Azaconazole

ChemicalBook > CAS DataBase List > Azaconazole

Product Name: Azaconazole
CAS No.: 60207-31-0
Chemical Name: Azaconazole
Synonyms: RODEWOD;madurox;R-28644;Aids108350;azoconozole;SAFETRAY SL;AZACONAZOLE;AZOCONAZOLE;Aids-108350;Azaconazol, Vetranal
CBNumber: CB3780871
Molecular Formula: C12H11Cl2N3O2
Formula Weight: 300.14
MOL File: 60207-31-0.mol

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Azaconazole Property

Melting point:: 109.9°
Boiling point:: 460.7±55.0 °C(Predicted)
Density: 1.51±0.1 g/cm3(Predicted)
vapor pressure: 8.6 x l0^-6 Pa (20 °C)
storage temp.: 0-6°C
Water Solubility: 300 mg l^-1 (20 °C)
pka: 2.94±0.12(Predicted)
CAS DataBase Reference: 60207-31-0(CAS DataBase Reference)
EPA Substance Registry System: Azaconazole (60207-31-0)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 46
WGK Germany: 1
RTECS: XZ4605000
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 34045
Product name: Azaconazole
Purity: PESTANAL?, analytical standard
Packaging: 100mg
Price: $67.6
Updated: 2024/03/01

TRC

Product number: A796033
Product name: Azaconazole
Packaging: 250mg
Price: $250
Updated: 2021/12/16

AK Scientific

Product number: L993
Product name: Azaconazole
Packaging: 100mg
Price: $126
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0122754
Product name: 1-[2-(2,4-DICHLOROPHENYL)-1,3-DIOXOLAN-2-YLMETHYL]-1H-1,2,4-TRIAZOLE
Purity: 95.00%
Packaging: 5MG
Price: $503.83
Updated: 2021/12/16

Alichem

Product number: 60207310
Product name: 1-((2-(2,4-Dichlorophenyl)-1,3-dioxolan-2-yl)methyl)-1H-1,2,4-triazole
Packaging: 1g
Price: $659.4
Updated: 2021/12/16

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Azaconazole Chemical Properties,Usage,Production

Originator

Azaconazole,Chemical

Uses

Fungicide for cultivation on wood; preservative for composite wood products.

Uses

Azaconazole is particularly active against wood-destroying and sapstain fungi. It is also used as a disinfectant in mushroom cultivation and on storage boxes for fruit and vegetables.

Definition

ChEBI: A member of the class of dioxolanes that is 1,3-dioxolane substituted at position 2 by 2,4-dichlorophenyl and 1,2,4-triazol-1-ylmethyl groups. A fungicide used mainly in ornamental crops to control canker and other diseases. Azaconazole is moderately toxic to mammals but is not expected to bioaccumulate. It is moderately toxic to birds, fish and aquatic invertebrates.

Manufacturing Process

A stirred and cooled (0°C) solution of 1-(2,4-diaminophenyl)-1-ethanone in a concentrated hydrochloric acid solution, water and acetic acid was diazotated with a solution of sodium nitrite in water. After stirring at 0°C, the whole was poured onto a solution of copper (I) chloride in a concentrated hydrochloric acid solution while stirring. The mixture was heated at 60°C. After cooling to room temperature, the product was extracted twice with 2,2'-oxybispropane. The combined extracts were washed successively with water, a diluted sodium hydroxide solution and again twice with water, dried, filtered and evaporated, yielding 1-(2,4-dichlorophenyl)-1-ethanone.
1-(2,4-Dichlorophenyl)-1-ethanon were dissolved in 1,2-ethanediol at heating. While stirring bromine were added dropwise, without external heating. After stirring at room temperature, 4-methylbenzenesulfonic acid and benzene were added. The whole was stirred and refluxed overnight with water-separator. The reaction mixture was evaporated and the residue was taken up in 2,2'- oxybispropane. The resulting solution was washed successively once with a dilute sodium hydroxide solution and 3 times with water, dried, filtered and evaporated. The residue was distilled, yielding 2-(bromomethyl)-2-(2,4- dichlorophenyl)-1,3-dioxolane.
6.9 parts of 1H-1,2,4-triazole in 150 parts of dimethylformamide were added to a stirred solution of 2.3 parts of sodium in 120 parts of methanol. The methanol was removed at normal pressure until the internal temperature of 130°C was reached. Then, 25 parts of 2-(bromomethyl)-2-(2,4- dichlorophenyl)-1,3-dioxolane were added. The reaction-mixture was stirred and refluxed for 3 h. It was allowed to cool to room temperature and poured onto water. The precipitated product was filtered off, yielding 12 parts of 1-[2- (2,4-dichlorophenyl)-1,3-dioxolan-2-yl-methyl]-1H-1,2,4-triazole, melting point 109.9°C (crystallized from diisopropylether, activated charcoal).

Therapeutic Function

Antifungal

Metabolic pathway

Little published dormation is available on the metabolism of azaconazole.

Degradation

Azaconazole is stable to light under normal storage conditions (but not in ketonic solvents). It is stable at temperatures up to 220 °C.

Azaconazole Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Azaconazole manufacturers

Career Henan Chemical Co

Product: Azaconazole 60207-31-0
Price: US $3.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,50kg
Release date: 2020-01-18

60207-31-0, AzaconazoleRelated Search:

1-CHLOROMETHYL-1H-1,2,4-TRIAZOLE 1,2,4-Triazole Thiophanate-methyl Propiconazole 5-Methyl-1H-benzotriazole 1,4-Dioxane Bensulfuron methyl Methyl acrylate Tebuconazole Dichlorodiphenylsilane Difenoconazole Cyproconazol Dichlorodimethylsilane Methylparaben 1-[[(2S,3S)-3-(2-Chlorophenyl)-2-(4-fluorophenyl)oxiran-2-yl]methyl]-1,2,4-triazole Penconazole METHYL THIOPHENE-2-CARBOXYLATE Kresoxim-methyl

AZOCONAZOLE

1-[[2-(2,4-Dichlorophenyl)-1,3-dioxolan-2-yl]methyl]-1,2,4-triazole

SAFETRAY SL

RODEWOD

4-triazole,1-((2-(2,4-dichlorophenyl)-1,3-dioxolan-2-yl)methyl)-1h-2

azoconozole

madurox

AZACONAZOLE

1-[2-(2,4-DICHLOROPHENYL)-1,3-DIOXOLAN-2-YLMETHYL]-1H-1,2,4-TRIAZOLE

Azaconazol, Vetranal

1H-1,2,4-Triazole, 1-2-(2,4-dichlorophenyl)-1,3-dioxolan-2-ylmethyl-

azaconazole (bsi,iso)

azaconazole (ISO) 1-{[2-(2,4-dichlorophenyl)-1,3-dioxolan-2-yl]methyl}-1H-1,2.4-triazole

R-28644

Aids108350

Aids-108350

Azaconazole Solution

Azaconazole 10.0 μg/ml Ethyl acetate

Azaconazole 100 μg/ml Acetonitrile

C10339000 Azaconazole

L10339000ALAzaconazolE10μg/mLin Acetonitril

L10339000CY AzaconazolE10μg/mLin Cyclohexane

Azaconazole in Acetonitrile

60207-31-0

C12H11Cl2N3O2