chemical Properties,Usage,Production

Uses

1,2,3,4,6-Penta-O-acetyl-α-D-mannopyranose (cas# 4163-65-9) is a compound useful in organic synthesis.

Uses

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE was used for glycosylation in a study that assessed novel synthetic inhibitors of selectin-mediated cell adhesion. 1 It has also been used in a study to investigate stereospecific entry to spiroketal glycosides using alkylidenecarbene CH insertion.

Synthesis

50-99-7

108-24-7

83-87-4

D-Anhydrous glucose (3.00 g, 16.6 mmol) was dissolved in anhydrous pyridine (33 mL) and acetic anhydride (31.5 mL, 333 mmol) was added slowly and dropwise at 0 °C and under nitrogen protection. The reaction mixture was stirred at 0 °C for 1 h. After that, a catalytic amount of DMAP (200 mg, 1.67 mmol) was added. Subsequently, the reaction mixture was gradually warmed up to room temperature, during which a slight exothermic phenomenon was observed. After 6 hours of reaction, the clarified yellow reaction solution was slowly poured into rapidly stirred ice water (125 mL) and a viscous solid was precipitated. After extraction by ethyl acetate (345 mL), the solvent was evaporated and co-evaporated with anhydrous toluene (320 mL) to give the final fully acetylated glucose as a yellow solid (5.84 g, 90% yield).

References

[1] Angewandte Chemie, International Edition, 2009, vol. 48, p. 2723 - 2726
[2] Angewandte Chemie, 2009, vol. 121, p. 2761 - 2764
[3] Tetrahedron, 2013, vol. 69, # 41, p. 8731 - 8737
[4] Green Chemistry, 2011, vol. 13, # 1, p. 59 - 63
[5] Journal of the Chinese Chemical Society, 2009, vol. 56, # 2, p. 398 - 403

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE Suppliers

Canada 1 China 172 Germany 4 India 4 Switzerland 1 United Kingdom 4 United States 18 Global 204

Jinan Samuel Pharmaceutical Co., Ltd.

Tel: 0531-88821801 15192360884
Fax: 0531-88821802
Email: 605818151@qq.com
Country: China
ProdList: 417
Advantage: 58

Zhejiang Synose Tech Co., Ltd.

Tel: 0579-89172082 18720986928
Fax: 0579-89172082
Email: 191094223@qq.com
Country: China
ProdList: 69
Advantage: 58

Hubei wei shi reagent group ltd., company

Tel: 027-59101766 13125137661
Email: 2853877621@qq.com
Country: China
ProdList: 7976
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Chemsky (shanghai) International Co.,Ltd

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 15402
Advantage: 60

Shanghai Sunway Pharmaceutical Technology Co., Ltd

Tel: 18270980682
Fax: 021 51613951
Email: mlcheng@sunwaypharm.cn
Country: China
ProdList: 8669
Advantage: 57

More

Less

View Lastest Price from 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE manufacturers

Shenzhen Nexcon Pharmatechs Ltd.

Product: 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE 4163-65-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 2000
Release date: 2025-06-05

Hebei Zhuanglai Chemical Trading Co Ltd

Product: D-alpha-Mannose pentaacetate 4163-65-9
Price: US $79.00-38.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-11-15

Henan Aochuang Chemical Co.,Ltd.

Product: 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE 4163-65-9
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-14

4163-65-9, 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSERelated Search:

INDEX NAME NOT YET ASSIGNED 1-O-METHYL-BETA-D-GLUCURONIC ACID, SODIUM SALT 4-NITROPHENYL-BETA-D-XYLOPYRANOSIDE 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-MANNOPYRANOSYL FLUORIDE beta-D-Galactose pentaacetate 2-ACETAMIDO-2-DEOXY-1,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE Thiotolyl beta-D-ribofuranoside METHYL-BETA-D-GALACTOPYRANOSIDE ALPHA-D-MANNOPYRANOSYL AZIDE TETRAACETAT beta-L-glucose pentaacetate 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE METHYL ALPHA-L-RHAMNOPYRANOSIDE 1,2,3,4,6-PENTA-O-ACETYL-D-MANNOPYRANOSE METHYL-ALPHA-D-MANNOPYRANOSIDE 2-methoxyoxane-3,4,5-triol 1,3,4,6-Tetra-O-acetyl-2-deoxy-D-glucopyranose 2,3,4,6-Tetra-O-acetyl-a-D-mannopyranose 2,3,4,6-Tetra-O-acetyl-D-mannopyranose

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE

ALPHA-D-MANNOSE PENTAACETATE

A-D-mannosepentaacetate

ACETIC ACID (2R,3R,4S,5S,6R)-3,4,5,6-TETRAACETOXY-TETRAHYDRO-PYRAN-2-YLMETHYL ESTER

1-O,2-O,3-O,4-O,6-O-Pentaacetyl-α-D-mannopyranose

Penta-O-acetyl-alpha-D-mannopyranose

(2R,3S,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate

1,2,3,4,6-O-Pentaacetyl-alpha-mannose

1,2,3,4,6-Penta-O-acetyl-alpha-D-mannose

2,3,4,6-Tetra-O-acetyl-alpha-D-mannopyranosyl acetate

alpha-D-Mannopyranose,1,2,3,4,6-pentaacetate

D-Mannose Pentacetate

1,2,3,4,6-O-pentaacetyl-α-mannose

2,3,4,6-Tetra-O-acetyl-α-D-Mannopyranosyl Acetate

NSC 51251

D-(alpha)-Mannose pentaacetate

penta-O-acetyl-α-D-Mannose

1,2,3,4,6-Penta-O-acetyl-α-D-mannopyranose

α-D-Mannose pentaacetate

6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANOSE

[(2R,3R,4S,5S,6R)-3,4,5,6-tetraacetyloxyoxan-2-yl]methyl acetate

.alpha.-D-Mannopyranose pentaacetate(4163-65-9)

1,2,3,4,6-Penta-O-acetyl-α-D-mannose

1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-MANNOPYRANO

per-O-acetyl-α-D-mannopyranose

α-D-Mannopyranose, 1,2,3,4,6-pentaacetate

1,2,3,4,6-O-pentaacetyl- Α- mannose

αlpha-D-Mannose pentaacetate

α-D-Mannose pentaacetate, CAS 4163-65-9

(2R,3S,4S,5R,6R)-6-(Acetoxymethyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetraacetate - [A72945]

4163-65-9

Monosaccharide

Carbohydrates

Biochemicals and Reagents

BioChemical

Carbohydrates & Derivatives

13C & 2H Sugars

Glycon Biochem