ChemicalBook > CAS DataBase List > 2,2'-Benzidinedisulfonic acid

2,2'-Benzidinedisulfonic acid

Product Name
2,2'-Benzidinedisulfonic acid
CAS No.
117-61-3
Chemical Name
2,2'-Benzidinedisulfonic acid
Synonyms
BDSA;BENZIDINE 2,2 DISULFONIC ACID;70.0%(T);2,2'-Benzidinedisulf;Benzidine-2,2'-disuL;2,2'-disulfobenzidine;2,2’-disulfo-benzidin;6,6'-bimetanilic acid;BENZIDINEDISULPHONICACID;BENZIDINE 2-2'DISUFONIC ACID
CBNumber
CB3732926
Molecular Formula
C12H12N2O6S2
Formula Weight
344.36
MOL File
117-61-3.mol
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2,2'-Benzidinedisulfonic acid Property

Melting point:
175°C
Boiling point:
638.25℃[at 101 325 Pa]
Density 
1.5417 (rough estimate)
vapor pressure 
0Pa at 25℃
refractive index 
1.6510 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
pka
-1.85±0.50(Predicted)
color 
Dark purple
Water Solubility 
<0.1 g/100 mL at 20 ºC
LogP
1.102 at 24℃
CAS DataBase Reference
117-61-3(CAS DataBase Reference)
EPA Substance Registry System
[1,1'-Biphenyl]-2,2'-disulfonic acid, 4,4'-diamino- (117-61-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-37/38-36-36/37/38
Safety Statements 
22-26-36-60-37
RTECS 
DV5230000
TSCA 
Yes
HS Code 
29215900
Toxicity
eye-rbt 500 mg/24H SEV 28ZPAK -,191,72
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B0395
Product name
2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)
Purity
>70.0%(T)
Packaging
25g
Price
$48
Updated
2024/03/01
TCI Chemical
Product number
B0395
Product name
2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)
Purity
>70.0%(T)
Packaging
500g
Price
$284
Updated
2024/03/01
Alfa Aesar
Product number
041472
Product name
4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate, cont. up to 30% water
Packaging
25g
Price
$53.1
Updated
2023/06/20
Alfa Aesar
Product number
041472
Product name
4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate, cont. up to 30% water
Packaging
100g
Price
$175
Updated
2023/06/20
TRC
Product number
D416193
Product name
4,4''-Diamino-[1,1''-biphenyl]-2,2''-disulfonicAcid
Packaging
250mg
Price
$45
Updated
2021/12/16
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2,2'-Benzidinedisulfonic acid Chemical Properties,Usage,Production

Chemical Properties

PURPLE CRYSTALLINE POWDER

Uses

4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. Benzidine-2,2' -disulfonic acid is used in the production of yellow and red azo dyes.

Production Methods

2,2'-Benzidinedisulfonic acid is made from the potassium or sodium salt of 3- nitrobenzenesulfonic acid by a gradual reduction using zinc dust and sodium hydroxide solution in a dilute aqueous solution. The product is subsequently rearranged using hydrochloric acid or dilute sulfuric acid. Electrochemical or catalytic reductions are also possible.

General Description

Leaflets or prisms or light purple powder.

Air & Water Reactions

Insoluble in water.

Fire Hazard

Flash point data for 2,2'-Benzidinedisulfonic acid are not available; however, 2,2'-Benzidinedisulfonic acid is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

A severe eye irritant. When heated to decomposition it emitsvery toxic fumes of SOx and NOx.

2,2'-Benzidinedisulfonic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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2,2'-Benzidinedisulfonic acid Suppliers

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View Lastest Price from 2,2'-Benzidinedisulfonic acid manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
Benzidine-2,2'-disulfonic acid 117-61-3
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2024-10-08
Career Henan Chemical Co
Product
2,2'-Benzidinedisulfonic acid 117-61-3
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-21

117-61-3, 2,2'-Benzidinedisulfonic acidRelated Search:

Sulfurous Acid IMINOCTADINE TRIS(ALBESILATE) Benzidine ACID RED 89 O-TOLUIDINE DISULFONIC ACID 3,3'-DIMETHYL-NAPHTHIDINE-DISULFONIC ACID Acid Yellow 42 ACID RED 97 (C.I. 22890) 4,4'-DIAMINO-5,5'-DIMETHYL-2,2'-BIPHENYL DISULFONIC ACID DISODIUM SALT Mordant Yellow 26 Acid Yellow 44 Acid Orange 56 2,2'-Benzidinedisulfonic acid

  • 2,2'-BENZIDINEDISULFONIC ACID
  • 2,2'-Disulfo-4,4'-diaminobiphenyl
  • 2,2'-disulfobenzidine
  • 2,2'-DISULFONIC ACID BENZIDINE
  • 1’-biphenyl)-2,2’-disulfonicacid,4,4’-diamino-(
  • 1’-biphenyl]-2,2’-disulfonicacid,4,4’-diamino-[
  • 1’-Biphenyl]-2,2’-disulfonicacid,4,4’-diamino-[1
  • BDSA
  • BENZIDINE 2,2 DISULFONIC ACID
  • benzidine-2,2'-disulphonic acid
  • BENZIDINEDISULPHONICACID
  • 2,2''-BENZIDINEDISULFONIC ACID: 70% (CONTAINS MAX. 30% WATER)
  • 4,4''-DIAMINEDIPHENY-2,2''-DISULFONICACID
  • 4,4'-Diamino-2,2'-biphenyldisulfonic acid, tech. 70+%
  • 2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)
  • 4,4'-Diamino-2,2'-biphenyldisulfonic acid, 70+%
  • [1,1'-Biphenyl]-2,2'-disulfonic acid, 4,4'-diamino-
  • 2,2'-Biphenyldisulfonic acid, 4,4'-diamino
  • 4,4'-Diamino-1,1'-biphenyl-2,2'-bissulfonic acid
  • 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate, cont. up to 30% water
  • 4,4'-Diamino-2,2'-biphenyldisulfonic acid,85%,tech.
  • (contains 30% Water at MaxiMuM)
  • 2,2'-Benzidinedisulfonic Acid&nbsp
  • 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate
  • 2,2'-Benzidinedisulf
  • 4,4'-Diaminobiphenyl-2,2'-disulfonic acid hydrate,may contain up to 30% water
  • 4,4'-DIAMINO-2,2'-BIPHENYLDISULFONIC ACID
  • 4,4'-Diamino-(1,1'-biphenyl)-2,2'-disulfonic acid
  • 4,4'-Diaminobiphenyl-2,2'-disulfonic acid
  • 2,2’-diamino-4’-biphenyldisulfonicacid
  • 2,2’-disulfo-benzidin
  • 4,4’-diamino-2’-biphenyldisulfonicacid
  • 4,4’-diaminodiphenyl-2,2’-disulfonicacid
  • 4,4'-Diamino-[1,1'-biphenyl]-2,2'-disulfonic acid(contains 30% Water at maximum)
  • 2,2'-Benzidinedisulfonic acid, 70%, water ≤30%
  • 5-amino-2-(4-amino-2-sulfophenyl)benzenesulfonic acid
  • kyselinabenzidin-2,2’-disulfonova
  • 2,2'-disulfo-4,4'diaminobibenzene
  • 2,2'-BENZIDINEDISULFONIC ACID (CONTAINS 30% WATER AT MAXIMUM) 70+%
  • 2,2’-BENZIDINE-DISULPHONIC ACID， HPLC 96+％
  • 6,6'-bimetanilic acid
  • BENZIDINE 2-2'DISUFONIC ACID
  • 2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)&gt
  • 70.0%(T)
  • Benzidine-2,2'-disuL
  • 5-amino-2-(4-amino-2-sulfophenyl)benzenesulfonicaci
  • 4,4’-Diamino-2,2’-biphenyldisulfonic Acid (contains 30% Water at maximum)
  • Benzidine-2,2'-disulfonic acid/BDSA
  • TIANFUCHEM--High purity 117-61-3 2,2'-Benzidinedisulfonic acid
  • 2,2'-Benzidinedisulfonic Acid (contains 20% Water at maximum)
  • 2,2'-Benzidinedisulfonic acid
  • 2,2'-Benzidinedisulfonic Acid (contains 30% Water at maximum)
  • 4,4'-Diamino-[1,1'-biphenyl]-2,2'-disulfonic acid(contains 30% Water at maximum)
  • Benzidine-2,2'-disulfonic acid
  • 4,4'-Diamino-2,2'-biphenyldisulfonic acid
  • 117-61-3
  • H2NC6H3SO3H2
  • C12H12N2O6S2