4-Bromo-2,6-di-tert-butylphenol

Product Name: 4-Bromo-2,6-di-tert-butylphenol
CAS No.: 1139-52-2
Chemical Name: 4-Bromo-2,6-di-tert-butylphenol
Synonyms: Probucol Impurity;Probucol Impurity 22;4-BROMO-2,6-DI-TERT-PHENOL;4-BROMO-2,6-DI-T-BUTYLPHENOL;4-BROMO-2,6-DI-TERT-BUTYLPHENOL;2,6-DI-TERT-BUTYL-4-BROMOPHENOL;2,6-Bis(tert-butyl)-4-bromophenol;4-Bromo-2,6-di-tert-butylphenol 98%;4-Bromo-2,6-di-tert-butylphenol,98%;4-Bromo-2,6-di-tert-butylphenol >
CBNumber: CB3734405
Molecular Formula: C14H21BrO
Formula Weight: 285.22
MOL File: 1139-52-2.mol

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4-Bromo-2,6-di-tert-butylphenol Property

Melting point:: 78-83 °C (dec.)(lit.)
Boiling point:: 128 °C / 4mmHg
Density: 1.2457 (rough estimate)
refractive index: 1.5130 (estimate)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 11.23±0.40(Predicted)
color: White to Orange to Green
BRN: 2051052
InChI: 1S/C14H21BrO/c1-13(2,3)10-7-9(15)8-11(12(10)16)14(4,5)6/h7-8,16H,1-6H3
InChIKey: SSQQUEKFNSJLKX-UHFFFAOYSA-N
SMILES: CC(C)(C)c1cc(Br)cc(c1O)C(C)(C)C
CAS DataBase Reference: 1139-52-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29081990
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 394378
Product name: 4-Bromo-2,6-di-tert-butylphenol
Purity: 98%
Packaging: 25g
Price: $143
Updated: 2023/06/20

Sigma-Aldrich

Product number: 394378
Product name: 4-Bromo-2,6-di-tert-butylphenol
Purity: 98%
Packaging: 100g
Price: $316
Updated: 2023/06/20

TCI Chemical

Product number: B1758
Product name: 4-Bromo-2,6-di-tert-butylphenol
Purity: >98.0%(GC)
Packaging: 25g
Price: $319
Updated: 2025/07/31

TRC

Product number: B686718
Product name: 4-Bromo-2,6-di-tert-butylphenol
Packaging: 250mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2701-9-X5
Product name: 4-Bromo-2,6-di-tert-butylphenol
Purity: 98%
Packaging: 25g
Price: $52
Updated: 2021/12/16

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4-Bromo-2,6-di-tert-butylphenol Chemical Properties,Usage,Production

Chemical Properties

yellow to brown crystals

Uses

4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:

As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.
Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.
As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (N_ArOH), a norbornene comonomer bearing an antioxidant hindered phenol.
As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.

General Description

4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by ¹H NMR. Its photolysis reaction in benzene solution has been investigated. The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.

4-Bromo-2,6-di-tert-butylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2,6-di-tert-butylphenol Suppliers

Americas 1 Belgium 3 China 97 Europe 1 Germany 4 India 5 Japan 3 Slovakia 1 Switzerland 4 United Kingdom 14 United States 18 Global 151

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View Lastest Price from 4-Bromo-2,6-di-tert-butylphenol manufacturers

Moxin Chemicals

Product: Probucol Impurity 22 1139-52-2
Price: US $0.00-0.00/mg
Min. Order: 10mg
Purity: 95%+
Supply Ability: 100000
Release date: 2025-01-21

ShenZhen H&D Pharmaceutical Technology Co., LTD

Product: Probucol Impurity 22 1139-52-2
Price: US $0.00/mg
Min. Order: 10mg
Purity: 0.98
Supply Ability: 5g
Release date: 2025-02-06

Shaanxi Dideu Medichem Co. Ltd

Product: 4-Bromo-2,6-di-tert-butylphenol 1139-52-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10 tons
Release date: 2024-08-05

1139-52-2, 4-Bromo-2,6-di-tert-butylphenolRelated Search:

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Probucol Impurity

Probucol Impurity 22

1139-52-2

BrC6H2CCH332OH

C14H21BrO

C14H21OBr

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Oxygen Compounds

Phenols

Organic Building Blocks

Oxygen Compounds

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