ChemicalBook > CAS DataBase List > 4-Bromo-2,6-di-tert-butylphenol

4-Bromo-2,6-di-tert-butylphenol

Product Name
4-Bromo-2,6-di-tert-butylphenol
CAS No.
1139-52-2
Chemical Name
4-Bromo-2,6-di-tert-butylphenol
Synonyms
4-BROMO-2,6-DI-TERT-PHENOL;4-BROMO-2,6-DI-T-BUTYLPHENOL;4-BROMO-2,6-DI-TERT-BUTYLPHENOL;2,6-DI-TERT-BUTYL-4-BROMOPHENOL;2,6-Bis(tert-butyl)-4-bromophenol;4-Bromo-2,6-di-tert-butylphenol 98%;4-Bromo-2,6-di-tert-butylphenol,98%;4-Bromo-2,6-di-tert-butylphenol >4-Bromo-2,6-di-tert-butylphenol;4-Bromo-2,6-bis(1,1-dimethylethyl)phenol
CBNumber
CB3734405
Molecular Formula
C14H21BrO
Formula Weight
285.22
MOL File
1139-52-2.mol
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4-Bromo-2,6-di-tert-butylphenol Property

Melting point:
78-83 °C (dec.)(lit.)
Boiling point:
128 °C / 4mmHg
Density 
1.2457 (rough estimate)
refractive index 
1.5130 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
pka
11.23±0.40(Predicted)
color 
White to Orange to Green
BRN 
2051052
CAS DataBase Reference
1139-52-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29081990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
394378
Product name
4-Bromo-2,6-di-tert-butylphenol
Purity
98%
Packaging
25g
Price
$143
Updated
2023/06/20
Sigma-Aldrich
Product number
394378
Product name
4-Bromo-2,6-di-tert-butylphenol
Purity
98%
Packaging
100g
Price
$316
Updated
2023/06/20
TCI Chemical
Product number
B1758
Product name
4-Bromo-2,6-di-tert-butylphenol
Purity
>98.0%(GC)
Packaging
25g
Price
$273
Updated
2024/03/01
TRC
Product number
B686718
Product name
4-Bromo-2,6-di-tert-butylphenol
Packaging
250mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
2701-9-X5
Product name
4-Bromo-2,6-di-tert-butylphenol
Purity
98%
Packaging
25g
Price
$52
Updated
2021/12/16
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4-Bromo-2,6-di-tert-butylphenol Chemical Properties,Usage,Production

Chemical Properties

yellow to brown crystals

Uses

4-Bromo-2,6-di-tert-butylphenol may be used in the following studies:

  • As a terminating comonomer phenol in the phase transfer catalyzed (PTC) polymerization of 4-bromo-2,6-dimethylphenol.
  • Synthesis of 1,1-[1,10-decanediylbis(oxy)]bis[(2,6-ditertbutyl-4-bromo)benzene], a monomer, which forms poly(p-phenylenevinylene) derivatives by reaction with 1,10-dibromodecane.
  • As a reactant in the synthesis of 2,6-di-tert-butyl-phenolnorbornene (NArOH), a norbornene comonomer bearing an antioxidant hindered phenol.
  • As a catalyst with methyl aluminium to form methylaluminum bis(4-bromo-2,6-di-tert-butylphenoxide) (MABR) which may be utilized for the transformation of various epoxides to carbonyl compounds.

General Description

4-Bromo-2,6-di-tert-butylphenol is a 4-substituted-2,6-di-tert-butylphenol. It is synthesized by the bromination of 2,6-di-tert-butylphenol. The structure was confirmed by 1H NMR. Its photolysis reaction in benzene solution has been investigated. The photochemical reaction of 4-bromo-2,6-di-tert-butylphenol single crystals doped with 2,6-di-tert-butyl-p-quinone has been studied by EPR spectroscopy.

4-Bromo-2,6-di-tert-butylphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2,6-di-tert-butylphenol Suppliers

Americas 1 Belgium 3 China 82 Europe 1 Germany 4 India 5 Japan 3 Slovakia 1 Switzerland 4 United Kingdom 14 United States 18 Global 136
Aladdin Scientific
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View Lastest Price from 4-Bromo-2,6-di-tert-butylphenol manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
4-Bromo-2,6-di-tert-butylphenol 1139-52-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10 tons
Release date
2024-08-05
Career Henan Chemical Co
Product
4-Bromo-2,6-di-tert-butylphenol 1139-52-2
Price
US $1.00/KG
Min. Order
1KG
Purity
97%
Supply Ability
200kg
Release date
2020-02-01

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